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Flame-retardant conductive adhesive for electronic packaging and preparation method thereof

A technology for electronic packaging and conductive adhesives, applied in conductive adhesives, adhesives, epoxy resin adhesives, etc., can solve problems such as inability to achieve permanent modification, prevent excessive contact from affecting bonding performance, not easily oxidized, and prepare simple craftsmanship

Inactive Publication Date: 2021-04-30
CHENDU NEW KELI CHEM SCI CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] Aiming at the defect that the anti-oxidation process of copper powder conductive adhesive widely used at present cannot achieve permanent modification, and at the same time directly adding flame retardants to the conductive adhesive affects the bonding effect, the present invention proposes a flame-retardant conductive adhesive for electronic packaging and the preparation method, on the one hand, the anti-oxidation performance of the conductive adhesive is effectively improved, and at the same time, the conductive adhesive has a flame retardant effect and does not affect the adhesion

Method used

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  • Flame-retardant conductive adhesive for electronic packaging and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] (1) 30 parts by weight of ultra-fine spherical copper powder with a particle size of 2-5 μm is ultrasonically cleaned to remove impurities, and then 3 parts by weight of silane coupling agent is added to 67 parts by weight of absolute ethanol, and 2 parts by weight of carbon airgel is added , stirring at a speed of 500 rpm for 15 minutes, then standing, filtering, and drying naturally to obtain carbon airgel-loaded copper powder;

[0032] (2) Stir and disperse the silica airgel, the flame retardant trimethyl phosphate, and the curing agent methyl hexahydrophthalic anhydride at a mass ratio of 1:3:1, so that the silica airgel can fully absorb the flame retardant Agent, curing agent, obtain the silica airgel of loading flame retardant and curing agent;

[0033] (3) Add 5 parts by weight of the carbon airgel-loaded copper powder prepared in step (1) to 46 parts by weight of the base glue bisphenol A epoxy resin, mix and stir for 1 hour, let stand at room temperature for 24...

Embodiment 2

[0035] (1) 35 parts by weight of ultra-fine spherical copper powder with a particle size of 2-5 μm is ultrasonically cleaned to remove impurities, and then 4 parts by weight of silane coupling agent is added to 60 parts by weight of absolute ethanol, and 2 parts by weight of carbon airgel is added , stirred at a speed of 800rpm for 20min, then left to stand, filtered, and dried naturally to obtain carbon airgel-loaded copper powder;

[0036] (2) Stir and disperse the silica airgel, the flame retardant triethylphosphonate, and the curing agent methyl hexahydrophthalic anhydride at a mass ratio of 1:3:1, so that the silica airgel can fully absorb and resist Flame retardant, curing agent, obtain the silica airgel of loading flame retardant and curing agent;

[0037](3) Add 8 parts by weight of the carbon airgel-loaded copper powder prepared in step (1) to 52 parts by weight of the base glue bisphenol A epoxy resin, mix and stir for 1.5 hours, let stand at room temperature for 24 ...

Embodiment 3

[0039] (1) 40 parts by weight of ultra-fine spherical copper powder with a particle size of 2-5 μm is ultrasonically cleaned to remove impurities, and then 5 parts by weight of silane coupling agent is added to 67 parts by weight of absolute ethanol, and 3 parts by weight of carbon airgel is added , stirred at a speed of 800rpm for 20min, then left to stand, filtered, and dried naturally to obtain carbon airgel-loaded copper powder;

[0040] (2) Stir and disperse the silica airgel, the flame retardant hexamethylphosphazene, and the curing agent methyl hexahydrophthalic anhydride at a mass ratio of 1:3:1, so that the silica airgel can fully absorb the flame retardant Agent, curing agent, obtain the silica airgel of loading flame retardant and curing agent;

[0041] (3) Add 10 parts by weight of the carbon airgel-loaded copper powder prepared in step (1) to 56 parts by weight of the base glue bisphenol A epoxy resin, mix and stir for 1.5 hours, and let stand at room temperature ...

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Abstract

The invention relates to the field of electronic materials, and provides a flame-retardant conductive adhesive for electronic packaging and a preparation method thereof. The preparation method comprises the following steps of loading silane coupling agent treated copper powder on carbon aerogel, then adding the carbon aerogel into matrix glue, fully and uniformly mixing, and then uniformly mixing with silicon dioxide aerogel loaded with a flame retardant and a curing agent and a plasticizer, so as to obtain the flame-retardant conductive adhesive for electronic packaging. According to the method, superfine copper powder is loaded through carbon aerogel, so that the copper powder is effectively prevented from being oxidized; the silicon dioxide aerogel loaded flame retardant is dispersed in the conductive adhesive, the prepared conductive adhesive has a flame retardant effect, the bonding usability of the conductive adhesive is not affected by loading the flame retardant, meanwhile, the preparation process is simple, the preparation cost is greatly reduced, and the application of the copper powder conductive adhesive in the field of electronic packaging is effectively broadened.

Description

technical field [0001] The invention relates to the field of electronic materials, in particular to the preparation of conductive glue, in particular to a flame-retardant conductive glue for electronic packaging and a preparation method. Background technique [0002] In the field of electronic packaging, the environmental pollution caused by tin-lead solder has attracted more and more attention. As a substitute for tin-lead solder, conductive adhesives have attracted widespread interest because of their environmental friendliness, mild processing conditions, and simple process. However, conductive adhesives generally have problems such as low conductivity. Therefore, the development of conductive adhesives with excellent performance and capable of replacing traditional lead-tin solders has become the focus of research. [0003] Conductive adhesive is usually composed of two parts: matrix resin and conductive filler. Among them, the conductive filler is mainly metal powder...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J9/02C09J163/00C09J11/06
CPCC08K2201/001C09J9/02C09J11/06C09J163/00C08K13/06C08K9/12C08K9/06C08K7/26C08K7/24C08K7/18C08K5/12C08K5/521C08K5/5333C08K5/5399
Inventor 陈庆昝航司文彬白涛
Owner CHENDU NEW KELI CHEM SCI CO LTD
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