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Monocrystal high-temperature alloy directional solidification growth device and method controlled by multi-mode static magnetic field and application of monocrystal high-temperature alloy directional solidification growth device

A technology of directional solidification and superalloy, which is applied in the direction of single crystal growth, single crystal growth, polycrystalline material growth, etc., can solve the problems of unfavorable influence on mechanical properties, severe microscopic segregation, low cooling capacity, etc., and improve the subsequent service performance , cracks are not easy to produce, and the effect of reducing the content of precipitated phase

Pending Publication Date: 2022-03-11
SHANGHAI UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

These processes show their disadvantages when producing blades, especially in the production of large industrial gas turbine blades
For example, in the HRS method, the directional heat is conducted through the water-cooled copper plate at the bottom of the casting, and its cooling capacity is low, which will produce uneven structures, including coarse dendrites, severe micro-segregation, and even freckles and free crystals; the mold shell used is thick and uneven, which will also generate an uneven thermal field that leads to the formation of free crystals, and these defects seriously reduce the mechanical properties of the alloy
In order to improve the cooling capacity, people have developed the LMC method, but there is a huge risk of the coolant eroding the casting, and it also has an adverse effect on the mechanical properties. It has not been widely used in industry at present.
DWDS and ZMLMC methods are currently limited to small and relatively simple samples, and are still in the stage of laboratory development

Method used

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  • Monocrystal high-temperature alloy directional solidification growth device and method controlled by multi-mode static magnetic field and application of monocrystal high-temperature alloy directional solidification growth device
  • Monocrystal high-temperature alloy directional solidification growth device and method controlled by multi-mode static magnetic field and application of monocrystal high-temperature alloy directional solidification growth device
  • Monocrystal high-temperature alloy directional solidification growth device and method controlled by multi-mode static magnetic field and application of monocrystal high-temperature alloy directional solidification growth device

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] In this embodiment, a single crystal superalloy directional solidification growth device controlled by a multi-mode static magnetic field, see figure 1, including a directional solidification system, a temperature measurement system and a magnetic field generator system; the directional solidification system includes a growth cavity, an insulating layer 3, a heating resistor 4, a crucible 5, a pull rod 15, a servo drawing system 17 and a cooling system; the growth cavity The body is composed of a stainless steel furnace shell 2 cooled by cooling water and an internal heat preservation layer 3. A heating resistor 4 is arranged in the inner cavity of the internal heat preservation layer 3, so that the crucible 5 is arranged in the space area of ​​the growth cavity, and the crucible 5 is heated. The crucible 5 is used to load the molten liquid metal 6 to be solidified; using the directional solidification method of pull-down or upward-leading zone melting, a pull rod 15 is ...

Embodiment 2

[0038] This embodiment is basically the same as Embodiment 1, especially in that:

[0039] In this embodiment, a method for preparing a single crystal Ni-based superalloy by directional solidification, the components of the single-crystal Ni-based superalloy prepared in terms of mass percentages are as follows: C: 0.067wt%, Al: 3.58wt%, Ti: 4.07wt%, Ta: 4.99wt%, Cr: 12.03wt%, Co: 8.94wt%, Mo: 1.84wt%, W: 3.91wt%, and the rest is Ni, using the multi-mode static magnetic field control of this embodiment A single crystal superalloy directional solidification growth device, including the following steps: the pulling rate is 20um / s, in one case, a static magnetic field is applied to the directional solidification device, and then a single crystal alloy is prepared by directional solidification; in another case, no magnetic field is applied prepared single crystal alloys.

[0040] Experimental test analysis:

[0041] For the test of the instantaneous tensile properties of the sing...

Embodiment 3

[0043] This embodiment is basically the same as the above-mentioned embodiment, and the special features are:

[0044] In this embodiment, the single crystal growth interface of the liquid metal 6 to be solidified in the crucible 5 is located in the uniform magnetic field area of ​​a single set of magnets, or near the uniform magnetic field area of ​​the geometric center of a double set of magnets. The single crystal growth interface of the liquid metal 6 to be solidified is placed under a controllable magnetic field, which is suitable for the adjustment of various pulling speeds and temperature gradients and other process parameters for directional solidification.

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Abstract

The invention discloses a single-crystal high-temperature alloy directional solidification growth device and method controlled by a multi-mode static magnetic field and application thereof. The single-crystal high-temperature alloy directional solidification growth device comprises a directional solidification system, a temperature control system and a magnetic field generator system, the directional solidification system comprises a growth cavity, a thermal insulation layer, a heating resistor, a crucible, a pull rod, a servo drawing system and a cooling system; the magnetic field generator system is located around a growth cavity of the directional solidification system, so that a single crystal growth interface of liquid metal to be solidified is located in a uniform or symmetrical magnetic field center area, and the intensity and configuration of a magnetic field applied by the magnetic field generator system are adjusted. The method is used for preparing the single-crystal high-temperature alloy including Ni-based, Co-based, Fe-based, Nb-based, TiAl-based and other metal single crystals, longitudinal and transverse component distribution in the single-crystal high-temperature alloy is controlled, and the microstructure and the precipitated phase of the single-crystal high-temperature alloy are changed, so that the high-temperature mechanical property of the single-crystal high-temperature alloy is improved, especially the instantaneous tensile strength and the creep durability are improved, and the service life of the single-crystal high-temperature alloy is prolonged. Therefore, the high-temperature mechanical property of the single-crystal high-temperature alloy is comprehensively

Description

technical field [0001] The invention relates to the field of material preparation and performance, and proposes a method and device for preparing directional / single crystal superalloys with excellent mechanical properties under a multi-mode static magnetic field, which is applied to the technical field of mechanical property control of various directional solidification / single crystal metal castings . Background technique [0002] Due to the elimination of grain boundaries, the single crystal superalloy has greatly improved its temperature resistance, so it has become the preferred material for the turbine blades of advanced aerospace and gas engines. The aeroengine F119 (US), GE90 (US) ), EJ200 (English, German, Italian, Spanish), M88-2 (French), P2000 (Russian), etc. all use single crystal alloy as the blade material. With the increase of the thrust-to-weight ratio of the engine, the temperature before the turbine is getting higher and higher, and the temperature before t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C30B29/52C30B11/00C30B30/04
CPCC30B29/52C30B11/00C30B11/006C30B30/04
Inventor 任维丽苏震奇袁笑坦胡兴金雷作胜钟云波
Owner SHANGHAI UNIV
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