The invention relates to the technical field of fresh air purification systems, and particularly discloses a fresh air purifying system composed of an air conditioner and a graphene nanofiber membranetotal heat exchanger. The system comprises the air conditioner and the total heat exchanger. The total heat exchanger comprises a shell, a fiber membrane is fixedly connected in the shell, an exchange channel is fixedly connected to the position, on the surface of the fiber membrane, in the shell, a flow limiting mechanism is movably connected in the exchange channel, adjusting plates are movablyconnected to the two sides of the exchange channel, spring rods are movably connected into the adjusting plates, the ends, away from the adjusting plates, of the spring rods are movably connected with blockage plates, and when the adjusting plates make contact with the blocking plates, airflow can directly enter the exchange channel, at the moment, the blockage plates are away from the adjustingplates, a flexible pipe is opened, the airflow can enter the shell again, the above operation is repeated, the temperature difference between fresh air entering a room and the airflow existing in a room cannot be too large while the gas normal exchange is ensured, the temperature of introduced fresh air is close to the room temperature, and the energy consumption is reduced.