Waterproof concrete synergist and preparation method thereof

A concrete synergist and waterproof technology, which is applied in the field of concrete admixtures, can solve the problems of no obvious improvement in the strength of concrete in the later stage, a decrease in the value of concrete compressive strength, and an increase in the number of pores in concrete, so as to improve slump and ease of use, improved compactness, and low-cost preparation

Active Publication Date: 2021-11-05
浙江鑫月新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The concrete synergist described in this invention patent can effectively stimulate the dispersion of cement particles, promote the degree of cement hydration, make full use of cement components, and improve the early strength of concrete. However, it can be seen from the experimental verification that this additive has no effect on the later strength of concrete. Significantly improved, and due to the introduction of calcium ions and thickeners, early setting phenomenon cannot be avoided in the early stage of concrete forming
[0006] Patent Application Publication Document CN108892411A has reported that a concrete waterproofing agent is composed of hyaluronic acid solution, gelatin solution, isocyanate, polyethylene glycol, ethylene glycol dishrink Glyceryl ether, etc., the highlight of the invention is the addition of modified polyethylene glycol and ethylene glycol diglycidyl ether, both of which form cross-linked esters with hyaluronic acid added to the product under the promotion of cement hydration reaction, Thereby improving the hydrophobicity of concrete, but the isocyanate in the composition will produce gas after directly reacting with water, which will lead to a substantial increase in the number of concrete pores and affect the compactness of concrete. The weakening of compactness will inevitably lead to a decrease in the compressive strength of concrete

Method used

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  • Waterproof concrete synergist and preparation method thereof
  • Waterproof concrete synergist and preparation method thereof
  • Waterproof concrete synergist and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] A preparation method of waterproof concrete synergist is realized through the following steps:

[0042] (1) Based on the percentage of the total weight of raw materials, weigh the following raw materials: polyaminated cellulose microspheres 13%, polymethyltriethoxysilane 11%, 4-methyl-1,3-phenylene 7% diisocyanate, 10% trimethylolpropane, 7% polyvinyl alcohol, 5% sodium pyrophosphate, 3% polyaluminum ferric sulfate, and the balance is water.

[0043] (2) Preparation of modified water-based polyurethane: Add organic solvent DMF and polymethyltriethoxysilane into a three-port device tank equipped with a stirrer, thermometer, and constant pressure dropping funnel, and add 4- Methyl-1,3-phenylene diisocyanate and trimethylolpropane, then slowly raise the temperature and add a certain amount of 18% NaOH solution drop by drop, when the temperature rises to 95 ° C, keep the reaction for 5 hours, so that the system has a A series of hydrolysis, block reaction. After the react...

Embodiment 2

[0048] A preparation method of waterproof concrete synergist is realized through the following steps:

[0049] (1) According to the percentage of the total weight of raw materials, weigh the following raw materials: polyaminated cellulose microspheres 16%, polymethyltriethoxysilane 9%, 2-methyl-1,3-phenylene 4% diisocyanate, 12% neopentyl glycine, 8% polyacryl alcohol, 6% sodium tripolyphosphate, 4% polyaluminum ferric sulfate, and the balance is water;

[0050] (2) Preparation of modified water-based polyurethane: Add organic solvent DMF and polymethyltriethoxysilane into a three-port device tank equipped with a stirrer, thermometer, and constant pressure dropping funnel, and add 2- Methyl-1,3-phenylene diisocyanate and neopentylglycine, then slowly increase the temperature and add a certain amount of 18% NaOH solution dropwise, when the temperature rises to 95 ° C, keep the reaction for 5 hours, so that the system undergoes a series of Hydrolysis, block reaction. After the...

Embodiment 3

[0055] A preparation method of waterproof concrete synergist is realized through the following steps:

[0056] (1) According to the percentage of the total weight of raw materials, weigh the following raw materials: polyaminated cellulose microspheres 12%, polymethyltriethoxysilane 6%, 4,4'-diphenylmethane diisocyanate 9%, cyclohexanetriol 7%, polyethylene glycol 10%, maltodextrin 4%, polyaluminum ferric sulfate 4%, the balance is water;

[0057] (2) Preparation of modified water-based polyurethane: Add organic solvent DMF and polymethyltriethoxysilane into a three-port device tank equipped with a stirrer, thermometer, and constant pressure dropping funnel, and add 4, 4'-diphenylmethane diisocyanate and cyclohexanetriol, then slowly raise the temperature and add a certain amount of 18% NaOH solution drop by drop, when the temperature rises to 95 ° C, keep it warm for 5 hours, so that the system undergoes a series of hydrolysis, block reaction. After the reaction was complete...

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Abstract

The invention discloses a waterproof concrete synergist and a preparation method thereof, and relates to the technical field of concrete admixtures. The waterproof concrete synergist comprises the following components by mass: 12-16% of polyaminated cellulose microspheres, 17-32% of modified waterborne polyurethane, 7-10% of a dispersant, 4-7% of a retarder, 2-5% of polyaluminum ferric sulfate, and the balance of water. According to the synergist, cement can be more sufficiently dispersed in concrete, so that the early strength and the later strength of the concrete are improved; and in addition, the synergist has the waterproof capability, and the practical engineering application range of the agent is expanded due to the improvement of the waterproof capability.

Description

technical field [0001] The invention relates to the technical field of concrete admixtures, in particular to a waterproof concrete synergist and a preparation method thereof. Background technique [0002] With the vigorous development of modern industry, concrete is widely used as a building material. Cement is the main raw material for the production of concrete. For a long time, cement, as an important cementitious material, has been widely used in civil engineering, water conservancy, national defense and other projects. According to a large number of studies, 10-20% of the cement in the concrete is still not fully dispersed and hydrated, resulting in the inability to fully play its due role. If the hydration rate of the cement can be increased, a lot of engineering costs will be saved. [0003] Concrete synergist is a new type of additive that is different from other concrete admixtures. It can fully disperse cement particles that have not undergone hydration reaction, ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B24/42C08G18/32C08G18/61C08G18/65
CPCC04B40/0039C08G18/3206C08G18/61C08G18/6517C04B24/383C04B24/282C04B2103/408C04B2103/22C04B22/142C04B22/002
Inventor 徐锋吴国庆
Owner 浙江鑫月新材料科技有限公司
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