Method for increasing dispersiveness of inorganic oxide powder in organic medium
An inorganic oxide and dispersive technology, applied in the treatment of dyed polymer organic compounds, etc., can solve the problems of high cost of organic solvent recovery and treatment, and achieve the effect of improving compatibility
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Embodiment 1
[0029] Put 200g of titanium dioxide powder (DuPont R902 type) in a 5000ml plastic beaker, add 3000ml of deionized water and 8g of sodium dodecylsulfonate, and disperse for 0.5hr at a high-speed disperser at 1000r / min. Transfer the dispersed slurry into a device equipped with stirring, heating and nitrogen protection, add 60 g of methyl methacrylate, stir for 15 minutes and then raise the temperature to 100°C. An aqueous solution containing 3 g of potassium persulfate was added to initiate polymerization, and the temperature was kept at 100° C. for 2 hours. The discharge was suction filtered and dried at 70°C for 5hr. The dispersibility test results of the powder after drying are shown in Table 1. SEM photo see figure 1 with figure 2 .
Embodiment 2
[0031] Put 200g of ordinary iron oxide yellow (type 313 of Shanghai Yipin International Pigment Co., Ltd.) into a 5000ml plastic beaker, add 3000ml of deionized water and 15g of sodium dodecylbenzenesulfonate, and disperse for 0.5hr at a high-speed disperser at 1000r / min. Transfer the dispersed slurry into a device with stirring, heating and nitrogen protection, add 45g of butyl methacrylate and 30g of methacrylic acid in batches, stir for 15min and then raise the temperature to 40°C. An aqueous solution containing 3 g of potassium persulfate was added to initiate polymerization, and the mixture was kept at 50° C. for 5 hr. The discharge was suction filtered and dried at 60°C for 5hr. The dispersibility test results of the dried powder are shown in Table 1, and the heat resistance properties are shown in Table 2. SEM photo see image 3 with Figure 4 .
Embodiment 3
[0033] Put 150g of ordinary iron oxide red (Shanghai Yipin International Pigment Co., Ltd. 130 type) in a 5000ml plastic beaker, add 3000ml of deionized water and 7g of ammonium lauryl sulfate, and disperse for 0.5hr at a high-speed disperser at 1000r / min. Transfer the dispersed slurry into a device equipped with stirring, heating and nitrogen protection, add 10 g of acrylic acid, 20 g of ethyl acrylate and 25 g of methyl acrylate in batches, stir for 15 minutes and then raise the temperature to 60°C. An aqueous solution containing 3 g of potassium persulfate was added to initiate polymerization, and the mixture was kept at 60° C. for 4 hours. The discharge was suction filtered and dried at 70°C for 5hr. The dispersibility test results of the powder after drying are shown in Table 1. SEM photo see Figure 5 with Image 6 .
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