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Coated controlled-release fertilizer and preparation method thereof

A technology of controlled-release fertilizers and coating materials, applied in the direction of layered/coated fertilizers, fertilizer mixtures, fertilization devices, etc., can solve the problems that have not been found in the research and reports of nano-calcium carbonate modification, and have not been reported in patents and literature , uneven dispersion and other problems, to achieve the effect of improving the quality and effect of the coating, improving the mechanical properties, and simplifying the production process

Active Publication Date: 2022-07-12
四川省农业科学院农业资源与环境研究所
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] Due to its high specific surface area and lipophilic and hydrophobic surface, nano-calcium carbonate is prone to agglomeration and flocculation in aqueous solution, and the dispersion is uneven. As a result, no one has thought of using nano-carbonic acid in the disclosed prior art solutions related to coated controlled-release fertilizers. Calcium Modification of Water-Based Polyacrylate
[0010] The inventor has not yet found that in the prior art, the research and reports about using nano-calcium carbonate for water-based polyacrylate emulsion modification, the patent and literature data of making coated fertilizers with nano-calcium carbonate-modified water-based polyacrylate are also Not reported

Method used

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  • Coated controlled-release fertilizer and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] This example is a comparative example, and this example describes the preparation method of unmodified water-based polyacrylate-coated urea, and the coated controlled-release urea prepared by this method. The specific steps of the preparation method of coated controlled-release urea in the present embodiment are as follows:

[0051] The selection of step a, coating mother liquor:

[0052] In the laboratory, 100 g of water-based polymer polyacrylate emulsion was prepared by water-based technology, and its solid content was (49±1)%.

[0053] The preparation of step b, coating liquid:

[0054] The same amount of distilled water as the coating mother liquor was slowly added dropwise to the stirring coating mother liquor, and the stirring was continued for 15 min after all the drops were added. The coating solution prepared by mixing should be prepared and used immediately. The storage temperature should be 5℃~25℃, and the storage time should not be longer than 4h.

[005...

Embodiment 2

[0066] This example describes a method for preparing coated urea based on a 1% nano-calcium carbonate-modified water-based polyacrylate emulsion, and a coated controlled-release fertilizer prepared by this method. The specific steps of the preparation method of the coated controlled-release fertilizer in the present embodiment are as follows:

[0067] The selection of step a, coating mother liquor:

[0068] In the laboratory, 100 g of water-based polymer polyacrylate emulsion was prepared by water-based technology, and its solid content was (49±1)%.

[0069] The preparation of step b, coating liquid:

[0070] Add 100 g of distilled water to 0.5 g of nano-calcium carbonate, stir for 15 min, and then ultrasonicate for 30 min, slowly add dropwise to the stirring coating mother liquor, and continue to stir for 15 min after all the dropwise addition. The coating solution prepared by mixing should be prepared and used immediately. The storage temperature should be 5℃~25℃, and the ...

Embodiment 3

[0081] This example describes a method for preparing coated urea based on a 1% nano-calcium carbonate-modified water-based polyacrylate emulsion dispersed by sodium hexametaphosphate, and a coated controlled-release fertilizer prepared by the method. The specific steps of the preparation method of the coated controlled-release fertilizer in the present embodiment are as follows:

[0082] The selection of step a, coating mother liquor:

[0083] In the laboratory, 100 g of water-based polymer polyacrylate emulsion was prepared by water-based technology, and its solid content was (49±1)%.

[0084] The preparation of step b, coating liquid:

[0085] Add 100 g of distilled water and 0.5 g of sodium hexametaphosphate to 0.5 g of nano-calcium carbonate, then add and stir for 15 min and then ultrasonicate for 30 min. After ultrasonic treatment, slowly drop it into the stirring coating mother liquor, and continue to stir for 15 min after all the dropwise addition. The coating solutio...

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Abstract

The invention discloses a coated controlled-release fertilizer which comprises inner-layer fertilizer core particles and an outer-layer polymer coating material, and the polymer coating material is a nano calcium carbonate modified water-based polyacrylate emulsion solid. The nano calcium carbonate modified water-based polyacrylate emulsion is used as a polymer coating main body, so that the controlled release performance of the fertilizer is obviously improved. A contrast test proves that under the condition that the dosage of a coating material and the dosage of fertilizer core particles are the same and the preparation process is the same, compared with unmodified water-based polyacrylate, the nano calcium carbonate modified water-based polyacrylate has the advantages that the fertilizer accumulative release rate in the same period of the slow-release fertilizer after the coating material is improved is lower, the release speed of the fertilizer is smoother and more uniform, and the slow-release effect is better. The release period can be prolonged to about 1.9 times, and the nutrient requirements of crops with relatively long growth seasons in the whole growth season can be met.

Description

technical field [0001] The invention belongs to the field of fertilizers, and relates to a controlled-release fertilizer and a preparation method of the controlled-release fertilizer. Background technique [0002] As the "food" of food, chemical fertilizers have made important contributions to ensuring global food security. my country's 9% of the world's arable land consumes 1 / 3 of the world's fertilizer, and the amount of fertilizer applied per unit area is three times the world average. The low utilization rate of chemical fertilizers, especially nitrogen fertilizers, brings environmental, economic and energy pressures. Slow / controlled release fertilizers have attracted worldwide attention due to their advantages of effectively improving nutrient utilization, reducing the harm caused by nutrient loss to the environment, and reducing fertilization costs. Among them, polymer-coated fertilizers have become the most promising due to their better controlled release effect. On...

Claims

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Application Information

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IPC IPC(8): C05G3/40C05G3/90C05G5/30
CPCC05C9/00C05B7/00C05G3/40C05G3/90C05G5/37C05D3/02Y02P60/21C05C9/005
Inventor 周子军曾祥忠郭松陈琨喻华秦鱼生何明江上官宇先代雨柔袁婉珍
Owner 四川省农业科学院农业资源与环境研究所