Method for simultaneous purification of elementary substance mercury and nitric oxides in coal-fired flue gas
A technology for nitrogen oxides and coal-fired flue gas, applied in chemical instruments and methods, separation methods, air quality improvement, etc., can solve the problem of difficulty in finding catalysts that can be used stably for a long time, catalyst poisoning, increasing the complexity of flue gas purification systems Investment cost and other issues, to achieve the effect of good reliability, low one-time investment and simple process flow
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Examples
Embodiment 1
[0023] Preparation of simulated boiler flue gas: Use a quartz tube with a diameter of 20mm and a length of 500mm as the reactor, with a 200mm water jacket cooling device downstream, and use a tubular heating furnace for heating. Use simulated flue gas prepared on site ([NO]=350ppm, [Hg 0 ] = 50μg / m 3 , [SO2]=1000ppm, all the other are air), the air flow of 800ml / min passes through the reactor continuously, and by the total mercury, Hg in the reactor outlet gas 0 , NOx concentration to determine the effect.
[0024] Ammonium chloride solution was prepared with deionized water, and the concentration of ammonium chloride in the solution was 1%. A metering pump is used to spray the mist of the mixed solution into the simulated gas from the inlet of the reaction tube, so that the stoichiometric ratio between the ammonium chloride added to the simulated flue gas and the NO in the flue gas is 0.7:1. When the temperature of the reaction tube is 1000°C and the reaction is stable, th...
Embodiment 2
[0027] Simulated flue gas conditions are the same as in Example 1.
[0028] The chemical additive adopts monochloramine, the main reducing agent adopts urea, utilizes tap water or deionized water to prepare the mixed solution containing 0.2% and 1% of monochloramine solution and urea respectively, make the chemical reaction of urea and monochloramine in the solution The metering ratio is 5.5:1. A metering pump is used to continuously spray mist droplets of monochloramine solution into the simulated flue gas from the inlet of the reaction tube, so that the stoichiometric ratio of monochloramine added to the simulated flue gas to NO in the flue gas is 0.5:1. When the temperature of the reaction tube is 1000°C and the reaction is stable, the oxidation rate of elemental mercury reaches 94%, and the reduction rate of nitrogen oxides is about 45%.
[0029] Then use simulated desulfurization lye (2% sodium carbonate solution) to absorb the above-mentioned gas (in a 500mL gas absorpt...
Embodiment 3
[0031] Simulated flue gas conditions are the same as in Example 1.
[0032] The chemical additive is monochloromethane, the main reducing agent is methane, and the mixed gas of methane and monochloromethane is prepared, the volume concentration is 1% and 0.2% respectively (the rest is air), and the ratio of the main reducing agent to the chemical additive is 5 : 1. The above-mentioned mixed gas is continuously sprayed into the simulated flue gas from the inlet of the reaction tube by a fan, so that the stoichiometric ratio of the total amount of methane and methyl chloride added to the simulated flue gas to the NO in the flue gas is 2:1. When the temperature of the reaction tube is 1000°C and the reaction is stable, it is measured that the oxidation rate of elemental mercury reaches 94%, and the reduction rate of nitrogen oxides is about 37%.
[0033] Then use simulated desulfurization lye (2% sodium carbonate solution) to absorb the above-mentioned gas (in a 500mL gas absorpti...
PUM
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com