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Silicon carbide substrate, semiconductor device and method for manufacturing silicon carbide substrate

a technology silicon carbide, which is applied in the direction of polycrystalline material growth, chemistry apparatus and processes, crystal growth process, etc., can solve the problems of high crystal defect density of silicon carbide substrate, current leakage or dielectric breakdown, and significant impact on the performance of semiconductor devices, etc., to achieve the effect of reducing the density of stacking faults, reducing the density of staking faults, and sufficient low defect density

Inactive Publication Date: 2014-11-18
HOYA CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This approach effectively reduces stacking fault density and prevents anisotropic extension, resulting in a substrate with low defect density suitable for high-performance semiconductor applications by blocking fault propagation at incoherent boundaries and absorbing lattice strain.

Problems solved by technology

However, in some cases, silicon carbide substrate includes high density of crystal defects.
A performance of the semiconductor device is significantly affected by such crystal defects included in the silicon carbide substrate.
For example, the representative planar defects, such as an anti-phase boundary and a stacking fault, cause a current leak or dielectric breakdown and remarkably reduce the performance of a power semiconductor device.
Therefore, reduction of such planar defects is the main issue for silicon carbide substrate applicable to the device use.
However, it is insufficient to reduce the stacking faults density only by using this misoriented-Si substrate.
As a result, the effect of annihilation is lost and complete elimination of the stacking faults is not achieved.
This is because the stacking faults exposing the Si-polar face are continuously occurred due to a lattice strain generated during the crystal growth.
One is caused by a temperature distribution in a substrate, and the other is caused by a lattice miss-matching due to annihilation of the stacking faults.
The stacking faults density is actually reduced by using SBE technique, however, complete elimination of the stacking faults is not achieved.
This is because the additional stacking faults occurrence during a SBE growth process, which is mainly caused by the strains existing in the cubic silicon carbide substrate and a homo-epitaxial layer.
Hence, new stacking faults are continuously occurred in the silicon carbide layer to release such strains.
Namely, it is quite difficult to fabricate the cubic silicon carbide substrate having extremely low stacking faults density, which is suitable for manufacture of the high performance device, without controlling the lattice strain generated during the crystal growth.
However, the off-angle is also introduced not only in one direction but also in a direction orthogonal thereto, control of the orientation of the polar-face shown in the aforementioned non-patent document 2 is deteriorated and hence elimination of the anti-phase boundaries is not achieved.
Therefore, the propagation direction of the planar defects cannot be controlled through the growth direction.

Method used

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  • Silicon carbide substrate, semiconductor device and method for manufacturing silicon carbide substrate
  • Silicon carbide substrate, semiconductor device and method for manufacturing silicon carbide substrate
  • Silicon carbide substrate, semiconductor device and method for manufacturing silicon carbide substrate

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first embodiment

[0102]The silicon carbide substrate according to the present invention will be described hereafter.

[0103]According to the first embodiment, the stacking faults density on the main surface 12 can be reduced by executing a manufacturing procedure of (I) to (III) shown below.

[0104](I) Formation of isolated regions

[0105](II) Reduction of the stacking faults density by homo-epitaxial growth

[0106](III) Expansion of a low stacking faults region by bridging the isolated regions

[0107](I) to (III) will be described hereafter in detail.

[0108](I) Formation of the Isolated Regions

[0109]First, as shown in FIG. 12, salient portions (called isolated regions 210 hereafter) having side walls of {110} planes are formed on (001) surface of the substrate made of 3C—SiC (simply called a SiC substrate 200 hereafter). Each isolated region 210 may have a so-called line-space structure or mesa-structure. As a condition, as described above, extremely preferably the isolated region 210 has a side wall of {110}...

second embodiment

[0116]First, the mechanism M1 will be described. As shown in FIG. 13, when the silicon carbide is homo-epitaxially grown on the SiC substrate 200, stacking fault SF1, which is initially exposed on the surface outside of the isolated regions 210, is propagated into the homo-epitaxial layer. However, when the homo-epitaxial layer is grown up to the surface indicated by the dashed line 201, the stacking fault SF1 is inhibited its propagation into the isolated region 211 by the side walls. Such a reducing method of the stacking faults density is called as a mechanism M1. Note that when SiC is selectively grown on the mask-patterned substrate, as shown in the second embodiment, propagation of SF1 is inhibited by the mask on the surface.

[0117]2>

[0118]Next, the mechanism M2 will be described. As shown in FIG. 13, the silicon carbide is homo-epitaxially grown on the SiC substrate 200, the stacking fault SF2, which is initially exposed on the surface within the isolated regions 210, is propa...

third embodiment

[0199]The silicon carbide substrate according to the present invention will be described hereafter.

[0200]First, similarly to the second embodiment of the present invention, the undulations were formed on the entire surface of 4-inch Si(001) substrate by rubbing with the abrasive grains in [−110] direction. Subsequently, the residual abrasive grains on the processed surface were cleaned off by the same cleaning process described in the second embodiment. Then, 0.5-μm-thick thermal oxide layer was formed on the undulant Si (001) substrate by sacrificial thermal oxidation and thereafter the thermal oxide layer was removed by a dilute hydrofluoric acid. Through the above described processes, the undulations, which are continuous wavy shape parallel to [−110] direction shown in FIG. 9, with a depth of a groove being 30-50 nm, a width of being 1-2 μm, and a gradient of being 3-5 degrees were obtained.

[0201]Next, in order to grow the thick cubic silicon carbide layer on the undulant Si(001...

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Abstract

There is provided a silicon carbide substrate composed of silicon carbide, including encapsulated regions inside, which form incoherent boundaries between the silicon carbide and the encapsulated regions, wherein propagation of stacking faults in the silicon carbide is blocked.

Description

TECHNICAL FIELD[0001]The present invention relates to a silicon carbide substrate used for a high performance semiconductor device. Particularly, there is provided a silicon carbide substrate which has an extremely low planar defects density on a specific crystal surface, and which can be preferably utilized as a material of a power semiconductor device having high efficiency and high breakdown voltage.DESCRIPTION OF RELATED ART[0002]Silicon carbide has been used as a compound semiconductor material for high performance semiconductor device. However, in some cases, silicon carbide substrate includes high density of crystal defects.[0003]A performance of the semiconductor device is significantly affected by such crystal defects included in the silicon carbide substrate. For example, the representative planar defects, such as an anti-phase boundary and a stacking fault, cause a current leak or dielectric breakdown and remarkably reduce the performance of a power semiconductor device. ...

Claims

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Application Information

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Patent Type & Authority Patents(United States)
IPC IPC(8): H01L29/16H01L29/15C30B29/36H01L21/02
CPCH01L21/0262C30B29/36H01L21/02447H01L21/02658H01L21/0243H01L21/02381H01L21/0265H01L21/02529H01L21/02639H01L29/1608
Inventor NAGASAWA, HIROYUKIKAWAHARA, TAKAMITSUYAGI, KUNIAKIHATTA, NAOKI
Owner HOYA CORP