Core-shell type multifunctional composite wood precursor solution and its preparation method
A precursor liquid, core-shell type technology, applied in wood impregnation, impregnated wood, wood processing utensils, etc., can solve the problems of ceramic wood performance degradation, toughness decline, complex composition, etc., to improve hardness and strength, improve loss resistance , the effect of simple preparation method
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Embodiment 1
[0028] Disperse 11.2g of vinyl tris(β-methoxyethoxy)silane in 200mL of absolute ethanol, disperse evenly by ultrasonic, then add 5.0g of SiO with an average particle size of 40nm 2 Particles, after ultrasonic dispersion for 2 hours, the solution was centrifuged, washed, and dried at low temperature to obtain surface-modified SiO 2 Nanoparticles; 1.0 g of surface-modified SiO 2 Nanoparticles were dispersed in an emulsion composed of 100mL water, 5g vinyl acetate (VAc), 1.0g sodium dodecylsulfonate and 2.5g p-nonylphenol polyoxyethylene ether. After ultrasonic emulsification for 1h, the system was transferred to a condenser containing N 2 Introduce the pipe and the reactor with electric stirring, the stirring speed is 250 rpm, add 0.05g potassium persulfate initiator, control the temperature at 70 ° C, and pass N 2 In the case of 12 hours of reaction, after the reaction is stopped, a small amount of gel filtration will be produced to obtain SiO with an average particle size of...
Embodiment 2
[0031] Disperse 7.6g of γ-aminopropylmethyldiethoxysilane in 200mL of absolute ethanol, ultrasonically disperse evenly, and then add 5.0g of SiO with an average particle size of 80nm 2 Particles, after ultrasonic dispersion for 2 hours, the solution was centrifuged, washed, and dried at low temperature to obtain surface-modified SiO 2 nanoparticles; 4.5 g of surface-modified SiO 2 Nanoparticles were dispersed in an emulsion composed of 300mL water, 40g methyl methacrylate (MMA), 2.0g sodium dodecylsulfonate and 6.5g p-nonylphenol polyoxyethylene ether. After ultrasonic emulsification for 2h, Transfer the system to a tank containing a condenser, N 2 Into the pipe and the electric stirring reactor, the stirring speed is 250 rpm, add 2.0g potassium persulfate initiator, control the temperature at 70°C, 2 In the case of the reaction for 6 hours, after the reaction is stopped, a small amount of gel filtration will be produced to obtain SiO with an average particle size of 330nm a...
Embodiment 3
[0034] Disperse 13.3g of γ-aminopropylmethyldiethoxysilane in 200mL of absolute ethanol, disperse evenly by ultrasonic, then add 5.0g of TiO with an average particle size of 80nm 2 Particles, after ultrasonic dispersion for 2 hours, the solution was centrifuged, washed, and dried at low temperature to obtain surface-modified TiO 2 nanoparticles; 3.5 g of surface-modified TiO 2 Nanoparticles were dispersed in an emulsion consisting of 250mL water, 10g methyl methacrylate (MMA), 5g butyl acrylate (BA), 5.0g sodium dodecylsulfonate and 5.5g p-nonylphenol ethoxylate In the process, after ultrasonic emulsification for 2 hours, the system was transferred to a 2 Introduce the pipe and the reactor with electric stirring, the stirring speed is 200 rpm, add 0.75g potassium persulfate initiator, control the temperature at 75 ° C, and pass N 2 In the case of the reaction for 6 hours, after the reaction is stopped, a small amount of gel filtration will be produced to obtain TiO with an a...
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