Preparation method and preparation system of ammonium catalyst, active iron and manganese oxide ammonium catalyst and deamination application

Abstract

The invention relates to the technical field of ammonium catalyst preparation, in particular to an ammonium catalyst preparation method, a preparation system, an active iron and manganese oxide ammonium catalyst and deamination application. The method includes the following steps: an iron and manganese salt solution is prepared, wherein the concentration of Fe < 2 + > is 6 mg / L to 100 mg / L, and the concentration of Mn < 2 + > is 20 mg / L to 400 mg / L; a potassium permanganate solution doped with multiple ions is prepared, wherein the concentration of KMnO4 is 49 mg / L to 945 mg / L, the concentration of Ca < 2 + > is 35 mg / L to 45 mg / L, the concentration of Mg < 2 + > is 20 mg / L to 28 mg / L, the concentration of HCO3 <-> is 244 mg / L to 610 mg / L, the concentration of F <-> is 0.5 mg / L to 3 mg / L, the concentration of H3BO3 is 56 mg / L to 109 mg / L, the concentration of PO4 < 3-> is 3 mg / L to 60 mg / L, the concentration of Sr < 2 + > is 0.5 mg / L to 1 mg / L, and the concentration of SiO3 < 2-> is 1.4 mg / L to 20 mg / L; then 20-30 L of an iron-manganese salt solution and 20-30 L of a potassium permanganate solution doped with multiple ions are mixed and are stirred for 3-5 minutes to obtain iron-manganese oxide doped with multiple elements; and mineralization is performed on the multi-element doped iron and manganese oxide to obtain the active iron and manganese oxide ammonium catalyst.

Description

Technical field [0001] The present invention relates to the field of preparation of ammonium catalysts, and more particularly to an ammonium catalyst preparation method, a preparation system, an active iron manganese oxide ammonium ammonium catalyst, and deammine. Background technique [0002] Ammonia nitrogen catalyzed oxidation treatment for low concentration ammonia nitrogen contamination, the method currently employed is biodefitricating method and ion exchange. The biological deconaving method is a method of converting the ammonia nitrogen in the wastewater into nitrogen by a microbial effect, ammonia, nitrification, and denitrification, etc., has high efficiency, economical, practical, etc., which is very common, and the application is very common. However, the primary effects of microorganisms during biological denitrification are very sensitive, susceptible to pH, temperature, and nutrients such as pH, temperature and nutrients, etc., caused microorganisms to lose biologi...

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Problems solved by technology

[0005] The object of the present invention is to provide a kind of ammonium catalyst preparation method, preparation system, active iron manganese oxide ammonium catalyst and deamination application, through the proposal of ammonium catalyst preparation method In order to solve the ammonia nitrogen catalytic oxidation treatment of the actual municipal water polluted by low concentration ammonia nitrogen in the existing technology, the biological denitrification method has high requirements on the environment, and the exchange capacity of the ion exchange method is limited, it is easy to absorb and saturate, the treatment is complicated, and the time is long technical problem

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