Silicon carbide substrate, semiconductor device and method for manufacturing silicon carbide substrate
a technology silicon carbide, which is applied in the direction of polycrystalline material growth, chemistry apparatus and processes, crystal growth process, etc., can solve the problems of high crystal defect density of silicon carbide substrate, current leakage or dielectric breakdown, and significant impact on the performance of semiconductor devices, etc., to achieve the effect of reducing the density of stacking faults, reducing the density of staking faults, and sufficient low defect density
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first embodiment
[0102]The silicon carbide substrate according to the present invention will be described hereafter.
[0103]According to the first embodiment, the stacking faults density on the main surface 12 can be reduced by executing a manufacturing procedure of (I) to (III) shown below.
[0104](I) Formation of isolated regions
[0105](II) Reduction of the stacking faults density by homo-epitaxial growth
[0106](III) Expansion of a low stacking faults region by bridging the isolated regions
[0107](I) to (III) will be described hereafter in detail.
[0108](I) Formation of the Isolated Regions
[0109]First, as shown in FIG. 12, salient portions (called isolated regions 210 hereafter) having side walls of {110} planes are formed on (001) surface of the substrate made of 3C—SiC (simply called a SiC substrate 200 hereafter). Each isolated region 210 may have a so-called line-space structure or mesa-structure. As a condition, as described above, extremely preferably the isolated region 210 has a side wall of {110}...
second embodiment
[0116]First, the mechanism M1 will be described. As shown in FIG. 13, when the silicon carbide is homo-epitaxially grown on the SiC substrate 200, stacking fault SF1, which is initially exposed on the surface outside of the isolated regions 210, is propagated into the homo-epitaxial layer. However, when the homo-epitaxial layer is grown up to the surface indicated by the dashed line 201, the stacking fault SF1 is inhibited its propagation into the isolated region 211 by the side walls. Such a reducing method of the stacking faults density is called as a mechanism M1. Note that when SiC is selectively grown on the mask-patterned substrate, as shown in the second embodiment, propagation of SF1 is inhibited by the mask on the surface.
[0117]2>
[0118]Next, the mechanism M2 will be described. As shown in FIG. 13, the silicon carbide is homo-epitaxially grown on the SiC substrate 200, the stacking fault SF2, which is initially exposed on the surface within the isolated regions 210, is propa...
third embodiment
[0199]The silicon carbide substrate according to the present invention will be described hereafter.
[0200]First, similarly to the second embodiment of the present invention, the undulations were formed on the entire surface of 4-inch Si(001) substrate by rubbing with the abrasive grains in [−110] direction. Subsequently, the residual abrasive grains on the processed surface were cleaned off by the same cleaning process described in the second embodiment. Then, 0.5-μm-thick thermal oxide layer was formed on the undulant Si (001) substrate by sacrificial thermal oxidation and thereafter the thermal oxide layer was removed by a dilute hydrofluoric acid. Through the above described processes, the undulations, which are continuous wavy shape parallel to [−110] direction shown in FIG. 9, with a depth of a groove being 30-50 nm, a width of being 1-2 μm, and a gradient of being 3-5 degrees were obtained.
[0201]Next, in order to grow the thick cubic silicon carbide layer on the undulant Si(001...
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Abstract
Description
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