Antibacterial water inlet pipe and processing technology thereof

A processing technology, water inlet pipe technology, applied in coating and other directions, can solve the problems of PPR water pipes not having antibacterial properties, affecting the service life of PPR water pipes, bacteria breeding and fouling, etc., to increase anti-aging ability, inhibit R water pipe damage, increase Antibacterial effect

Active Publication Date: 2022-04-15
WUXI JINHUA YIYUAN TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in ordinary PPR water pipes, most of them are in the α-crystal form, resulting in poor toughness, poor hoop strength, and weak impact resistance, which limits its application.
[0003] On the other hand, PPR water pipes are usually not antibacterial, causing bacterial growth and dirt deposits
At the same time, most of the PPR water pipes are polypropylene chains, and the tertiary carbon atoms are easier to depolymerize than other polyolefins, causing embrittlement problems, so it is necessary to add toughening agents, antioxidants, antibacterial agents and other substances; however, water pipes When used in harsh environments such as hot water, the added small molecular substances will migrate, dissolve, and be eluted; and the chlorine plasma in the water will corrode the pipe, which will aggravate the degradation of the water pipe, thus affecting the service life of the PPR water pipe.

Method used

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  • Antibacterial water inlet pipe and processing technology thereof
  • Antibacterial water inlet pipe and processing technology thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Step 1: Preparation of raw materials: (1) Ultrasonic dispersion of titanium dioxide nanoparticles in ethanol solution, adding vinyl silane coupling agent, acid to adjust pH=5.3, stirring evenly; set temperature at 70°C, react for 6 hours to obtain ethylene base titanium dioxide; disperse it in DMF, add 2,2'-azobis(2-amidinopropane) dihydrochloride and cysteamine hydrochloride in sequence, and set the temperature at 70°C to react for 24 hour, cool, add 1M sodium hydroxide solution, wash, filter and dry to obtain cysteamine / titanium dioxide; mix it with maleic anhydride-modified polypropylene at a mass ratio of 1:1, and reflux in toluene solution for 24 , obtain polypropylene / cysteamine / titanium dioxide. (2) Wash and dry the grape seed meal, grind and sieve; use ethanol with a concentration of 30%, at a solid-liquid ratio of 1:25, set the temperature at 40°C for ultrasonic extraction for 55 minutes, and the ultrasonic frequency is 45KHz; solid-liquid separation, Freeze-d...

Embodiment 2

[0032]Step 1: Preparation of raw materials: (1) Ultrasonic dispersion of titanium dioxide nanoparticles in ethanol solution, adding vinyl silane coupling agent, adjusting the pH to 5.2 with acid, stirring evenly; setting the temperature at 72°C, and reacting for 4 hours to obtain ethylene base titanium dioxide; disperse it in DMF, add 2,2'-azobis(2-amidinopropane) dihydrochloride and cysteamine hydrochloride in sequence, and set the temperature at 68°C to react for 20 hour, cooling, adding 1M sodium hydroxide solution, washing, filtering and drying to obtain cysteamine / titanium dioxide; mix it with maleic anhydride-modified polypropylene at a mass ratio of 1:1, and reflux in toluene solution for 20 hours to obtain polypropylene / cysteamine / titanium dioxide. (2) Wash and dry the grape seed meal, grind and sieve; use ethanol with a concentration of 30%, at a solid-liquid ratio of 1:22, set the temperature at 42°C for ultrasonic extraction for 50-60 minutes, and the ultrasonic fre...

Embodiment 3

[0037] Step 1: Preparation of raw materials: (1) Ultrasonic dispersion of titanium dioxide nanoparticles in ethanol solution, adding vinyl silane coupling agent, acid to adjust pH = 5.6, stirring evenly; set the temperature at 78 ° C, react for 8 hours to obtain ethylene base titanium dioxide; disperse it in DMF, add 2,2'-azobis(2-amidinopropane) dihydrochloride and cysteamine hydrochloride in sequence, and set the temperature at 75°C to react for 24 hour, cool, add 1M sodium hydroxide solution, wash, filter and dry to obtain cysteamine / titanium dioxide; mix it with maleic anhydride-modified polypropylene at a mass ratio of 1:1, and reflux in toluene solution for 24 hours to obtain polypropylene / cysteamine / titanium dioxide. (2) Wash and dry the grape seed meal, grind and sieve; use ethanol with a concentration of 30%, at a solid-to-liquid ratio of 1:25, set a temperature of 45°C for ultrasonic extraction for 60 minutes, and an ultrasonic frequency of 45KHz; solid-liquid separa...

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Abstract

The invention discloses an antibacterial water inlet pipe and a processing technology thereof. Comprising the following steps: step 1, mixing polypropylene random copolymer, polypropylene / cysteamine / titanium dioxide, a lubricant and an antioxidant, and heating and melting; a double-screw extruder is used, a mandrel and a mold are arranged to rotate in the same direction at the same rotating speed, extrusion forming is conducted, and a water inlet pipe A is obtained; and 2, the inner wall of the water inlet pipe A is washed with isopropanol, the water inlet pipe is preheated, an organic silicon resin solution is rotationally sprayed to the inner wall, curing is conducted, and the antibacterial water inlet pipe is obtained. The preparation method has the beneficial effects that polypropylene / cysteamine / titanium dioxide is prepared by using multiple reactions, the dispersion of titanium dioxide nanoparticles is enhanced, and the antibacterial property is improved; meanwhile, polypropylene / cysteamine / titanium dioxide and a grape seed meal extract are combined, and a double-screw same-speed rotary extrusion process is adopted, so that the crystallinity of beta-phase crystals of the antibacterial water inlet pipe is effectively improved, and the toughness and the impact strength are improved.

Description

technical field [0001] The invention relates to the technical field of water inlet pipes, in particular to an antibacterial water inlet pipe and its processing technology. Background technique [0002] At present, in common water pipes, polypropylene random copolymer (PPR) is the most commonly used due to its advantages of light weight, non-toxicity, and pressure resistance. It is a copolymer in which ethylene molecules are randomly grafted along the polypropylene chain, and the resulting crystal forms have different mechanical properties. Since the water pipe is used in the process of water delivery, the water pipe needs to bear a large hoop stress. However, in ordinary PPR water pipes, most of them are in the α-crystal form, which leads to poor toughness, poor hoop strength, and weak impact resistance, which limits its application. [0003] On the other hand, PPR water pipes are usually not antibacterial, causing bacterial growth and dirt deposits. At the same time, mos...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/14C08L87/00C08K5/00C08J7/04C08G83/00
CPCC08L23/14C08J7/0427C08G83/001C08J2323/14C08J2483/04C08L2205/242C08L2203/18C08L87/005C08K5/005
Inventor 顾年东陆晓佳
Owner WUXI JINHUA YIYUAN TECH CO LTD
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