Brain-targeted nano-drug delivery system and preparation method thereof
A nano-drug and delivery system technology, applied in the field of biomedicine, can solve the problems of difficulty in crossing the blood-brain barrier, low bioavailability, short half-life, etc., achieving good biocompatibility and biodegradability, great development potential, delayed release effect
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Embodiment 1
[0085] Take 2100mg PLA-PEG-NH 2and 100 mg DTPA were dissolved in 10 ml DMSO. After adding about 1ml of triethylamine dropwise, react at 45°C for 12h. After the reaction, the reaction solution was dialyzed for 24 hours with a dialysis bag with a molecular weight cut-off of 3500 Da, during which the water was changed 6 times. Finally, the dialysate in the bag was freeze-dried to obtain PLA-PEG-DTPA. figure 1 PLA-PEG-NH 2 and the infrared spectrum of PLA-PEG-DTPA. figure 2 for PLA-PEG-DTPA 1 H NMR spectrum.
Embodiment 2
[0087] Take 200mg of gadolinium chloride hexahydrate and 100mg of PLA-PEG-DTPA prepared in Example 1 and dissolve them in a mixed solvent of 15ml of water / dioxane (1:2v / v). Then the pH value of the mixed raw material solution was adjusted to 6.0-6.5 with 0.1M NaOH solution, and the reaction mixture was stirred at 50° C. for 4 h. Then, the reaction mixture was dialyzed for 24 h with a dialysis bag with a molecular weight cut-off of 1000 Da, during which the water was changed 6 times. Freeze-dry the dialysate in the bag to obtain PLA-PEG-Gd. image 3 It is the morphology (A) and particle size distribution (B) of PLA-PEG-Gd. Figure 4 Magnetic resonance imaging properties of PLA-PEG-Gd.
Embodiment 3
[0089] 100 mg each of PLA-PEG-Gd and PLA-PEG-Mal prepared in Example 2 were dissolved in tetrahydrofuran and set aside. Take rifampicin 100mg and dissolve in tetrahydrofuran, set aside. The rifampicin solution was added dropwise to the PLA-PEG-Mal mixture of the above two PLA-PEG-Gd on an ultrasonic cell pulverizer while ultrasonicating, and ultrasonically dispersed for 15 minutes. The ratio of PLA-PEG-Gd and PLA-PEG-Mal is 1:1, and rifampicin with the same quality as PLA-PEG-Gd is added. The above mixture of rifampin and polymer was added dropwise to 25 mL of water under the condition of ultrasound, and the ice bath was sonicated for 30 minutes. The ultrasonic solution was transferred to a 3500Da dialysis bag for dialysis in an ice bath for 24 hours, during which the water was changed 6 times. The dialysate in the bag was freeze-dried to obtain RIF@PLA-PEG-Gd / Mal.
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