Additive and electrolyte and lithium ion battery using same

A lithium-ion battery and electrolyte technology, applied in the field of lithium-ion batteries, can solve the problems of low rapid discharge capacity, increased self-discharge of lithium-ion batteries, and low oxidation potential.

Active Publication Date: 2022-03-15
ZHUHAI SMOOTHWAY ELECTRONICS MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in recent years, as consumers have higher and higher charging and discharging requirements for electronic products and electric vehicles, the problems of long charging time and low rapid discharge capacity of lithium-ion batteries have been plaguing the lithium-ion battery market.
The rate of deintercalation and intercalation of lithium-ion batteries in the positive/negative active material, that is, the speed at which lithium ions run out of the positive/negative active material, or the speed at which they enter the active material from the surface of the positive/negative electrode to find a place to settle down How fast it is is an important factor affecting the charge and discharge rate; at the same time, the stability of the solid electrolyte interface film is also subject to a greater test. If the solid electrolyte interface film has many pores but the stability is not good, there is no Significance, so this also poses a great challenge to the solid electrolyte interface film on the positive and negative electrodes
[0003] In order to improve the ionic conductivity and interface stability of the solid electrolyte interface film of the positive electrode, a lot of related research has been done in the industry in recent years. The invention patent CN111162318A reports a lithium-ion battery electrolyte containing a thiophene conjoined compound, a thiophene conjoined co

Method used

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  • Additive and electrolyte and lithium ion battery using same
  • Additive and electrolyte and lithium ion battery using same
  • Additive and electrolyte and lithium ion battery using same

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] In a nitrogen-filled glove box (O 2 2 (02 2 (0<1ppm), slowly add 20g of lithium hexafluorophosphate into the mixed solution, and mix well to make an electrolyte solution.

[0029] The components of the electrolyte solutions of Examples 2-16 and Comparative Examples 1-6 are shown in Table 1, and the preparation methods of the electrolyte solutions of Examples 2-16 and Comparative Examples 1-6 refer to the preparation method of Example 1.

[0030] Table 1 Electrolyte formula

[0031]

[0032]

[0033] Using LCO with a maximum charging voltage of 4.5V as the positive electrode material and natural graphite as the negative electrode material, the electrolytes of Examples 1 to 16 and Comparative Examples 1 to 6 were used to make lithium ion batteries with reference to the conventional lithium battery preparation method, and carried out 5C respectively. Rate discharge test, 3C rate cycle test, high temperature storage test, the test results are shown in Table 2.

[00...

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PUM

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Abstract

The invention discloses an additive and an electrolyte and a lithium ion battery using the additive, the additive comprises a compound 1, a compound 2 or a compound 3, the additive can orderly form a film when the battery is charged and discharged for the first time, and a formed solid electrolyte interface film has the characteristics of strong conductivity, strong ionic conductivity and low electron conductivity; therefore, the rate cycle performance, the rate discharge performance and the storage performance of the lithium ion battery can be effectively improved.

Description

technical field [0001] The invention belongs to the technical field of lithium ion batteries, and in particular relates to an additive, an electrolyte using the additive, and a lithium ion battery. Background technique [0002] Due to the advantages of high power density and energy density, small size, and long life, lithium-ion batteries are widely used in consumer electronics, mobile terminals, communication energy storage, and electric vehicles. However, in recent years, as consumers have higher and higher charging and discharging requirements for electronic products and electric vehicles, the problems of long charging time and low rapid discharge capacity of lithium-ion batteries have been plaguing the lithium-ion battery market. The rate of deintercalation and intercalation of lithium-ion batteries in the positive / negative active material, that is, the speed at which lithium ions run out of the positive / negative active material, or the speed at which they enter the acti...

Claims

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Application Information

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IPC IPC(8): H01M10/0567H01M10/0569H01M10/0568H01M10/0525
CPCH01M10/0567H01M10/0569H01M10/0568H01M10/0525H01M2220/20H01M2220/30Y02E60/10
Inventor 白晶王霹霹毛冲黄秋洁欧霜辉张元青戴晓兵
Owner ZHUHAI SMOOTHWAY ELECTRONICS MATERIALS
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