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Organic electroluminescence device

a technology of electroluminescence device and organic el, which is applied in the direction of discharge tube/lamp details, discharge tube luminescence screen, other domestic articles, etc., can solve the problems of affecting the luminescence characteristics of the device, and affecting the luminescence luminance of the device. , to achieve the effect of suppressing not only the lowering of initial luminescence luminan

Inactive Publication Date: 2005-03-10
CANON KK
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The solution effectively increases initial luminance and extends the device's operational life by reducing oxygen-induced degradation, achieving higher external quantum efficiency and prolonged luminescence half-life compared to conventional devices.

Problems solved by technology

Generally, it is difficult to satisfy the above luminescence characteristics in combination in the case of forming luminescence layers for R, G, B of a single material.
There-are several factors for such energy consumption, whereby device characteristics are adversely affected considerably.
Generally, the organic EL device is considerably affected by moisture (or water content).
Specifically, the organic EL device is accompanied with a defective region causing no luminescence therein (called “dark spots”) due to degradation or deterioration of a metal electrode and / or adsorption of water content to impurities in some cases.
Such dark spots are gradually enlarged with time by the influence of water content, thus adversely affecting the life of the organic EL device.
Further, in addition to the influence of water content, it has been generally known that oxygen entering the organic EL device oxidizes electrodes and / or organic materials used therein, thus lowering durability of the organic EL device.
In the organic EL device of this type, however, a fluorescence organic compound is used as a luminescence center material as in the above-described conventional EL devices, thus merely providing a lower quantum efficiency and a lower luminance relative to power supply.
The organic EL device utilizing phosphorescence is, however, accompanied with a serious problem of oxygen quenching (quenching due to oxygen) causing deterioration in initial performance or that with time of the resultant EL device.
According to our study, this problem is particularly noticeable in th case of the organic EL device using a phosphorescent material compared with that using a fluorescent material.
For this reason, a time from the energy excitation step to a subsequent luminescence step is longer in the case of utilizing phosphorescence, thus resulting in an increased probability of consumption of the excitation energy due to energy transition with no luminescence including the oxygen quenching.
As a result of our study, it has been confirmed that the presence of oxygen in an organic EL device particularly using a phosphorescent material adversely affects not only an initial luminescence luminance but also the life of the resultant EL device, such as lowerings in luminescence luminance and luminescence efficiency when the EL device is continuously or discontinuously driven for a certain period of time.

Method used

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  • Organic electroluminescence device
  • Organic electroluminescence device
  • Organic electroluminescence device

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0063] On a 1.1 mm-thick glass substrate (20×25 mm), a ca. 100 nm-thick transparent electrode (anode) of ITO (indium tin oxide) was formed by sputtering, followed by patterning.

[0064] On the ITO electrode, four organic luminescence function layers (first to fourth layers) were successively formed in the following manner.

[0065] First, on the ITO electrode, a 40 nm-thick first layer (hole transport layer) of α-NPD (N4,N4′-di-naphthalene -1-yl-N4,N4′-diphenylbiphenyl-4,4′-diamine) shown below was formed by vacuum deposition (2.7×10−3 Pa).

[0066] On the first layer, a 40 nm-thick second layer (luminescence layer) of a luminescent material comprising CPB (4,4′-N,N′-dicarbazole biphenyl) shown below and Ir(ppy)3 (fac tris(2-phenylpyridine)iridium) (CBP: Ir(ppy)3=93:7 by weight) by co-vacuum deposition (2.7×10−3 Pa) at a controlled deposition rate.

[0067] On the second layer, a 10 nm-thick third layer (exciton diffusion prevention layer) of BCP (2,9-dimethyl-4,7-diphenyl-1-,10-phenanth...

example 2

[0077] A simple matrix-type organic EL device as shown in FIG. 4 was prepared in the following manner.

[0078] On a 1.1 mm-thick glass substrate 51 (75×75 mm), a ca. 100 nm-thick transparent electrode 52 of ITO (anode) was formed by sputtering, followed by patterning in a stripe form including 100 lines each having a width of 100 μm and a spacing (with an adjacent line) of 40 μm.

[0079] On the stripe ITO electrode 52, an oxygen absorbent of Mg was formed by vacuum deposition with a mask in a stripe pattern 53 at respective center portions of the spacing of the stripe ITO electrode 52 so as to have a width of 10 μm and a thickness of 50 nm (for each stripe Mg layer).

[0080] On the ITO electrode 52 and the stripe pattern 53 of Mg, four organic luminescence function layers 54 were formed in the same manner as in Example 1 except that Mg (as the oxygen absorbent) was not used at all.

[0081] Then, on the organic luminescence function layers 54, a lamination metal electrode (cathode) 55 co...

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Abstract

A luminescence device is constituted by a substrate, a first electrode disposed on the substrate, at least one organic luminescence function layer disposed on the first electrode, a second electrode disposed on the above at least one organic luminescence function layer, and an oxygen absorbent disposed between the substrate and the second electrode or between the first and second electrodes. To the luminescence device, a voltage is applied between the first and second electrodes to cause phosphorescence from at last one layer constituting the above-mentioned at least one organic luminescence function layer preferably containing the oxygen absorbent. The oxygen absorbent may be formed in a layer disposed at a region other than pixel portions.

Description

FIELD OF THE INVENTION AND RELATED ART [0001] The present invention relates to an organic electroluminescence (EL) device used as a light-emitting device for flat panel displays, projection displays, printers, etc. [0002] Self-emission type devices for the flat panel display, such as a plasma emission device, a field emission device, and an electroluminescence (EL) device have attracted notice in recent years. [0003] Of these self-emission type devices, the EL device is classified into an organic EL device and an inorganic EL device. [0004] The inorganic EL device is a self-emission device utilizing luminescence based on collisional excitation. On the other hand he organic EL device is a self-emissin device of a carrier injection-type utilizing luminescence caused at the time of recombination of electron and hole carried into a luminescence layer. [0005] With respect to the organic EL device, T. W. Tang et al. have substantiated in 1987 that it is possible to realize a high-luminanc...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C09K11/06H01L27/32H01L51/50H01L51/52H05B33/04
CPCH01L27/3281Y10S428/917H01L51/5237H01L51/5012H10K59/17H10K50/11H10K2101/10H10K50/16H10K59/874H10K50/846H10K50/18
Inventor MORIYAMA, TAKASHIOKADA, SHINJIROTSUBOYAMA, AKIRATAKIGUCHI, TAKAONOGUCHI, KOJIKAMATANI, JUNFURUGORI, MANABU
Owner CANON KK