Hybrid acrylate AB glue and preparation method thereof

A technology of acrylate and methacrylic acid, applied in the field of hybrid acrylate AB glue and its preparation, can solve the problems of poor fatigue resistance and creep resistance, can not meet the needs of use, poor adhesion and adhesion, and improve fatigue resistance. and creep resistance, good flexibility and adhesion, and the effect of reducing volatility

Active Publication Date: 2022-06-17
GLEIHOW NEW MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the traditional acrylate AB glue on the market has the characteristics of easy operation, fast curing at room temperature, and high bonding strength, but it also has poor toughness, poor fatigue resistance and creep resistance, and is not suitable for new energy vehicles such as ABS and ASA. The shortcomings of engineering plastics, such as poor adhesion, cannot meet the needs of use

Method used

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  • Hybrid acrylate AB glue and preparation method thereof
  • Hybrid acrylate AB glue and preparation method thereof
  • Hybrid acrylate AB glue and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] A hybrid acrylate AB glue, measured by mass percentage, comprises the following components:

[0033] Component A:

[0034]

[0035] Component B:

[0036]

[0037]

Embodiment 2

[0039] A hybrid acrylate AB glue, measured by mass percentage, comprises the following components:

[0040] Component A:

[0041]

[0042] Component B:

[0043]

[0044] The preparation method of the hybrid acrylate AB glue of embodiment 1 and embodiment 2 specifically comprises the following steps:

[0045] Preparation of component A:

[0046] a, the preparation of modified tackifying alkyd resin (almond oil alkyd tackifying resin): weigh each raw material according to mass percentage, add glycerin in almond oil, stir and be warming up to 220 ℃, carry out alcoholysis reaction 1~ After 2 hours, the temperature was lowered to 160° C., maleic anhydride and nadic anhydride were added, the temperature was raised to 190° C. with stirring, and an alkyd polycondensation reaction was carried out for 5 to 6 hours. After cooling, the almond oil modified tackifying resin was obtained;

[0047] b, weigh each raw material according to the mass percentage, drop pentaerythritol tria...

Embodiment 3

[0053] A hybrid acrylate AB glue, measured by mass percentage, comprises the following components:

[0054] Component A:

[0055]

[0056]

[0057] Component B:

[0058]

[0059] The preparation method of the hybrid acrylate AB glue of embodiment 3, the concrete steps of this method are:

[0060] Preparation of Component A:

[0061] a, the preparation of modified tackifying alkyd resin (almond oil alkyd tackifying resin): weigh each raw material according to mass percentage, add glycerin in almond oil, stir and be warming up to 220 ℃, carry out alcoholysis reaction 1~ After 2 hours, the temperature was lowered to 160° C., maleic anhydride and nadic anhydride were added, the temperature was raised to 190° C. with stirring, and an alkyd polycondensation reaction was carried out for 5 to 6 hours. After cooling, the almond oil alkyd tackifying resin was obtained;

[0062] B, each raw material is weighed according to the mass percentage, polyethylene glycol dimethacryla...

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Abstract

The invention discloses a hybrid acrylate AB adhesive which comprises the following components in percentage by mass: a component A: 50.0%-65.0% of a polymeric monomer, 5.0%-10.0% of a functional monomer, 5.0%-10.0% of modified tackified alkyd resin, 10.0%-25.0% of reinforced resin, 10.0%-20.0% of toughened rubber, 2.0%-6.0% of a reducing agent and 0.1%-2.0% of a stabilizer; and the component B comprises the following components in percentage by weight: 55.0%-65.0% of a polymeric monomer, 2.0%-8.0% of a functional monomer, 1.0%-5.0% of methacrylic acid wax, 20.0%-35.0% of reinforced resin, 5.0%-15.0% of toughened rubber, 1.0%-6.0% of an oxidant and 0.5%-5.0% of a stabilizer. The invention also discloses a preparation method of the hybrid acrylate AB adhesive. Through compounding of the raw materials, the prepared hybrid acrylate AB glue has excellent adhesion to engineering plastics such as ABS, ASA and the like, has the characteristics of low odor, good curing debonding property, strong adhesive force, high toughness, fatigue resistance, creep resistance, good heat resistance, good weather resistance and wide range of bonding materials, and can meet the bonding requirements of new energy automobile body materials.

Description

technical field [0001] The invention relates to the technical field of adhesives, in particular to a hybrid acrylate AB adhesive and a preparation method thereof. Background technique [0002] In recent years, energy problems and environmental pollution problems have become increasingly serious, and the development of new energy vehicles has become an important strategy to implement the national requirements for energy conservation and emission reduction, and the development of a low-carbon economy. Different from traditional automobiles, new energy automobile body materials are more inclined to lightweight materials, such as high-strength steel, aluminum alloy, magnesium alloy, carbon fiber and various engineering plastics. At present, the traditional acrylate AB glue on the market has the characteristics of easy operation, fast curing at room temperature and high bonding strength, but it also has poor toughness, fatigue resistance and creep resistance, and is not suitable ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J155/02C09J167/08C09J109/02C09J191/06
CPCC09J155/02C08L67/08C08L9/02C08L91/06Y02E60/10
Inventor 杨猛王德鹏田学深夏令明匡广际王波
Owner GLEIHOW NEW MATERIALS CO LTD
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