Method for defluorinating and degrading complete fluorine substituted compounds

A fluorooctane sulfonate, perfluorooctanoic acid technology, applied in chemical instruments and methods, organic decomposition, solid waste removal, etc., can solve the problems of unclear changes in PFOS, inability to effectively decompose PFOA and PFOS, etc.

Inactive Publication Date: 2007-11-07
TSINGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Existing pollutant treatment methods, such as incineration, but the changes in PFOS during incineration are still unclear
Existing pollutant treatment methods, such as biodegradation, hydrolysis, and photolysis, cannot effectively decompose PFOA and PFOS

Method used

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  • Method for defluorinating and degrading complete fluorine substituted compounds
  • Method for defluorinating and degrading complete fluorine substituted compounds
  • Method for defluorinating and degrading complete fluorine substituted compounds

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Embodiment 1: the vacuum ultraviolet ray reduction decomposition of perfluorooctanoic acid (PFOA)

[0026]As shown in Figure 1, 800mL containing the PFOA aqueous solution of 15mg / L is put into reactor 3, and nitrogen is passed into reactor 3 from bottom gas distribution plate 4, and under the irradiation of 15W emission 185nm vacuum ultraviolet ray lamp 1, PFOA desorbs The effect of fluorine decomposition is shown in Figure 2. The defluorination rate is calculated according to the fluoride ion concentration in the water during the reaction, and the fluoride ion concentration in the water is measured by fluorine reagent spectrophotometry. Under the situation of feeding nitrogen under 185nm vacuum ultraviolet irradiation (indicated as "185nm passing nitrogen" in Fig. 2), the concentration of fluoride ions in the reaction solution increases with the reaction time, and the defluorination rate of PFOA reaches 28.7% after 380 minutes of reaction, the average Of the 15 fluori...

Embodiment 2

[0027] Embodiment 2: the vacuum ultraviolet ray reduction decomposition of perfluorooctane sulfonate (PFOS)

[0028] As shown in Figure 1, 800mL of PFOS aqueous solution containing 20mg / L is put into the reactor 3, and nitrogen gas is passed into the reactor 3 from the gas distribution plate 4 at the bottom. The effect of decomposition is shown in Figure 3. The fluoride ion concentration in the solution is measured by fluorine reagent spectrophotometry. The fluoride ion concentration in the reaction solution increases with the reaction time. After 675 minutes of reaction, the defluorination rate of PFOS reaches 15%. On average, PFOS molecules 2.55 fluorines of 17 fluorines (F) contained in have come off in the solution. In the case of 185nm vacuum ultraviolet radiation and oxygen, PFOS does not defluorinate and decompose; under 254nm radiation, no matter whether oxygen or nitrogen is introduced, it does not defluorinate and decompose.

Embodiment 3

[0029] Example 3: Catalytic defluorination and decomposition of perfluorooctanoic acid by vacuum ultraviolet light

[0030] As shown in Figure 1, 800mL of PFOA aqueous solution containing 19mg / L is put into reactor 3, nitrogen gas is passed into reactor 3 from the bottom gas distribution plate, and semiconductor photocatalyst LiNbO is added at the same time. 3 , the concentration in its reaction solution is 0.1g / L, under the irradiation of 15W emission 185nm vacuum ultraviolet ray lamp 1, the effect of PFOA defluorination decomposition is shown in Figure 4. Measure the concentration of fluoride ion in the reaction solution with fluorine reagent spectrophotometry, the concentration of fluoride ion in the reaction solution increases with the reaction time, the defluorination rate of PFOA reaches 23.5% after reacting for 210 minutes, on average, 15% contained in the PFOA molecule A fluorine (F) has 3.5 fluorine dropped into the solution. And correspondingly, if LiNbO is not adde...

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Abstract

A defluorinating and degrading method of fluorine substituted compound is characterized by vacuum ultraviolet irradiating PFOS and PFOA etc. fluorine substituted compound at anaerobic condition, defluorinating reacting fluorine substituted compound at irradiation of 185nm ultraviolet mercury vapour light or 172nm xenon quasi molecule laser light, inducing protective inert gas or reducing gas for realizing anaerobic condition, or adding reducing substance or semiconductor catalyst with high conducting band energy level during reacting process to improve defluorinating and decomposing ratio. It achieves simple operation and non-toxic.

Description

technical field [0001] The invention relates to the technical field of decomposition of perfluorooctanoic acid or perfluorooctane sulfonate, and is used for eliminating perfluorooctanoic acid or perfluorooctane sulfonate in water, air and soil. Background technique [0002] Perfluorinated compounds (PFCs) refer to organic compounds in which the hydrogen (H) connected to the carbon atom (C) in the organic structure is replaced by fluorine (F), such as carbon tetrafluoride (CF 4 ) and perfluorooctane sulfonate (PFOS) - CF 3 -CF 2 -CF 2 -CF 2 -CF 2 -CF 2 -CF 2 -CF 2 -SO 3 - . Perfluorinated compounds have been used since the 1950s and are widely used in industrial and consumer products, including as protective coatings for fabrics and carpets, paper coatings, insecticide components, surfactants, etc. [0003] Since many research reports have shown that a widely used perfluorinated compound-perfluorooctane sulfonate (PFOS) exists in wild animals and humans around the ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C07B35/06B09B3/00
Inventor 张彭义陈静张丽余刚常晓珺
Owner TSINGHUA UNIV
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