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Scale and corrosion inhibitor and preparation method and application thereof

A scale and corrosion inhibitor, mass ratio technology, applied in the field of scale and corrosion inhibitors and their preparation, can solve the problems affecting the safety, stability and economical operation of coal chemical equipment, and reduce the operating efficiency, stability and biological effects of circulating cooling water systems. Poor degradability and other problems, to achieve the effects of economy and stability, reducing system sewage discharge, reducing the amount and type of chemicals

Pending Publication Date: 2021-04-16
金瓷科技实业发展有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

It has seriously affected the safety, stability and economic operation of coal chemical plants
[0005] At present, there are many kinds of scale and corrosion inhibitors used in the circulating cooling water system of the coal chemical industry, but their components are relatively single, the stability and biodegradability are not good, and they are not suitable for water quality with high alkalinity and high hardness. PH water quality, the effect of scale and corrosion inhibition is poor, which reduces the operating efficiency of the circulating cooling water system
[0006] In order to ensure the economical, safe and stable operation of the circulating water in the coal chemical industry, in addition to the design of the device should be reliable, the configuration should be reasonable, and the operation management should be perfect and thoughtful. Constantly concentrated and deteriorated, the corrosion rate of each heat exchange equipment is accelerated, and the fouling is serious, which affects the heat exchange efficiency

Method used

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  • Scale and corrosion inhibitor and preparation method and application thereof
  • Scale and corrosion inhibitor and preparation method and application thereof
  • Scale and corrosion inhibitor and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] Example 1. A coking plant of the National Energy Group uses municipal water and reclaimed water in the industrial park as circulating water for replenishment. The water quality analysis is shown in Table 1.

[0037] Table 1

[0038]

[0039] A scale and corrosion inhibitor suitable for coal coking circulating water in the coal chemical industry, the raw material content is as follows:

[0040] In component A, zinc sulfate heptahydrate is 2-6g, sodium molybdate is 12-25g, and sodium hexametaphosphate is 5-10g. In component B, 2-phosphonobutane-1,2,4-tricarboxylic acid is 14-20 g, phosphinohydrolyzed polymaleic anhydride is 8-13 g, and 2-hydroxyphosphoacetic acid is 7-10 g. In component C, benzotriazole is 2-6g. In component D, the amount of acrylic acid-2-methyl-2-acrylamidopropanesulfonic acid copolymer is 8-15g, and the amount of sodium humate is 2-4g. In component E, the dendritic polymer (DTPA-PAMAM) is 2-4g. Deionized water accounting for 30-50% of the total ...

Embodiment 2

[0042]Example 2. A coal-to-methanol project of the National Energy Group uses municipal water and reclaimed water in the industrial park as circulating water for replenishment. The water quality analysis is shown in Table 2.

[0043] Table 2

[0044]

[0045] A scale and corrosion inhibitor suitable for coal-to-methanol circulating water in the coal chemical industry. The raw material content is as follows:

[0046] In component A, zinc salt is zinc sulfate heptahydrate, molybdate is sodium molybdate, polyphosphate is sodium hexametaphosphate, zinc sulfate heptahydrate is 2-6g, sodium molybdate is 12-25g, hexametaphosphate Sodium 5-10g. In component B, 2-phosphonobutane-1,2,4-tricarboxylic acid is 14-20 g, phosphinohydrolyzed polymaleic anhydride is 8-13 g, and 2-hydroxyphosphoacetic acid is 7-10 g. In component C, benzotriazole is 2-6g. In component D, the amount of acrylic acid-2-methyl-2-acrylamidopropanesulfonic acid copolymer is 8-15g, and the amount of sodium humat...

Embodiment 3

[0048] Example 3. A coal-to-olefins project of the National Energy Group uses municipal water and reclaimed water in the park as circulating water for replenishment. The water quality analysis is shown in Table 3.

[0049] table 3

[0050]

[0051] A scale and corrosion inhibitor suitable for coal-to-olefin circulating water in the coal chemical industry. The raw material content is as follows:

[0052] In component A, zinc salt is zinc sulfate heptahydrate, molybdate is sodium molybdate, polyphosphate is sodium hexametaphosphate, zinc sulfate heptahydrate is 2-6g, sodium molybdate is 12-25g, hexametaphosphate Sodium 5-10g. In component B, 2-phosphonobutane-1,2,4-tricarboxylic acid is 14-20 g, phosphinohydrolyzed polymaleic anhydride is 8-13 g, and 2-hydroxyphosphoacetic acid is 7-10 g. In component C, benzotriazole is 2-6g. In component D, the amount of acrylic acid-2-methyl-2-acrylamidopropanesulfonic acid copolymer is 8-15g, and the amount of sodium humate is 2-4g. I...

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Abstract

The invention provides a scale and corrosion inhibitor which comprises a component A, a component B, a component C, a component D and a component E. The component A is one or more of zinc salt, molybdate and polyphosphate, the component B is one or more of 2-phosphonic acid butane-1, 2, 4-tricarboxylic acid, phosphino hydrolytic polymaleic anhydride and 2-hydroxy phosphonoacetic acid, the component C is benzotriazole, the component D is an acrylic acid-2-methyl-2-acrylamide propane sulfonic acid copolymer and sodium humate, and the component E is a dendritic polymer. The scale and corrosion inhibitor provided by the invention is simple to use, low in dosage, excellent in performance, high in stability and good in biodegradability.

Description

technical field [0001] The invention relates to a scale and corrosion inhibitor, a preparation method and application thereof. Background technique [0002] Water is the foundation of industry, and industrial circulating cooling water accounts for more than 70% of the entire industrial water. High hardness, high alkali, high pH value, corrosion, scaling and microorganisms of industrial circulating water are the main factors affecting the operation of circulating water system. Therefore, whether the industrial circulating cooling water system operates efficiently, safely and economically is an important consideration for enterprises, and the performance of water treatment chemical products in industrial circulating systems directly affects the life of production system equipment, production costs and production efficiency. [0003] In recent years, with the rapid development of the coal chemical industry, the problem of water use in coal chemical enterprises has become incre...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F5/10C02F5/14C23F11/08C02F103/34
Inventor 赵剑张广军王曰锋聂大刚洪宇郎晓政闫浩尹新旺
Owner 金瓷科技实业发展有限公司