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Halogen-free expansion fire retardant for polypropylene

An intumescent flame retardant, polypropylene technology, applied in the field of flame retardants for polyolefins, can solve the problems affecting the mechanical properties and prices of materials, processing difficulties, application restrictions, etc. The effect of less smoke generation

Active Publication Date: 2008-03-19
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The biggest disadvantages of the above-mentioned mixed intumescent flame retardants are difficult processing, moisture absorption, large dosage, affecting the mechanical properties of materials and high prices, which limit the application

Method used

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  • Halogen-free expansion fire retardant for polypropylene
  • Halogen-free expansion fire retardant for polypropylene
  • Halogen-free expansion fire retardant for polypropylene

Examples

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Embodiment 1~26

[0036] Examples are shown in Table 1. First, melamine melamine salt and ammonium polyphosphate are dried so that the water content is less than 0.2% (wt), and then pulverized so that the particle size is less than 35 μm.

[0037] Secondly, put the melamine melamine salt and ammonium polyphosphate, lubricant, coupling agent, and char-forming accelerator into the high-speed mixer and mix for 1-10 minutes with the composition shown in Table 1 to obtain halogen-free polypropylene Intumescent flame retardant.

[0038] Table 1 Proportion of halogen-free flame retardant for polypropylene

[0039] Real

[0040] 13

[0041] Table C 18 Stearic acid; C 18 Zn zinc stearate; C 18 Ca is calcium stearate; KH-550 is a product of γ-aminopropyl triethoxysilane; NDZ-101 is monoalkoxy titanate coupling agent; ZQ-560 is γ-glycidyl ether A product of oxypropyltrimethoxysilane; TiO 2 It is titanium dioxide; PA-6 is nylon 6.

[0042] Put the halogen-free flame retardant compounded w...

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Abstract

A halogen-free intumescent flame retardant for polypropylene relates to a flame retardant for polyolefine, which is formulated by melamine salt, ammonium polyphosphate, lubricant, coupling agent and char-forming accelerator, wherein the percentage of each component in the total weight of the flame retardant is: 14 percent-90 percent of melamine salt, 9 percent-85 percent of ammonium polyphosphate, 0.1 percent-2 percent of lubricant, 0.1 percent-2 percent of coupling agent, and 0.1 percent-5 percent of char-forming accelerator; when the flame retardant of the invention is used for flame retardant of polyethylene powder or granular materials, and the lowest addition of the main frame element is 21 percent(wt), the flame retardancy grade reaches the V-0 grade according to US UL94 test, so compared with the prior art, the addition of the flame retardant of the invention is greatly decreased, the cost is reduced and the processing property of the polypropylene is not affected. Compared with brominated, the halogen-free flame retardant of the invention is environment-friendly with low smoke density, small smoke mass, lower mass loss rate and big residual mass when used for the flame retardancy of polypropylene.

Description

Technical field [0001] The invention relates to a flame retardant for polyolefin, in particular to a halogen-free intumescent flame retardant for polypropylene. Background technique [0002] Flame-retardant materials, especially environmentally friendly halogen-free flame-retardant polymer materials and flame-retardant technologies are becoming a hot spot in the world. The demand for halogen-free flame retardancy is increasing. The European Union and other countries have successively introduced laws and regulations to restrict halogen-based flame retardancy. The use of agents. To make polymer materials flame-retardant and not produce toxic smoke during combustion, pollution-free flame-retardant elements must be introduced into the polymer. The most practical and effective way to introduce pollution-free flame-retardant elements into the material is to add environmentally friendly Type flame retardant. [0003] At present, the flame retardant methods used for polymers are mainly t...

Claims

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Application Information

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IPC IPC(8): C08L23/12C08K5/54C08K3/32C08K5/521C08K5/09C08K3/22
Inventor 逯翠霞安彦杰严金荣李冬霞张瑞孟凡瑞何书艳李广东吴林美邹恩广姜进宪李洪涛王熺张怀志赵晶莹袁宗辉
Owner PETROCHINA CO LTD
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