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Method for resource utilization of sludge biochar

A technology of recycling and biochar, applied in chemical instruments and methods, cement mixing devices, manufacturing tools, etc., can solve the problems of complex biochar preparation process, poor applicability, and high cost, and achieve good economic and environmental benefits , Low product cost and simple process

Active Publication Date: 2022-04-26
INST OF URBAN ENVIRONMENT CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The above methods all need to remove some heavy metals from the sludge by leaching, then plate and frame filter, then add fly ash or blast furnace slag, mix and granulate, dry, and then crack at high temperature for 3 to 4 hours to obtain sludge biochar. This sludge biochar The preparation process is complicated and the applicability is poor; moreover, waste fabrics need to be added in the brick making process, which makes the whole process cost high and the application is limited

Method used

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  • Method for resource utilization of sludge biochar
  • Method for resource utilization of sludge biochar
  • Method for resource utilization of sludge biochar

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] The biochar used in this test was taken from the biochar formed by pyrolysis of sludge from a sewage treatment plant in Xiamen City at 600 °C, and was used as brick-making material after being crushed and screened; standard 42.5 grade ordinary Portland cement was used; Ordinary fine-grained river sand; water for ingredients is ordinary tap water.

[0034] Fine grinding: finely grind the above-mentioned biochar to <100 mesh and magnetically separate to obtain ferromagnetic material and biochar micropowder without iron; among them, the ferromagnetic material is used as smelting raw material or chemical raw material.

[0035] Preparation of the primary mixture: Dry premix the above iron-free biochar micropowder with cement and early-strength agent to obtain the pre-mixture; the early-strength agent is calcium chloride, and its addition ratio is 1%.

[0036] Secondary mixture preparation: add river sand to the premixed material obtained above, and perform secondary mixing t...

Embodiment 2

[0049] Embodiment 2: Existing speciation analysis of heavy metals in biochar micropowder and solid brick

[0050] Existing forms of heavy metals are closely related to their hazards. At present, the BCR continuous extraction method is the main test method for the form of heavy metals in biochar and its products. Among them, the F1 state is a weak acid extraction state, which mainly refers to the existence of adsorption on the particle surface or in the form of carbonate binding, and is easily affected by the type of ions in the water body and the adsorption and desorption; the F2 state is a reducible state , mainly refers to the form combined with iron-manganese oxides, which is relatively unstable under anoxic or anaerobic conditions; F3 state is an oxidizable state, mainly referring to heavy metals combined with organic matter, sulfide, etc. Form, which can be degraded under certain conditions and thus be used by organisms; F4 state is a residue state, mainly referring to t...

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Abstract

The invention discloses a method for resource utilization of sludge biochar. Comprising the following steps: performing fine grinding and magnetic separation on biochar prepared from sludge to obtain a ferromagnetic material and biochar micro powder without iron; wherein the charcoal micro powder, the cement and the early strength agent are subjected to dry premixing to obtain a premix; then adding river sand and mixing to obtain a secondary mixture; uniformly dispersing a water reducing agent and water in a stirrer, and adding the secondary mixture to obtain a third mixture; feeding into a mold for pressure forming; placing the mold in a steam curing box, cooling to room temperature after steam curing, and removing the mold after the green body is solidified; and curing at normal temperature to obtain concrete solid bricks, building blocks or thermal insulation materials. According to the method, harmful heavy metal in the sludge is solidified, secondary pollution to the environment is avoided, the concrete solid brick is directly prepared, resource utilization and large-scale treatment of the sludge are achieved, and the method is particularly suitable for treatment of biochar obtained through pyrolysis of the sludge containing the heavy metal. The method is simple in process and low in cost, and has good economic and environmental benefits.

Description

technical field [0001] The invention relates to the field of comprehensive utilization of solid waste resources, in particular to a method for resource utilization of sludge biochar. Background technique [0002] Although sludge contains potentially useful organic matter and nutrients such as N, P, and K, the direct entry of salt, pathogenic microorganisms, organic polymers, and especially heavy metals into the environment will cause air, water, and soil pollution. The study found that the larger the city, the higher the concentration of heavy metals in the sludge. Heavy metals in sludge in my country have obvious regional characteristics. For example, coal-fired heating is more common in the north, so the content of As and Hg is higher; the distribution of non-ferrous metal mining areas in the south is concentrated and the degree of human development is higher, so the content of Cr, Ni, Cu, Zn, Cd, and Pb is higher. At present, the problem of high heavy metal content in s...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B28/04C04B28/06C04B14/02B28B3/00B28B11/24B28C5/00
CPCC04B28/04C04B28/06C04B14/022B28B3/00B28B11/245B28C5/003C04B2201/20C04B2201/50C04B22/124C04B14/068C04B2103/302C04B22/002Y02W30/91
Inventor 余广炜王玉
Owner INST OF URBAN ENVIRONMENT CHINESE ACAD OF SCI
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