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Antibacterial viscose fiber added with rare earth oxide and preparation method of antibacterial viscose fiber

A rare earth oxide and viscose fiber technology, applied in the direction of man-made filaments made of viscose, can solve the problems of mismatch, rare earth elements do not have antibacterial effect, etc., and achieve difficult agglomeration, good spinnability, and good dispersion. sexual effect

Pending Publication Date: 2021-06-15
镧明材料技术(上海)有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

First of all, the role of the rare earth in this patent application is: the rare earth element is coated on the surface of the titanium dioxide antibacterial agent, and it is not easy to lose, thereby improving the antibacterial and antifungal properties of the product, but the rare earth element itself does not play an antibacterial effect
Secondly, the patent application uses a non-aqueous system suspension, which does not match the viscose preparation process (aqueous system suspension is required)

Method used

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  • Antibacterial viscose fiber added with rare earth oxide and preparation method of antibacterial viscose fiber
  • Antibacterial viscose fiber added with rare earth oxide and preparation method of antibacterial viscose fiber

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] A kind of preparation method of the antibacterial viscose fiber that adds rare earth oxide, comprises the following steps:

[0025] Firstly, the rare earth nano-antibacterial suspension is prepared: the rare earth antibacterial powder with good antibacterial effect is processed by a sand mill with temperature control, and the rare earth antibacterial suspension is prepared.

[0026] (1) Take by weight 20 parts of rare earth antibacterial powder (cerium oxide: mass ratio of rare earth oxide=95:5), dispersant (polycarboxylate ammonium salt dispersant: the quality of nonionic polymer dispersant Ratio = 1:1) 6 parts, 50 parts of water, 1 part of 1mol / L sodium hydroxide solution, first add all the water and 2 parts of dispersant to the circulation tank of the sand mill, and wait until the dispersant is fully mixed in water .

[0027] (2) Use 0.1mm zirconia balls for sand milling, the cavity temperature of the sand mill is controlled at 20°C-22°C, and the speed of the sand m...

Embodiment 2

[0031] A kind of preparation method of the antibacterial viscose fiber that adds rare earth oxide, comprises the following steps:

[0032] Firstly, the rare earth nano-antibacterial suspension is prepared: the rare earth antibacterial powder with good antibacterial effect is processed by a sand mill with temperature control, and the rare earth antibacterial suspension is prepared.

[0033] (1) Weigh 25 parts of rare earth antibacterial powder (cerium oxide: rare earth oxide: copper oxide mass ratio=93:5:2), dispersant (water-based acrylic polymer: containing rare earth affinity group) by weight The mass ratio of polymer block copolymer=4:1) 8 parts, 55 parts of water, 2 parts of 1mol / L sodium hydroxide solution, first add all the water and 2 parts of dispersant to the circulation cylinder of the sand mill, Thoroughly mix the dispersant in water.

[0034] (2) Use 0.1mm zirconia balls for sand milling, the chamber temperature of the sand mill is controlled at 22°C-24°C, and the...

Embodiment 3

[0037] A kind of preparation method of the antibacterial viscose fiber that adds rare earth oxide, comprises the following steps:

[0038] Firstly, the rare earth nano-antibacterial suspension is prepared: the rare earth antibacterial powder with good antibacterial effect is processed by a sand mill with temperature control, and the rare earth antibacterial suspension is prepared.

[0039](1) Take by weight 30 parts of rare earth antibacterial powder (cerium oxide), 12 parts of dispersant (maleic acid styrene-based dispersant: mass ratio=1:1 of ultra-macromolecular polymer dispersant containing carboxyl group), 55 parts of water, 3 parts of 1mol / L sodium hydroxide solution, first add all the water and 3 parts of dispersant to the circulation cylinder of the sand mill, and mix the dispersant fully in the water.

[0040] (2) Use 0.1mm zirconia balls for sand milling, the chamber temperature of the sand mill is controlled at 23°C-25°C, and the speed of the sand mill is controlled...

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Abstract

The invention discloses an antibacterial viscose fiber added with rare earth oxide and a preparation method of the antibacterial viscose fiber. The antibacterial viscose fiber is prepared from the following raw materials in parts by weight of 20 to 30 parts of rare earth antibacterial powder, 6 to 12 parts of dispersing agent, 50 to 55 parts of water and cellulose, wherein the rare earth antibacterial powder takes cerium oxide as a base, and the balance is one or more of other rare earth oxides and copper oxide. The rare earth antibacterial powder with good antibacterial performance is selected, the rare earth antibacterial powder is prepared into the nano rare earth antibacterial suspension through an appropriate dispersion system and a sanding process, the viscose spinning mixed solution is prepared through an appropriate adding mode, the obtained rare earth antibacterial suspension is good in dispersion performance, is matched with the high viscosity and alkalinity of a viscose system, and is easy to add; and the obtained antibacterial viscose fiber is durable in antibacterial effect and wide in antibacterial spectrum.

Description

technical field [0001] The invention belongs to the field of functional fiber preparation, and in particular relates to an antibacterial viscose fiber added with rare earth oxides and a preparation method thereof. Background technique [0002] In the prior art, the inorganic nano antibacterial suspension with high solid content and good dispersibility is not easy to prepare, and the suspension cannot maintain suspension for a long time. Because the viscose collagen solution has the characteristics of high alkalinity, if the inorganic antibacterial suspension is added to the viscose collagen solution, the particles are easy to agglomerate and agglomerate, which affects the spinning of viscose. Although the organic antibacterial suspension has good compatibility with the viscose collagen solution, its cost is high, and the organic antibacterial agent has poor heat resistance, is easy to decompose and lose efficacy, and the toxic decomposition products may cause secondary pollu...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F2/08
CPCD01F2/08
Inventor 高曾伟吴文远
Owner 镧明材料技术(上海)有限公司
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