Inkjet recording sheet

Abstract

Disclosed is an inkjet recording sheet having a colorant-receiving layer on the surface of its support, in which the colorant-receiving layer contains at least one of compounds represented by the following general formula (1) and compounds represented by the following general formula (2), and contains a vapor-phase-process silica, a polyvinyl alcohol, a boron compound, and a mordant. In the formulae, R represents a saturated hydrocarbon group having from 1 to 12 carbon atoms, an unsaturated hydrocarbon group having from 1 to 12 carbon atoms, a phenyl group, or an acyl group, and n indicates an integer of 1 to 3. RO(CH2CH2O)nH (1) RO(CH2CH(CH3)O)nH (2)

Description

[0001] This is a divisional of application Ser. No. 10 / 115,283 filed Apr. 4, 2002; the disclosure of which is incorporated herein by reference.[0002] 1. Field of the Invention[0003] The present invention relates to a recording material suitable for inkjet recording with liquid ink such as aqueous ink (containing a colorant of dye or pigment) or oily ink or with solid ink that is solid at room temperature but is melted into liquid for image formation. Precisely, the present invention relates to an inkjet recording sheet having the advantage of good receptivity to ink.[0004] 2. Description of the Related Art[0005] With remarkable development of information industries in recent years, various information-processing systems have been developed, and various recording methods and devices suitable for such information systems have been developed and put into practical use.[0006] Among the recording methods for information systems, an inkjet recording method has become much popularized not ...

AI Technical Summary

Benefits of technology

[0018] Specifically, one object of the present invention is to provide an inkjet recording sheet that satisfies the following requirements: Its colorant-receiving layer has good ink absorbability, and does not shrink in dry while the porous structure of the layer is formed; the layer does not crack and the sheet having the layer does not curl, or that is, the productivity of the sheet is high, the quality of the sheet is good, and the ability of the sheet to smoothly run in printers is good; and the colorant-receiving layer well adheres to the support.

[0192] As mentioned above, the colorant-receiving layer contains at least one of compounds represented by formula (1) and compounds represented by formula (2) and contains a vapor-phase-process silica, a polyvinyl alcohol, a boron compound and a mordant. Therefore, the colorant-receiving layer is prevented from shrinking in dry while its porous structure is formed, not lowering its ability to absorb ink. The layer does not crack and the inkjet recording sheet having the layer does not curl. In addition, the adhesion of the colorant-receiving layer to its support is high. Moreover, when the colorant-receiving layer that contains a vapor-phase-process silica has a three-dimensional network structure having a porosity of from 50 to 80%, it exhibits an excellent ink absorbability, and can form high-resolution images of high density. Further, even when stored in a high-temperature high-humidity atmosphere for long, the images formed are free from the problem of color bleeding in storage and have good lightfastness and waterproofness because of the excellent ability of the color-receiving layer to absorb ink.

Problems solved by technology

However, the porous structure-having inkjet recording sheet is problematic in that the porous colorant-receiving layer thereof may crack and the sheet itself often curls since the colorant-receiving layer shrinks in dry while its porous structure is formed.

If the layer cracks, the yield of the recording sheet lowers and the quality thereof worsens; and if the recording sheet curls, it could not well run in printers.

This is another problem with the porous structure-having inkjet recording sheet.

However, the filler used does not still solve the problem of poor ink absorbability and poor glossiness of the sheet.

Having such a structure, the recording sheet proposed has a good ability to absorb ink and has a good ability to receive ink to form high-resolution images thereon and its glossiness is high, but when it is stored for a long time in a high-temperature and high-humidity atmosphere after processed to have images thereon, the solvent in the colorant-receiving layer thereof diffuses along with dye therein to thereby cause a problem of image bleeding in the sheet.

In this, the water-soluble plasticizer used is ethylene glycol, diethylene glycol or triethylene glycol, and it worsens the storage stability of the coating liquid for the ink-receiving layer.

When the sheet contains urea, it often deposits on the surface of the ink-receiving layer while the recording sheet is stored for a long time.

Anyhow, at present, no one has succeeded in providing a satisfactory inkjet recording sheet that satisfies all the following requirements: Its colorant-receiving layer is tough, not readily cracking, and has a good ink absorbability to form high-resolution images, or that is, the layer has a good ink absorbability; the images formed are glossy and have good lightfastness and good waterproofness not bleeding even after stored for a long time; the images formed are vivid and have a high density, and they can be stably stored for a long time as they are, or that is, the images have good storage stability; and the colorant-receiving layer of the sheet shrinks little in dry while its porous structure is formed, and it well adheres to the support.