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Preparation method of coating type denitration catalyst taking modified honeycomb activated carbon as carrier and prepared catalyst

A honeycomb activated carbon, denitration catalyst technology, applied in chemical instruments and methods, physical/chemical process catalysts, metal/metal oxide/metal hydroxide catalysts, etc. The effect of lifetime, obvious carbon neutrality advantage, excellent chemical bonding ability

Pending Publication Date: 2022-04-15
ANHUI YUANCHEN ENVIRONMENTAL PROTECTION SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0007] The technical problem to be solved by the present invention is how to solve the problem that the existing coated denitration catalyst falls off during use and thus affects the service life of the catalyst

Method used

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  • Preparation method of coating type denitration catalyst taking modified honeycomb activated carbon as carrier and prepared catalyst

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] A method for preparing a coated denitration catalyst with modified honeycomb activated carbon as a carrier, comprising the following steps:

[0032] (1) According to the mass ratio of 100:1:3:2:30, activated carbon powder (specific surface area is 800m 2 / g), barium fluoride, methyl cellulose, polyethylene oxide and deionized water are added to the mixer and mixed evenly to obtain plastic mud, which is added to the filter after aging overnight. The wet green body is obtained by extruding in the extruder of the mesh and honeycomb mold, the extrusion pressure is 3MPa, the number of mold holes is 50 mesh, the wet green body is dried at 80°C to constant weight, and calcined under the protection of inert gas. The calcination temperature is 600°C, and the calcination time is 5h to obtain a solid acid-modified honeycomb activated carbon carrier;

[0033] (2) According to the mass ratio of 89:5:6, titanium dioxide, vanadium pentoxide and molybdenum trioxide are mixed, and the ...

Embodiment 2

[0036] A method for preparing a coated denitration catalyst with modified honeycomb activated carbon as a carrier, comprising the following steps:

[0037] (1) According to the mass ratio of 100:3:3:2:30, activated carbon powder (specific surface area is 800m 2 / g), barium fluoride, methyl cellulose, polyethylene oxide and deionized water are added to the mixer and mixed evenly to obtain plastic mud, which is added to the filter after aging overnight. The wet green body is obtained by extruding in the extruder of the mesh and honeycomb mold, the extrusion pressure is 3MPa, the number of mold holes is 50 mesh, the wet green body is dried at 80°C to constant weight, and calcined under the protection of inert gas. The calcination temperature is 600°C, and the calcination time is 5h to obtain a solid acid-modified honeycomb activated carbon carrier;

[0038] (2) According to the mass ratio of 84:10:6, titanium dioxide, vanadium pentoxide and molybdenum trioxide are mixed, and the ...

Embodiment 3

[0041] A method for preparing a coated denitration catalyst with modified honeycomb activated carbon as a carrier, comprising the following steps:

[0042] (1) According to the mass ratio of 100:5:3:2:30, activated carbon powder (specific surface area is 800m 2 / g), barium fluoride, methyl cellulose, polyethylene oxide and deionized water are added to the mixer and mixed evenly to obtain plastic mud, which is added to the filter after aging overnight. The wet green body is obtained by extruding in the extruder of the mesh and honeycomb mold, the extrusion pressure is 3MPa, the number of mold holes is 50 mesh, the wet green body is dried at 80°C to constant weight, and calcined under the protection of inert gas. The calcination temperature is 600°C, and the calcination time is 5h to obtain a solid acid-modified honeycomb activated carbon carrier;

[0043] (2) According to the mass ratio of 79:15:6, titanium dioxide, vanadium pentoxide and molybdenum trioxide are mixed, and the...

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Abstract

The invention discloses a preparation method of a coating type denitration catalyst taking modified honeycomb activated carbon as a carrier, which comprises the following steps: taking solid acid, activated carbon powder and a binder as raw materials, mixing, extruding, drying and carrying out anaerobic sintering to obtain modified activated carbon honeycomb ceramic; vanadium pentoxide, titanium dioxide, molybdenum trioxide powder and acidic aluminum sol are mixed and pulped, nitric acid is added to adjust the pH value, and coating slurry is obtained; and uniformly coating the surface of the modified activated carbon honeycomb ceramic with the coating slurry through an impregnation method. The invention also provides the catalyst prepared by the preparation method. The activated carbon honeycomb carrier is subjected to solid acid modification, so that the activated carbon honeycomb carrier has good surface acidity, then the acidic coating slurry containing the active substance is loaded on the activated carbon honeycomb carrier, and the solid acid modified honeycomb activated carbon and the acidic coating slurry have excellent chemical bonding ability; the coating slurry and the activated carbon carrier are combined more firmly, and the service life of the catalyst is prolonged.

Description

technical field [0001] The invention relates to the field of environmental protection technology, in particular to a preparation method of a coated denitration catalyst with modified honeycomb activated carbon as a carrier and the prepared catalyst. Background technique [0002] With the rapid development of modern industry, environmental problems are becoming more and more serious. Especially due to the increase of nitrogen oxide (NOx) emission, it has caused serious damage to the human atmospheric environment and ecology. Therefore, the emission control of nitrogen oxides is one of the most urgent and necessary tasks in the field of air pollution control in my country. Because the development of NOx control technology in my country is late and not comprehensive enough, the problem of air pollution is still the focus and unresolved problem. Therefore, in recent years, the country has added the "denitrification" index to the pollutant emission control requirements, strictl...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J27/135B01J23/28B01J35/04B01D53/86B01D53/56
Inventor 赵羽蒯贇王光应
Owner ANHUI YUANCHEN ENVIRONMENTAL PROTECTION SCI & TECH