A kind of high-durability concrete in high-salt service state and preparation method thereof
A technology of durable concrete and service state, applied in the field of concrete, can solve the problems of reducing the stability and safety of structures, reducing the corrosion resistance of concrete, poor corrosion resistance of concrete, etc., and achieves high internal relative humidity and drying self-shrinking effect. Small, the effect of improving the impermeability
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preparation example 1
[0071] At a temperature of 20 °C, 8 mL of acrylic acid and 8 mL of distilled water were mixed and stirred, and then NaOH aqueous solution with a concentration of 20 wt% was slowly added for neutralization. The neutralization degree of the reaction system was controlled to be 84%, and then 0.008 mL of N,N-methylene was added. base bisacrylamide and 0.8g sepiolite, stir and react for 30min, then add 0.32mL composite initiator to the reaction system, react at 55℃ for 4h, then soak in methanol for washing to remove water-soluble oligomers, The uncrosslinked polymer and the unreacted monomer are then dried in an oven at 70° C. to a constant weight, and pulverized through a 60-mesh sieve to obtain a sepiolite composite superabsorbent resin.
[0072] The composite initiator includes 0.16 mL of L-ascorbic acid with a concentration of 0.5 wt % and 0.16 mL of hydrogen peroxide with a concentration of 0.35 wt %.
preparation example 2
[0074] At a temperature of 28 °C, 8 mL of acrylic acid and 9.6 mL of distilled water were mixed and stirred, and then slowly added NaOH aqueous solution with a concentration of 24 wt% for neutralization. Methylbisacrylamide and 2.4g of sepiolite were stirred and reacted for 40min, then 0.48mL of composite initiator was added to the reaction system, and the reaction was carried out at a temperature of 60°C for 5h, and then soaked in methanol for washing to remove water-soluble oligomers , uncrosslinked polymer and unreacted monomer, then dried in an oven at 70°C to constant weight, pulverized through a 60-mesh sieve, to obtain a sepiolite composite superabsorbent resin.
[0075] The composite initiator includes 0.218 mL of L-ascorbic acid with a concentration of 0.55 wt % and 0.262 mL of hydrogen peroxide with a concentration of 0.4 wt %.
preparation example 3
[0077] The difference from Preparation Example 1 is that after the composite initiator is added, 0.24 mL of an aqueous solution of polyvinyl alcohol with a concentration of 10 wt % is also added to the reaction system.
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