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Method for loading TiO2 photocatalyst on ferromagnetic metal thin film

A metal thin film, photocatalyst technology, applied in chemical instruments and methods, physical/chemical process catalysts, chemical/physical processes, etc. Recycling, good buoyancy effect

Inactive Publication Date: 2009-06-24
CHINA NAT ACAD NANOTECH & ENG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Since the pollution of water bodies is often in very open waters, it is a big problem to recover them after putting in photocatalysts to complete the decomposition of organic matter, and nano-TiO 2 Remaining in water will also cause secondary pollution, so nano-TiO 2 If the problem of separation and recovery from water cannot be solved well, it will greatly limit the production of TiO 2 The widespread use of photocatalysts

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0010] A kind of TiO 2 The method of loading photocatalyst on ferromagnetic metal thin film is prepared by micro-particle magnetron sputtering coating equipment. The particle size range of 1g is 1-100μm, the average particle size is 80μm, and the material density is about 0.3g / cm 3 The hollow microsphere granular material is used as the substrate, and the hollow microsphere is obtained from the floating beads in the fly ash of the thermal power plant. Before the coating, the surface of the hollow microspheres is pre-purified. The treatment steps are 1) first wash the hollow microspheres with a cleaning solution, stir for 10 minutes and then let stand for 3 minutes, then remove the supernatant, and then use deionized Wash with water for three times; 2) Soak with weak alkaline solution at 50-70°C and fully stir for 15 minutes, then wash with deionized water for three times; 3) Soak with weak acid solution and fully stir for 15 minutes at room temperature, then use Wash three ti...

Embodiment 2

[0014] A method of loading TiO2 photocatalysts on ferromagnetic metal thin films, prepared by microparticle magnetron sputtering coating equipment, the specific steps of coating are the same as in Example 1, but first depositing metal Co on the hollow microspheres, pulse power frequency It is 30KHz, the power is 400W, and other conditions are the same as that of depositing metal Ni in Example 1. The second step of depositing metal Ti is the same as Example 1, only the power supply is a pulse power supply, and the power is 400W. The conditions for the third step of depositing titanium oxide film are: fill the vacuum chamber with argon and oxygen at the same time, adjust the flow ratio of argon and oxygen to 4:1, the working pressure in the vacuum chamber is 1.2Pa, and the pulse power frequency is 30KHz; The radiation power is 600W; the substrate temperature is 150°C; the sputtering time is 600 minutes. Other conditions are with example 1. The sample was detected by SEM, XRD a...

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Abstract

A method for loading TiO2 photocatalyst on a ferromagnetic metallic film comprises the steps: hollow microballon particle material is taken as a substrate, ferromagnetic metal Ni or Co is taken as sputtering target material, and the metal Ni or Co is evenly coated on the hollow microballon by magnetron sputtering; then, the coated hollow microballon is taken as the material of the substrate, metal Ti as the sputtering target material, and a layer of metal Ti is evenly coated on the microballon which is plated with a metallic film by sputtering; after that, a vacuum chamber is simultaneously pumped with argon and oxygen to lead the Ti to be oxidized as TiO2 at the same time of sputtering, and the TiO2 is sedimentated on the hollow microballon coated by the metal Ni or Co. The method has the advantages that as the ferromagnetic metal materials are sedimentated on the hollow microballon, the TiO2 photochemical catalyst film material prepared by taking the ferromagnetic metal materials as the substrate can be attracted by a magnetic collector, and is convenient for centralized collection when not in use, so that the metallic film can be recycled, saves resource and avoids the secondary pollution for the environment.

Description

(1) Technical field [0001] The invention relates to a vacuum coating process, in particular to a TiO 2 A method in which photocatalysts are supported on ferromagnetic metal thin films. (2) Background technology [0002] In recent years, the pollution control of water bodies has become a common concern of all countries in the world. People have noticed that the anatase phase TiO 2 The photocatalytic reaction can effectively degrade organic pollutants in water, and this technology has become a sewage treatment method with important application prospects. In the reported use of TiO 2 In the research of photocatalytic degradation of harmful pollutants in water, most of them use TiO 2 Particle dispersion suspension system, because petroleum organic pollutants are insoluble in water and float on the water surface, TiO insoluble in water 2 The density of TiO is greater than that of water, and it will sink to the bottom of the water, so if this suspension system is used, it will...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C14/35B01J21/06
Inventor 范洪涛许可俞晓正王莉
Owner CHINA NAT ACAD NANOTECH & ENG
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