Electric charge regulator used for electrostatic image developing and preparing method thereof
A technology of charge regulator and static electricity, which is applied in the directions of developer, electrography, optics, etc., can solve the problems of poor environmental stability and environmental safety, slow electrification speed of charge regulator, uneven crystal shape and size, etc., to achieve The effect of uniform crystal shape and size, fast electrification speed and mild conditions
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Embodiment 1
[0018] A new type of charge regulator for electrostatic image development and its preparation method. The polyhydroxy aromatic acid is selected from propyl gallate, the metal ion is selected from trivalent chromium ion, the alcohol is selected from ethylene glycol methyl ether, the mole of chromium ion and propyl gallate The ratio is 1 / 3. Dissolve propyl gallate with ethylene glycol methyl ether, add it to the reaction vessel, and adjust to weak alkalinity; slowly add chromium formate into the reaction vessel while stirring, and use ethylenediamine to keep the pH of the reaction system at 6.0 during the reaction At about 80°C for 3.0 hours; generate a black jelly, filter, treat the black substance with hydrochloric acid to obtain a green powder, wash with deionized water, and dry to obtain a metal Cr(III) complex charge regulator.
[0019] The metal complex charge control agent produced in this embodiment is a green powder with stable performance in the air, no oxidative disco...
Embodiment 2
[0021] A novel charge regulator for developing an electrostatic image and a preparation method thereof. Polyhydroxy aromatic acid is selected from octyl gallate, metal ions are selected from trivalent chromium ions, alcohol is selected from ethanol, and the molar ratio of chromium ion to octyl gallate is 1 / 3. First, make chromium sulfate into a solution with a concentration of 25.0%, and add it to the reaction vessel; dissolve octyl gallate with ethanol, and adjust it to weak alkalinity; slowly add the alcohol solution of octyl gallate dropwise to the prepared mixture while stirring. In the chromium sulfate solution, use sulfuric acid and caustic soda to keep the pH of the reaction system at about 6.5 during the reaction process, pay attention to prevent the formation of hydroxide, and keep it at 60°C for 6.0 hours; a black jelly is formed, which is treated with hydrochloric acid and deionized Washing with water and drying to obtain a metal Cr(III) complex charge regulator.
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Embodiment 3
[0024] A novel charge regulator for electrostatic image development and a preparation method thereof. Polyhydroxy aromatic acid is selected from propyl gallate, metal ions are selected from trivalent chromium ions, and the molar ratio of chromium ion to propyl gallate is 1 / 3. First, make chromium sulfate into a solution with a concentration of 10.0%, and add it to the reaction container; dissolve propyl gallate with distilled water, and adjust it to weak alkalinity with caustic soda; slowly add propyl gallate dropwise to the prepared solution while stirring. In the chromium sulfate solution, prevent generation of hydroxide, keep the pH of the reaction solution at about 5.5 with sulfuric acid and caustic soda during the reaction, and keep the temperature at 30°C for 10.0 hours. After the crystals are precipitated in the solution, they are washed with deionized water and dried to obtain a metal Cr(III) complex charge regulator.
[0025] The metal complex charge control agent pro...
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