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Preparations of bicomponent PSU type liquid rubber-based sealant and PSU liquid rubber thereof

A liquid rubber and sealant technology, applied in the field of sealants, can solve problems such as no single-component sealant reports, no mention of polyether types, no discussion of the influence of polyether properties, etc., to achieve excellent comprehensive mechanical properties, production The effect of low cost and simple preparation process

Inactive Publication Date: 2009-05-20
HENAN YONGLI CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the type of polyether is not indicated, and the influence of polyether functionality on the reaction and the structure and properties of modified polysulfide rubber is not discussed.
It is proposed that this modified polysulfide rubber is very suitable for the production of various types of one-component sealants, but there is no report on it in one-component sealants

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] Embodiment 1: the preparation method of two-component PSU type liquid rubber-based sealant and PSU type liquid rubber

[0041] (1) Prepare the two-component PSU type liquid rubber-based sealant according to the following formula, and each material in the formula is expressed in parts by weight:

[0042] Component A: PSU type liquid rubber 50, light calcium carbonate 40, heavy calcium carbonate 70, dibutyl phthalate 50, octyl phenolic tackifying resin 2, stearic acid 2, antioxidant AT-215 0.5, ultraviolet absorber UV-328 0.5.

[0043] Component B: manganese dioxide 30, furnace carbon black 20, lithopone 20, light calcium carbonate 10, tetramethylthiuram disulfide 1, dibutyl phthalate 30, chlorinated paraffin 52 30 .

[0044] Components A and B are mixed evenly according to the above formula and conventional production methods, and packaged separately; components A and B are mixed in a ratio of A:B=10:1 for use. According to the requirements of GB / T 13477-2002, the bon...

Embodiment 2

[0047] Embodiment 2: the preparation method of two-component PSU type liquid rubber-based sealant and PSU type liquid rubber

[0048] (1), prepare the two-component PSU type liquid rubber-based sealant according to the following formula, and each material in the formula is expressed in parts by weight:

[0049] Component A: PSU type liquid rubber 80, light calcium carbonate 40, heavy calcium carbonate 140, dibutyl phthalate 50, alkyl phenolic tackifying resin 4, stearic acid 2.5, antioxidant 264 0.8, UV absorber UV-329 0.7.

[0050] Component B: manganese dioxide 40, furnace carbon black 40, light calcium carbonate 20, zinc dibutyldithiocarbamate 1, diphenylguanidine 1, dibutyl phthalate 30, chlorinated paraffin 5230 .

[0051] Components A and B are mixed evenly according to the above formula and conventional production methods, and packaged separately; components A and B are mixed in a ratio of A:B=10:1 for use. According to the requirements of GB / T 13477-2002, bonded con...

Embodiment 3

[0054] Embodiment 3: the preparation method of two-component PSU type liquid rubber-based sealant and PSU type liquid rubber

[0055] (1), prepare the two-component PSU type liquid rubber-based sealant according to the following formula, and each material in the formula is expressed in parts by weight:

[0056] Component A: PSU type liquid rubber 90, light calcium carbonate 50, heavy calcium carbonate 120, dioctyl phthalate 60, C 5 Petroleum resin 10, stearic acid 3, antioxidant 1330 1, ultraviolet absorber UV-3281.

[0057] Component B: calcium peroxide 40, white carbon black 30, lithopone 20, light calcium carbonate 10, tetramethylthiuram disulfide 1, dibenzothiazole disulfide 1, dioctyl phthalate 40, chlorinated paraffins 52 20.

[0058] Components A and B are mixed evenly according to the above formula and conventional production methods, and packaged separately; components A and B are mixed in a ratio of A:B=12:1 for use. According to the requirements of GB / T 13477-200...

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PUM

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Abstract

The invention discloses a dual-component PSU-typed liquid rubber-based sealant and a preparation method of the PSU-typed liquid rubber, wherein, the sealant comprises a component A and a component B; the component A comprises PSU-typed liquid rubber, plasticizer, filling material, tackifier, antioxidant and vulcanization retarder; the component B comprises vulcanizing agent, vulcanization accelerator, plasticizer and filling material; and the component A and the component B are mixed together by normal method so as to prepare the finished product. The PSU-typed liquid rubber uses the mixture of polyether glycol and polyether-tribasic alcohol and polyisocyanate as raw materials to generate isocyanate-terminated polyurethane prepolymer under the action of acidic catalyst; furthermore, the isocyanate-terminated polyurethane prepolymer is terminated by sulfhydryl compounds to synthesize the sulfhydryl-terminated liquid rubber which takes the polyurethanes as main chain and has local crosslinking structure characteristic; the liquid rubber is taken as the basic rubber to prepare the sealant which has excellent mechanic performances and can be widely applied to the fields such as the construction of housing, plazas, roads, airports, bridges, hydraulic engineering, water conveyance project, sewage disposal engineering, and the like, the manufacture of automobiles, trains, containers, and the like, and the electric apparatuses, power, aeronautics and astronautics, and the like.

Description

1. Technical field: [0001] The invention relates to a sealant, in particular to a two-component PSU type liquid rubber-based sealant and a preparation method of the PSU type liquid rubber. 2. Background technology [0002] Sealant is a type of engineering material used to fill gaps (holes, joints or seams, etc.), and is widely used in devices and projects involving fluid storage, transmission, and energy conversion. When in use, it is a fluid or extrudable amorphous material, which is coated, extruded, and embedded in the part to be sealed through a certain process, and depends on temperature changes, solvent volatilization or chemical crosslinking to stabilize the adhesion with the substrate. Knots, and gradually set into a tough solid or elastic body. [0003] The main types of sealant are: polyurethane, polysulfide, silicone, acrylate, styrene-butadiene rubber, butyl rubber, asphalt and oily caulk, etc. Among them, polyurethane, polysulfide rubber and silicone sealant ha...

Claims

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Application Information

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IPC IPC(8): C09K3/10C09J175/08
Inventor 黄正强杨宏生张宪利郭步钦许书珍王玉广李健
Owner HENAN YONGLI CHEM
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