High-durability concrete in high-salt service state and preparation method thereof
A durable concrete and service state technology, applied in the field of concrete, can solve the problems of poor corrosion resistance of concrete, reduction of corrosion resistance of concrete, corrosion of concrete, etc.
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preparation example 1
[0071] At a temperature of 20°C, mix and stir 8mL acrylic acid and 8mL distilled water, then slowly add 20wt% NaOH aqueous solution for neutralization, control the neutralization degree of the reaction system to 84%, and then add 0.008mL N,N-methylene base bisacrylamide and 0.8g sepiolite, stirred and reacted for 30min, then added 0.32mL composite initiator to the reaction system, reacted at a temperature of 55°C for 4h, and then soaked in methanol for washing to remove water-soluble oligomers, The uncrosslinked polymer and unreacted monomers are then dried in an oven at 70°C to constant weight, crushed and passed through a 60-mesh sieve to obtain a sepiolite composite superabsorbent resin.
[0072] Wherein the composite initiator comprises 0.16 mL of L-ascorbic acid with a concentration of 0.5 wt % and 0.16 mL of hydrogen peroxide with a concentration of 0.35 wt %.
preparation example 2
[0074] At a temperature of 28°C, mix and stir 8 mL of acrylic acid and 9.6 mL of distilled water, then slowly add 24 wt% NaOH aqueous solution for neutralization, control the neutralization degree of the reaction system to 86%, and then add 0.016 mL of N,N- Methylbisacrylamide and 2.4g sepiolite, stirred and reacted for 40min, then added 0.48mL composite initiator to the reaction system, reacted at 60°C for 5h, then soaked in methanol for washing to remove water-soluble oligomers , uncrosslinked polymers and unreacted monomers, and then dried in an oven at 70°C to constant weight, crushed through a 60-mesh sieve to obtain a sepiolite composite superabsorbent resin.
[0075] Wherein the composite initiator comprises 0.218mL of L-ascorbic acid with a concentration of 0.55wt% and 0.262mL of hydrogen peroxide with a concentration of 0.4wt%.
preparation example 3
[0077] The difference from Preparation Example 1 is that after adding the composite initiator, 0.24 mL of 10 wt % polyvinyl alcohol aqueous solution was added to the reaction system.
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