Fluorine-containing auxiliary agent and product thereof
A technology of additives and antioxidants, used in the field of fluorine-containing additives and their products, can solve problems such as adverse effects on the service life of polymer materials, changes in mechanical properties of materials, molecular fractures, yellowing, etc., to avoid long-term fading, The effect of reducing the severity of yellowing and promoting dispersion
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[0046] The chitosan-grafted acrylate of the present invention can be prepared by polymerizing chitosan and acrylate under the action of an initiator. In one embodiment, the preparation method of the chitosan-grafted acrylate comprises: Chitosan is added to water, heated to 40-50° C., and the mixture of acrylate and initiator is added dropwise, reacted for 5-7 hours, washed and dried to obtain the chitosan-grafted acrylate. The present invention does not specifically limit the initiator, which can be exemplified as potassium dipiodate copper (III), potassium dipiodate silver (II), potassium dihydroxydiperiodic copper (III), In one embodiment, the initiator accounts for 0.1-3 wt% of the acrylate.
[0047] Further preferably, the acrylates of the present invention also include fluorine-containing alkyl acrylates. More preferably, the molar ratio of the alkyl acrylate and the fluorine-containing alkyl acrylate in the present invention is (3-5):1, which can be exemplified as 3:1, ...
Embodiment 1
[0055] This example provides a fluorine-containing auxiliary agent. The preparation raw materials of the fluorine-containing auxiliary agent include a fluorine-containing mixture, an antioxidant, an acid absorbing agent, a pigment, and a chitosan-grafted acrylate in a weight ratio of 500:5000:1000 : 500:1500, the antioxidant is antioxidant 1010 and antioxidant 168 with a weight ratio of 1.5:1, the acid absorbing agent is calcium stearate, and the pigment is a weight ratio of 1:1 Ultramarine blue and phthalocyanine blue, the raw materials for the preparation of the chitosan-grafted acrylate include chitosan and acrylate in a weight ratio of 1:4, and the acrylate includes methyl acrylate and acrylic acid in a molar ratio of 4:1 Trifluoroethyl ester; the preparation method of the chitosan-grafted acrylate comprises: adding chitosan into water, heating to 45° C., dropping a mixture of acrylate and an initiator, reacting for 6 hours, washing and drying to obtain The chitosan is gra...
Embodiment 2
[0059] This example provides a fluorine-containing auxiliary agent. The preparation raw materials of the fluorine-containing auxiliary agent include a fluorine-containing mixture, an antioxidant, an acid absorbing agent, a pigment, and a chitosan-grafted acrylate in a weight ratio of 500:5000:1000 : 500:1500, the antioxidant is antioxidant 1010 and antioxidant 168 with a weight ratio of 1.5:1, the acid absorbing agent is calcium stearate, and the pigment is a weight ratio of 1:1 Ultramarine blue and phthalocyanine blue, the raw materials for the preparation of the chitosan-grafted acrylate include chitosan and acrylate in a weight ratio of 1:4, and the acrylate includes methyl acrylate and acrylic acid in a molar ratio of 4:1 Trifluoroethyl ester; the preparation method of the chitosan-grafted acrylate comprises: adding chitosan into water, heating to 45° C., dropping a mixture of acrylate and an initiator, reacting for 6 hours, washing and drying to obtain The chitosan is gra...
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