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Solvent-free temperature-resistant epoxy phenolic aldehyde anticorrosive coating and preparation method thereof

An epoxy phenolic and anti-corrosion coating technology, applied in the coating field, can solve the problems of low volume solid content, low coating efficiency, large environmental pollution, etc., and achieve enhanced temperature resistance, convenient coating construction, temperature resistance and chemical resistance. good effect

Active Publication Date: 2021-03-30
无锡中油瑞德防腐科技(靖江)有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to solve the common epoxy phenolic coatings in the prior art with low volume solid content, high VOC, low coating efficiency and great environmental pollution.

Method used

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  • Solvent-free temperature-resistant epoxy phenolic aldehyde anticorrosive coating and preparation method thereof
  • Solvent-free temperature-resistant epoxy phenolic aldehyde anticorrosive coating and preparation method thereof
  • Solvent-free temperature-resistant epoxy phenolic aldehyde anticorrosive coating and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] The composition of A component according to the mass parts is:

[0041]

[0042] The preparation method of modified silica powder:

[0043] Propyltrimethoxysilane is diluted to mass concentration 30% with ethanol, sprays and joins in the 800 order silicon micropowder body (silane consumption is 1.0% of silicon micropowder) in the high-speed stirring equipment, after stirring for 20 minutes, in Dry at 110°C to remove the solvent and moisture to obtain modified silicon micropowder with oil absorption ≤ 18g / 100g.

[0044] Preparation of A component

[0045] F51 epoxy phenolic resin needs to be baked and heated to 50°C in advance for use. Add E51 epoxy resin, core-shell toughening agent (30%), hyperbranched resin, hyperdispersant, defoamer, leveling agent into the paint kettle, stir evenly, add titanium dioxide and modified silica powder, Stir at high speed for 30 minutes, fineness ≤ 75um, add preheated F51 epoxy phenolic resin, then add rheological agent and thickene...

Embodiment 2

[0058]The composition of A component according to the mass parts is:

[0059]

[0060] The preparation method of modified silica powder and component A is the same as in Example 1.

[0061] The composition of B component according to the mass parts is:

[0062] Modified aromatic amine 350 parts

[0063] Modified fatty amine Ancamide 2766 650 parts

[0064] Modified aromatic amine is composed of according to the mass parts:

[0065] E51 100 copies

[0066] DDM 35 copies

[0067] Ruetasolv DI 10 servings

[0068] The preparation method of DDM modified aromatic amine prepolymer and component B is the same as in Example 1.

[0069] A:B=4:1.

Embodiment 3

[0071] The composition of A component according to the mass parts is:

[0072]

[0073] The preparation method of modified silica powder and component A is the same as in Example 1.

[0074] The composition of B component according to the mass parts is:

[0075] Modified aromatic amine 250 parts

[0076] Modified fatty amine Ancamide 2766 750 parts

[0077] Modified aromatic amine is composed of according to the mass parts:

[0078] E51 100 copies

[0079] DDM 40 copies

[0080] Ruetasolv DI 20 servings

[0081] The preparation method of DDM modified aromatic amine prepolymer and component B is the same as in Example 1.

[0082] A:B=4:1.

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PUM

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Abstract

The invention belongs to the technical field of coatings, and particularly discloses a solvent-free temperature-resistant epoxy phenolic anticorrosive coating and a preparation method thereof. The preparation method comprises the steps that resin, a wetting dispersant, a toughening diluent, filler, a curing agent and other components are screened or modified, and viscosity reduction is conducted on the coating; and finally the solvent-free epoxy phenolic aldehyde temperature-resistant anticorrosive coating with the operable time of more than 2 hours is obtained. The environment-friendly requirement of VOC is met and the coating construction is facilitated, and the production efficiency is improved. Meanwhile, the glass transition temperature of the epoxy phenolic aldehyde coating is further increased, the temperature resistance of the coating is enhanced, and the prepared coating has good adhesive force, flexibility and impact resistance. Good balance between the mechanical property and the temperature-resistant and chemical-resistant properties of a paint film is obtained.

Description

technical field [0001] The invention belongs to the technical field of coatings, and in particular relates to a solvent-free temperature-resistant epoxy phenolic anticorrosion coating and a preparation method thereof. Background technique [0002] The difficulty of solvent-free epoxy phenolic coatings is that the viscosity of epoxy phenolic resin is too high and the fluidity is very poor, so it is difficult to process into solvent-free epoxy phenolic coatings. The volume solid content of existing phenolic coatings is generally 50-60%. Such products have low viscosity and easy construction, but have high VOC content and low film thickness at one time, which are not suitable for the requirements of efficient and environmentally friendly coating. [0003] Solvent-free phenolic epoxy coatings have extremely low VOC emissions, but have a high viscosity, and the operating time is less than 30 minutes. When spraying, it is necessary to strictly control the spraying time, or use mul...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D163/04C09D163/00C09D5/08C09D7/65C09D7/61C09D7/62
CPCC09D163/04C09D163/00C09D5/08C09D7/65C09D7/61C09D7/62C08K2003/2241C08L2205/02C08L2205/035C08L63/00C08L101/005C08L9/00C08L9/06C08K3/22C08K9/06C08K3/36C08L63/04
Inventor 钟广义曹兵
Owner 无锡中油瑞德防腐科技(靖江)有限公司
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