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Fluorine-containing auxiliary agent and product thereof

A technology of additives and antioxidants, used in the field of fluorine-containing additives and their products, can solve problems such as adverse effects on the service life of polymer materials, changes in mechanical properties of materials, molecular fractures, yellowing, etc., to avoid long-term fading, The effect of reducing the severity of yellowing and promoting dispersion

Pending Publication Date: 2022-06-21
上海齐润新材料有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] As commonly used materials in daily life, polymer materials can be used in various fields such as daily chemicals, medicine, building materials, etc. PP, PE, PVC, PLA, PB, mPE, etc. are common thermoplastic polymers, which can be extruded by screw, heated Processing and preparation in various ways such as pressing, but pure polymer materials are prone to problems such as extrusion and cracking during processing
[0003] And for thermoplastic polymers, especially those with low melt index, they are prone to molecular fracture and yellowing when exposed to light, heat, pH or long-term storage. In order to improve the anti-yellowing performance, anti-yellowing agents can be added etc., but with the prolongation of use or storage time, there will still be problems such as yellowing
[0004] In addition, during long-term use or storage, the mechanical properties of materials may also change, resulting in creep and cracking, etc., which will adversely affect the service life of polymer materials.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0046] The chitosan-grafted acrylate of the present invention can be prepared by polymerizing chitosan and acrylate under the action of an initiator. In one embodiment, the preparation method of the chitosan-grafted acrylate comprises: Chitosan is added to water, heated to 40-50° C., and the mixture of acrylate and initiator is added dropwise, reacted for 5-7 hours, washed and dried to obtain the chitosan-grafted acrylate. The present invention does not specifically limit the initiator, which can be exemplified as potassium dipiodate copper (III), potassium dipiodate silver (II), potassium dihydroxydiperiodic copper (III), In one embodiment, the initiator accounts for 0.1-3 wt% of the acrylate.

[0047] Further preferably, the acrylates of the present invention also include fluorine-containing alkyl acrylates. More preferably, the molar ratio of the alkyl acrylate and the fluorine-containing alkyl acrylate in the present invention is (3-5):1, which can be exemplified as 3:1, ...

Embodiment 1

[0055] This example provides a fluorine-containing auxiliary agent. The preparation raw materials of the fluorine-containing auxiliary agent include a fluorine-containing mixture, an antioxidant, an acid absorbing agent, a pigment, and a chitosan-grafted acrylate in a weight ratio of 500:5000:1000 : 500:1500, the antioxidant is antioxidant 1010 and antioxidant 168 with a weight ratio of 1.5:1, the acid absorbing agent is calcium stearate, and the pigment is a weight ratio of 1:1 Ultramarine blue and phthalocyanine blue, the raw materials for the preparation of the chitosan-grafted acrylate include chitosan and acrylate in a weight ratio of 1:4, and the acrylate includes methyl acrylate and acrylic acid in a molar ratio of 4:1 Trifluoroethyl ester; the preparation method of the chitosan-grafted acrylate comprises: adding chitosan into water, heating to 45° C., dropping a mixture of acrylate and an initiator, reacting for 6 hours, washing and drying to obtain The chitosan is gra...

Embodiment 2

[0059] This example provides a fluorine-containing auxiliary agent. The preparation raw materials of the fluorine-containing auxiliary agent include a fluorine-containing mixture, an antioxidant, an acid absorbing agent, a pigment, and a chitosan-grafted acrylate in a weight ratio of 500:5000:1000 : 500:1500, the antioxidant is antioxidant 1010 and antioxidant 168 with a weight ratio of 1.5:1, the acid absorbing agent is calcium stearate, and the pigment is a weight ratio of 1:1 Ultramarine blue and phthalocyanine blue, the raw materials for the preparation of the chitosan-grafted acrylate include chitosan and acrylate in a weight ratio of 1:4, and the acrylate includes methyl acrylate and acrylic acid in a molar ratio of 4:1 Trifluoroethyl ester; the preparation method of the chitosan-grafted acrylate comprises: adding chitosan into water, heating to 45° C., dropping a mixture of acrylate and an initiator, reacting for 6 hours, washing and drying to obtain The chitosan is gra...

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PUM

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Abstract

The invention relates to the technical field of polymer processing, in particular to a fluorine-containing auxiliary and a product thereof. The fluorine-containing auxiliary agent is prepared from a fluorine-containing mixture and an anti-yellowing agent; the fluorine-containing mixture is added, in the polymer processing process, the lubricating effect is achieved, melt fracture is reduced, so that the brightness and smoothness of a product are improved, the fluorine-containing mixture and the anti-yellowing agent jointly act, surface performance is improved, meanwhile, migration of the anti-yellowing agent to the surface of an object is reduced, and the anti-yellowing performance is more sufficiently achieved; the fluorine-containing auxiliary agent is obtained by adding chitosan grafted acrylic ester and carrying out melt blending with a fluorine-containing mixture and an anti-yellowing agent, so that dispersion is promoted, serious yellowing and even breakage of partial areas are reduced, and long-term color fading is avoided. When the fluorine-containing auxiliary agent provided by the invention is used for processing macromolecules, especially macromolecules with low melt index, the consumption of electric energy can be reduced, the production speed can be increased, and the prepared product has high additional value.

Description

technical field [0001] The present invention relates to the technical field of polymer processing, and more particularly, to a fluorine-containing auxiliary and its products. Background technique [0002] As a commonly used material in daily life, polymer materials can be used in various fields such as daily chemicals, medicine, building materials, etc. PP, PE, PVC, PLA, PB, mPE, etc. are all common thermoplastic polymers. However, pure polymer materials are prone to problems such as extrusion and cracking during processing. [0003] And for thermoplastic polymers, especially polymers with low melt index, molecular breakage and yellowing are prone to occur during exposure to light, heat, pH or long-term storage. In order to improve the anti-yellowing performance, anti-yellowing agents can be added. However, with the prolongation of use or storage time, there will still be problems such as yellowing. [0004] In addition, during long-term use or storage, the mechanical prop...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L51/02C08K5/134C08K5/526C08K5/098C08K3/013C08K5/00C08L23/12
CPCC08L51/02C08K5/1345C08K5/526C08K5/098C08K3/013C08K3/34C08K5/0041C08K5/0091C08L23/12
Inventor 曹子卿曹林
Owner 上海齐润新材料有限公司
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