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Method for co-producing mesopore-developed activated carbon and high-modulus silicate by using rice husks

A technology of activated carbon and silicate, which is applied in the direction of silicate, alkali metal silicate, chemical instruments and methods, etc., which can solve the problems of difficulty in increasing silicate concentration and modulus, low adsorption capacity of activated carbon, and dissolution of silica Low efficiency and other problems, to achieve the effect of controllable product quality, good product quality, simple and not cumbersome production process

Pending Publication Date: 2021-12-03
NANPING YUANLI ACTIVE CARBON CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Conventional rice husk activated carbon is first pyrolyzed and carbonized, then silica is extracted, and finally steam, CO 2 Or chemical agents are activated, the production process is cumbersome, the energy consumption is high, the amount of agents is large, and the amount of waste liquid is large
The quality of the existing rice husk co-production activated carbon or silicate product is uncontrollable, the consumption of liquid alkali is large, the dissolution rate of silica is low, the concentration and modulus of silicate are difficult to increase, the adsorption capacity of activated carbon is low, and the pore structure is underdeveloped

Method used

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  • Method for co-producing mesopore-developed activated carbon and high-modulus silicate by using rice husks
  • Method for co-producing mesopore-developed activated carbon and high-modulus silicate by using rice husks
  • Method for co-producing mesopore-developed activated carbon and high-modulus silicate by using rice husks

Examples

Experimental program
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Effect test

Embodiment 1

[0050] The rice husk is collected by the rice processing plant, the sand and large particles of foreign matter are removed by the cyclone separator, and then dried at a low temperature in a 150°C steam tube rotary kiln until the moisture is less than 5%, and then transported to the two-stage rotary kiln by the cyclone, using the same direction of the material and hot air , the carbonization section is carbonized at a temperature of 550°C for 180 minutes, and the carbonization section is fed with reducing gas natural gas and 90% pure oxygen to assist combustion and heat supply, wherein the reducing gas natural gas accounts for 0.05% of the total atmosphere volume concentration, and pure oxygen accounts for the total atmosphere The volume concentration is 8%; the activation section is simultaneously fed with auxiliary agent natural gas and activator steam at a temperature of 800 ° C for 60 minutes, natural gas accounts for 1% of the total atmosphere volume concentration, and water...

Embodiment 2

[0053] The rice husk is collected by the rice processing factory, the sand and large particles of foreign matter are removed by the cyclone separator, and then dried at a low temperature in a 160°C steam tube rotary kiln until the moisture is less than 5%, and then transported to the two-stage rotary kiln by the cyclone, using the same direction of the material and hot air In the carbonization section, the temperature is controlled at 600°C for 120 minutes of carbonization. The carbonization section is fed with reducing gas hydrogen as an auxiliary agent and 92% pure oxygen to assist combustion and heat supply. Among them, the reducing gas hydrogen accounts for 4% of the total atmosphere volume concentration, and pure oxygen accounts for 4%. The total atmosphere volume concentration is 2%; the activation section is simultaneously fed with auxiliary agent reducing gas hydrogen and activator steam at a temperature of 850 ° C for 50 minutes, hydrogen accounts for 7% of the total at...

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Abstract

The invention provides a method for co-producing mesopore-developed activated carbon and high-modulus silicate by using rice husks, and belongs to the technical field of activated carbon production, the method comprises the following steps: respectively carbonizing and activating the rice husks in two sections in a carbon activation integrated furnace, wherein a carbon section and an activation section are in a reducing gas atmosphere, and meanwhile, steam is introduced into the activation section; activating to obtain a rice hull activated material with high carbon content and high-activity silicon dioxide, extracting active silicon dioxide from the rice hull activated material at normal pressure in a gradient manner, and reacting gradient silicate with quartz sand wet-process silicate and solid silicate to prepare a silicate solution with high modulus and high concentration, so that the evaporation and concentration cost is reduced, and the silicon dioxide extraction rate is up to more than 95%. The the mesopore-developed activated carbon is obtained from rice husk activated material by washing, pickling purification, filtration, drying, crushing, uniform mixing, iron removal and packaging. The method is high in production efficiency, good in product quality, small in environmental pollution, low in production cost and suitable for industrial production, and has good industrial popularization significance.

Description

technical field [0001] The invention belongs to the technical field of activated carbon production, and in particular relates to a method for co-producing activated carbon with well-developed mesopores and high modulus silicate by using rice husks. Background technique [0002] The information disclosed in this Background section is only intended to increase the understanding of the general background of the disclosure, and is not necessarily to be taken as an acknowledgment or any form of suggestion that the information constitutes prior art that is already known to those skilled in the art. [0003] my country is a big rice country, with an annual rice output of more than 200 million tons, accounting for about one-third of the global annual output, ranking first in the world, and rich in rice husk resources. The chemical composition of the dry basis of rice husk is about 80% organic matter and 20% ash. The organic matter is mainly cellulose, lignin, hemicellulose and other...

Claims

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Application Information

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IPC IPC(8): C01B32/336C01B32/324C01B32/378C01B33/32
CPCC01B32/336C01B32/324C01B32/378C01B33/32Y02P20/129
Inventor 陈卫群方世国余梁哥欧文周晓兰林祥龙
Owner NANPING YUANLI ACTIVE CARBON CO LTD
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