Method for processing cobalt copper alloy

A cobalt-copper alloy and process technology, which is applied in the field of cobalt-copper alloy treatment by wet method, can solve the problems affecting the recovery rate of cobalt and copper, the leaching process efficiency is not high, and the reaction speed is slow, so as to achieve high leaching operation efficiency and easy control , fast response effect

Inactive Publication Date: 2006-07-12
浙江盈联科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This method is under normal pressure, and reaction speed is slow, and leaching process efficiency is not high, and process flow is long, and production cost is high
[0009] In addition, with the above methods, since a large amount of iron is also leached into the leach solution at the same time, the subsequent iron removal process will lead to the loss of cobalt and copper, which directly affects the recovery rate of cobalt and copper.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] Example 1 Take 1000 grams of cobalt-copper alloy and put it into a ball mill for 90 minutes, and then vibrate mill it for 120 minutes. The average particle size is 47 microns. Take by weighing 80 grams of this alloy, 80 grams of ammonium chloride, 20 grams of ferric chloride, 133 milliliters of 36% hydrochloric acid, add 500 milliliters of water, heat up to 87 degrees, feed air (flow rate is 1.2 liters / minute), under stirring condition The reaction was carried out for 8 hours, and the pH at the end of the reaction was 3.5. Then the slurry is magnetically separated and filtered. 2.6 grams of unreacted residual cobalt-copper alloy were magnetically separated, and the obtained leaching solution contained 26.9 grams / liter of cobalt, 24.8 grams / liter of copper, and 0.06 grams / liter of iron. The leaching slag contains 0.42 grams of cobalt and 0.30 grams of copper. The leaching rate of cobalt was 94.3%, and the leaching rate of copper was 95.2%. The actual yield of cobalt w...

Embodiment 2

[0030] Example 2 Take 1000 grams of cobalt-copper alloy and put it into a ball mill for 90 minutes, and then vibrate mill it for 120 minutes. The average particle size is 47 microns. Weigh 80 grams of the alloy, 50 grams of ammonium chloride, 30 grams of sodium fluoride, 133 milliliters of 36% hydrochloric acid, add 500 milliliters of water, heat up to 87 degrees, feed air (flow rate is 1.2 liters / min), and stir The reaction was carried out for 8 hours, and the pH value at the end of the reaction was 3.5. Then the slurry is magnetically separated and filtered. 2.1 grams of unreacted residual cobalt-copper alloy were magnetically separated, and the obtained leaching solution contained 32.8 grams / liter of cobalt, 27.6 grams / liter of copper, and 0.08 grams / liter of iron. The leaching slag contains 0.31 grams of cobalt and 0.33 grams of copper. The leaching rate of cobalt was 95.8%, and the leaching rate of copper was 95.5%. The actual yield of cobalt was 98.4%, and that of cop...

Embodiment 3

[0031]Example 3 Take 1000 grams of cobalt-copper alloy and put it into a ball mill for 90 minutes, and then vibrate mill it for 120 minutes. The average particle size is 47 microns. Weigh 160 grams of this alloy, 50 grams of ammonium chloride, 30 grams of sodium fluoride, 20 grams of ferric chloride, 266 milliliters of 36% hydrochloric acid, add 500 milliliters of water, heat up to 87 degrees, feed air (flow rate is 1.5 liters / After 6.5 hours of reaction under stirring conditions, slowly add 5% sodium hydroxide solution until the pH value is 4.0, and continue the reaction for 45 minutes. Then the slurry is magnetically separated and filtered. 3.5 grams of unreacted residual cobalt-copper alloy were magnetically separated, and the obtained leaching solution contained 57.2 grams / liter of cobalt, 50.0 grams / liter of copper, and 0.005 grams / liter of iron. The leaching slag contains 0.39 grams of cobalt and 0.77 grams of copper. The leaching rate of cobalt was 96.6%, and the lea...

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Abstract

The invention discloses a method for processing the cobalt copper alloy, which comprises the following steps: 1) machine activating program: sending the cobalt copper alloy to the ball crusher to do cruse milling, sending it to the pipe crusher to do correct grinding, then the cobalt copper alloy powder has high internal energy, surface energy and rate surface area so that it has high reacting activity; 2) extracting process: adding the cobalt copper alloy powder in the reacting extraction groove and adding water and muriatic acid by a certain ratio to heat stir on catalyzed oxidation condition so that the cobalt and copper mental 90%-99% extracting of the cobalt copper alloy enters into the solution; 3) Magnetic separating program: separating the residual cobalt copper alloy of the extracting slip and the slip by the magnetic separator, dosing filter solid-liquid separation to the magnetic separated slip to obtain the solution with cobalt and copper.

Description

technical field [0001] The invention relates to a method for processing cobalt-copper alloy, in particular to a method for processing cobalt-copper alloy by wet method. Background technique [0002] Cobalt copper alloy is an important raw material for the production of cobalt metal and various cobalt products, commonly known as cobalt white alloy or cobalt red alloy or cobalt AB alloy, mainly produced in Africa. Cobalt-copper alloy is produced by reducing and smelting copper oxide cobalt concentrate and cobalt-containing copper slag in electric furnace, generally containing cobalt: 10%-40%, copper: 10%-50%, iron: 5%-50%, nickel: 0.1 %-5%, Manganese: 0.1%-5%. The processing of this alloy raw material is relatively difficult, and the main problems are low yield of cobalt and copper, high cost and long process flow. [0003] At present, the methods for processing cobalt-copper alloy mainly include: [0004] 1. Electrolysis method: Cobalt-copper alloy ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B3/10C22B3/22
CPCY02P10/20
Inventor 陈刚冯德茂应明明
Owner 浙江盈联科技有限公司
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