Method for producing iron oxide black
A technology of iron oxide black and production method, applied in the direction of fibrous fillers, etc., can solve the problems of inconsistent shape of primary particles of iron black products, low color saturation and tinting strength, large particle size, etc., and achieves strong tinting strength, The effect of fine and uniform particle size and high purity
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Embodiment 1
[0022] The method for producing blue-phase iron oxide black pigment in this example is:
[0023] 1. Put the waste residue containing ferrous sulfate discharged from the production of titanium dioxide into the dissolution tank, heat it with steam, and after fully dissolving, let it settle and take the upper clear liquid to make ferrous sulfate with a concentration of 45% Aqueous solution 2000Kg, put into the reaction vessel;
[0024] 2. While stirring, add about 865Kg of 30% liquid caustic soda as a neutralizing agent into the ferrous sulfate aqueous solution to generate ferrous hydroxide, and the pH value of the system is 8.5;
[0025] 3. Pump the prepared ferrous hydroxide into a 5000L reaction tank, use steam to control the temperature at 95°C, the pH value at about 8.5, and the flow rate is 0.3m while stirring. 3 / min of air, the oxidation reaction produces iron black;
[0026] The reaction formula of above-mentioned 2,3 steps is:
[0027]
[0028]
[0029]...
Embodiment 2 Embodiment 3
[0036] Example 2 Example 3 Example 4
[0037] Ferrous salt solution (concentration) 30% 40% 50%
[0038] Neutralizer Solid caustic 42% liquid caustic 30% liquid caustic
[0039] PH value after neutralization 7.5 8 9
[0040] Oxidation reaction temperature 90 95 100
[0041] Oxidation reaction pH value 7.5 8 9
[0042] The product that embodiment 2-4 produces all can obtain substantially identical effect with embodiment 1.
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