Strip-shaped brazing filler metal for lap joint brazing of copper plate and aluminum plate and preparation method thereof

A technology of strip brazing filler metal and aluminum plate, applied in the direction of welding equipment, welding/cutting medium/material, welding medium, etc., can solve the problems of poor brazing process, high temperature, poor wettability, etc., and achieve brazing process Excellent performance, wide application range and high mechanical properties

Active Publication Date: 2021-06-04
ZHENGZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Chinese patent CN103317253B (application date is June 3, 2013) discloses a Zn-Al-Cu based solder for aluminum / copper brazing and its preparation method, which has high shear strength and good corrosion resistance , but using 5%-16% aluminum, the melting point of the solder obtained is 370°C-410°C, and the temperature is relatively high, which cannot fully meet the application of copper-aluminum brazing, and the excessive aluminum content and copper content cause brazing Cu 3 Al 2 and CuAl 2 The intermetallic compound weakens the shear strength of the brazed joint, and the summary of the invention and the examples do not give the experimental data of the shear strength
[0006] At present, the technical problems in this field are: the melting temperature of the solder is relatively high, resulting in poor wettability during brazing, and poor brazing processability; the shear strength of copper-aluminum joints is low

Method used

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  • Strip-shaped brazing filler metal for lap joint brazing of copper plate and aluminum plate and preparation method thereof
  • Strip-shaped brazing filler metal for lap joint brazing of copper plate and aluminum plate and preparation method thereof
  • Strip-shaped brazing filler metal for lap joint brazing of copper plate and aluminum plate and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0039] like figure 1 As shown, a strip-shaped brazing filler metal for overlapping brazing of a copper plate and an aluminum plate includes a brazing filler metal body 1, a coating I2 and a coating II 3, the brazing filler metal body 1 is a strip with a rectangular cross section, and the upper surface There is a coating I2 in contact with the copper plate, and a coating II3 in contact with the aluminum plate is provided on the lower surface of the solder body 1 .

[0040] The chemical composition of the solder body 1 is calculated by mass percentage: 3.2% of nano-zinc oxide, 6.8% of selenium, 2.6% of aluminum, and the balance is zinc; coating I2 is composed of surface-modified nano-copper and polyvinyl alcohol; coating II3 is composed of surface-modified nano-aluminum and polyvinyl alcohol.

[0041] The molecular weight of polyvinyl alcohol is 8000-12000.

[0042] The mass percentage of surface-modified nano-copper in coating I2 is 90%, and the balance is polyvinyl alcohol; ...

Embodiment 2

[0053] Basically the same as Example 1, the difference is: 1. the chemical composition of the solder body 1 is calculated by mass percentage: 3.9% of nano-zinc oxide, 7.5% of selenium, 3.4% of aluminum, and the balance is zinc; 2. surface modification in coating I2 The mass percentage of permanent nano-copper is 91%, and the balance is polyvinyl alcohol; the mass percentage of surface-modified nano-aluminum in coating II3 is 91%, and the balance is polyvinyl alcohol.

Embodiment 3

[0055] Basically the same as Example 1, the difference is that: 1. the chemical composition of the solder body 1 is calculated by mass percentage: 4.5% of nano-zinc oxide, 8.2% of selenium, 4.2% of aluminum, and the balance is zinc; The mass percentage of permanent nano-copper is 92%, and the balance is polyvinyl alcohol; the mass percentage of surface-modified nano-aluminum in coating II3 is 92%, and the balance is polyvinyl alcohol.

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Abstract

The invention belongs to the field of welding materials, and relates to strip-shaped brazing filler metal for lap joint brazing of a copper plate and an aluminum plate and a preparation method thereof. The strip-shaped brazing filler metal comprises a brazing filler metal body, a coating I and a coating II, the brazing filler metal body comprises the chemical components of 3.2%-4.5% of nano-zinc oxide, 6.8%-8.2% of selenium, 2.6%-4.2% of aluminum and the balance zinc, the coating I is composed of 90%-92% of surface modified nano-copper and the balance of polyvinyl alcohol, the coating II is composed of 90%-92% of surface modified nano-aluminum and the balance of polyvinyl alcohol, and the molecular weight of the polyvinyl alcohol is 8000 to 12000. According to the strip-shaped brazing filler metal for lap joint brazing of the copper plate and the aluminum plate and the preparation method thereof, the melting point of the brazing filler metal is 330 DEG C +/-10 DEG C, the wettability of the brazing filler metal is good, and due to the existence of the nano-zinc oxide, the nano-copper coating and the nano-aluminum coating, the shear strength of a copper plate and aluminum plate brazed joint is effectively improved and reaches 121 MPa or above. The preparation method is an innovation in the aspect of the strip-shaped brazing filler metal for lap joint brazing of the copper plate and the aluminum plate.

Description

technical field [0001] The invention belongs to the technical field of welding materials, and in particular relates to a strip-shaped brazing filler metal for overlapping brazing of a copper plate and an aluminum plate and a preparation method thereof. Background technique [0002] Copper is an excellent electrical and thermal conductive material with good calendering properties, and is widely used in power transmission, heat exchange, electronic products, refrigeration equipment and other fields. However, copper is a scarce metal and belongs to strategic resources. In recent years, the price of copper has remained high, which limits the application of copper. The shortage of copper resources and the resulting rise in copper prices have prompted scientific and technological workers to devote themselves to finding copper substitutes. Aluminum has excellent electrical and thermal conductivity, corrosion resistance and good processing performance, and is the best material to re...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B23K35/02B23K35/28B23K35/365B23K35/40
CPCB23K35/0238B23K35/282B23K35/365B23K35/40B23K35/404
Inventor 陈永刘胜新陈志民潘继民吴奇隆李宇佳颜新奇
Owner ZHENGZHOU UNIV
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