Integrative electroplating waste treatment process

A technology of electroplating wastewater and treatment process, which is applied in metallurgical wastewater treatment, water/sewage treatment, reduced water/sewage treatment, etc. It can solve the problems of different solubility products of heavy metal ions, high operating costs, and high investment in comprehensive electroplating wastewater treatment. Achieve the effects of saving dosage, saving investment and floor area, reducing engineering investment and processing costs

Inactive Publication Date: 2009-07-08
LIDA ENVIRONMENT ENG DALIAN ECONOMIC TECH DEV ZONE
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Problems solved by technology

[0004] The invention discloses a comprehensive electroplating wastewater treatment process, which solves the problem that different heavy metal ions have different solubility products and needs to be treated separately or multiple cycles, solves the problem

Method used

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  • Integrative electroplating waste treatment process
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Embodiment 1

[0026] Example 1: A large-scale electroplating enterprise in Dalian Development Zone discharges 400 tons of comprehensive electroplating wastewater per day, and the influent water quality index:

[0027] Table 1 Water quality of 5 kinds of wastewater Unit: mg / L

[0028]

[0029] treatment techniques such as figure 1 The method shown:

[0030] 1. Comprehensive electroplating wastewater classification collection, treatment of waste acid, waste alkali

[0031] The electroplating wastewater is divided into five categories, namely wastewater containing hexavalent chromium, wastewater containing cyanide, wastewater containing zinc and copper, waste acid and alkali. Wastewater containing hexavalent chromium, wastewater containing cyanide, wastewater containing zinc, nickel, and copper are respectively built into wastewater pools, and the volume of the wastewater pool is designed to be 6-8 times the average hourly water volume of each type of wastewater, that is, the nominal hydr...

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Abstract

The invention discloses a process for treating comprehensive electroplating wastewater, which solves the technical problems existing in the prior process for treating the comprehensive electroplating wastewater. The process comprises the following steps: (1) establishing wastewater disposal basins for the electroplating wastewater by classification, and automatically adding waste acid and waste alkali into the basins; (2) reducing hexavalent chrome for pretreatment; (3) carrying out secondary oxidation decyanation and reduction treatment on wastewater containing cyanogen; (4) mixing pretreated wastewater containing chromium and wastewater subjected to the secondary oxidation decyanation treatment without cyanogen with the comprehensive electroplating wastewater containing copper, nickel and zinc, adjusting the mixed wastewater to neutrality, and adding an NTC coagulating agent into the mixed wastewater; (5) after coagulation, carrying out solid-liquid separation on the wastewater in a high-speed sedimentation tank; and (6) filtering the wastewater which is subjected to the solid-liquid separation in an intermediate water tank, and recycling the qualified wastewater or discharging the qualified wastewater in accordance to standard. The process has the advantages that the problem that different metal ions require respective treatment or multiple circulating treatments because of different concentrations can be solved, the problem of independently setting air flotation to remove oil can be solved, the problem of recycling the waste acid and the waste alkali can be solved; and investment, operating cost and floor area are saved.

Description

technical field [0001] The invention belongs to an electroplating wastewater treatment process, in particular to a comprehensive electroplating wastewater treatment process. Background technique [0002] Electroplating is one of the three major polluting industries in the world today. Electroplating wastewater, especially comprehensive electroplating wastewater, has the characteristics of many types of pollutants, complex components, high toxicity and serious hazards. The main pollutants are various heavy metal ions, cyanide, waste acid and waste alkali, etc. Traditional electroplating wastewater treatment processes such as chemical precipitation, electrolysis, extraction, adsorption, membrane separation, and biological methods all have high investment, high operating costs, complicated management, poor results, and secondary pollution. They are only suitable for Limitations such as specific electroplating wastewater. [0003] The Chinese invention patent published in 2008...

Claims

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Application Information

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IPC IPC(8): C02F9/04C02F1/70C02F1/72C02F1/52C02F1/58C02F103/16
Inventor 刘强张敬郗洪军石林张健
Owner LIDA ENVIRONMENT ENG DALIAN ECONOMIC TECH DEV ZONE
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