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High power lithium iron phosphate cell and manufacturing method thereof

A lithium iron phosphate battery, lithium iron phosphate technology, applied in secondary batteries, battery electrodes, final product manufacturing, etc., can solve the problems of low reversible specific capacity, battery power consumption, low tap density, etc., and achieve an increase in volume ratio. Capacity, increase heat dissipation effect, and reduce the effect of usage

Active Publication Date: 2013-01-02
OPTIMUM BATTERY CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, LiFePO 4 There are two problems in using it as a positive electrode material. One is that the ion diffusion coefficient and electronic conductivity are very low, resulting in poor high-rate charge and discharge performance and low reversible specific capacity; the other is that the tap density is low, resulting in low volume specific capacity.
[0004] In addition, when using traditional methods to manufacture lithium iron phosphate batteries, the electrical impedance of the battery itself cannot be ignored, especially in the case of high current discharge, the large internal resistance of the battery will generate heat, which consumes the power of the battery on the one hand, and on the other hand The heat generated will also significantly affect the discharge performance of the battery, so it is necessary to reduce the internal resistance and increase the heat dissipation capacity

Method used

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  • High power lithium iron phosphate cell and manufacturing method thereof
  • High power lithium iron phosphate cell and manufacturing method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0045] Taking the manufacture of 18650 type 1100mAh lithium iron phosphate battery as an example, the tap density is less than 1.1g / cm 3 , the specific surface area is higher than 18m 2 Lithium iron phosphate powder with a D50 of 0.3 to 1 micron and a carbon content of less than 3% is used as the initial lithium iron phosphate material. It is placed in a closed vacuum container and stirred at a high speed by a mixer. At the same time, the upper part of the vacuum container The spray nozzle sprays a polyvinyl alcohol aqueous solution with a concentration of 5%, and the total amount of the sprayed solution is 1% of the powder weight, and lasts for 1 hour until the material is semi-dry granular, and the particle diameter is 1mm.

[0046] The granulated powder is treated at 700°C for 4 hours under the protection of flowing inert gas to obtain a high tap density lithium iron phosphate product. After measurement, the average particle size of the product is 8-15μm, and the tap densi...

Embodiment 2

[0052] Taking the manufacture of 18650 type 1300mAh lithium iron phosphate battery as an example, the selected tap density is less than 1.1g / cm 3 , the specific surface area is higher than 18m 2 Lithium iron phosphate powder with a D50 of 0.3 to 1 micron and a carbon content of less than 3% is used as the initial lithium iron phosphate material. It is placed in a closed vacuum container and stirred at a high speed by a mixer. At the same time, the upper part of the vacuum container The concentration of the spray nozzle is 0.5% ethanol solution of epoxy resin, the total amount of the sprayed solution is 10% of the powder weight, and lasts for 4 hours, until the material is semi-dry granular, and the particle diameter is 0.5mm.

[0053] The granulated powder is treated at 650°C for 10 hours under the protection of flowing inert gas to obtain high tap density lithium iron phosphate. After measurement, the average particle size of the product is 6-13μm, and the tap density is 2.3...

Embodiment 3

[0059] Taking the manufacture of 18650 type 1300mAh lithium iron phosphate battery as an example, the selected tap density is less than 1.1g / cm 3 , the specific surface area is higher than 18m 2 Lithium iron phosphate powder with a D50 of 0.3 to 1 micron and a carbon content of less than 3% is used as the initial lithium iron phosphate material. It is placed in a closed vacuum container and stirred at a high speed by a mixer. At the same time, the upper part of the vacuum container The spray nozzle sprays out a methanol solution with a concentration of 10% phenolic resin. The total amount of the sprayed solution is 2% of the powder weight, and lasts for 1 hour until the material is semi-dry and granular, and the particle diameter is 0.8mm.

[0060] The granulated powder is treated at 700°C for 4 hours under the protection of flowing inert gas to obtain high tap density lithium iron phosphate. After measurement, the average particle size of the product is 7-15μm, and the tap d...

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Abstract

The invention provides a high power lithium iron phosphate battery and a production method thereof. The battery comprises a positive plate, a negative plate and a diaphragm. The positive plate is composed of coating a positive slurry on a positive afflux body, and the negative plate is composed of coating a negative slurry on a negative afflux body. An active material in the positive slurry is made by high speed mixing the submicron lithium iron phosphate powder and simultaneously spraying a high polymer solution for the granulation, and then performing a sintering treatment. The final end section of the negative plate is a bare afflux body without coating the negative slurry. The tap density of the submicron lithium iron phosphate powder is less than 1.1 g / cm <3>, and the specific surface area thereof is greater than 18 m <2> / g. The D50 of the lithium iron phosphate powder is 0.3 to 1 micron, and the carbon content thereof is less than 3%. The invention performs a pre-treatment to the active material, improves the electric conductivity of the positive plate, reduces the use amount of an adhesive and a conductive agent in the plate, thereby increasing a specific volumetric capacity. The structure design enables the negative afflux to cling to a steel housing, which increases a current path and an electrical core heat dispersion effect.

Description

technical field [0001] The invention relates to the technical field of lithium ion secondary battery manufacturing. Background technique [0002] LiFePO with olivine structure 4 Lithium ions in the crystal can be in FeO 6 Octahedron and PO 4 Free movement in the tetrahedral structure, with reversible lithium ion deintercalation / intercalation. When 1 mole of lithium ions are deintercalated from the structure, the theoretical discharge specific capacity of lithium iron phosphate is as high as 169mAh / g, the discharge platform is 3.4V-3.5V, the theoretical volume density is 3.6 g / cm3, and the volume energy density is 2.1 Wh / cubic centimeter. In addition, since lithium, iron, and phosphorus are all elements with abundant reserves on the earth, especially iron-based materials have a wide source of raw materials, low prices, and are environmentally friendly, LiFePO 4 It has the prospect of becoming the cathode material of the next generation lithium ion battery. Moreover, it ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M10/40H01M4/02H01M4/48H01M4/58H01M4/62H01M4/64H01M4/26H01M10/38
CPCY02E60/124Y02E60/122Y02E60/10Y02P70/50
Inventor 赵兵李瑶
Owner OPTIMUM BATTERY CO LTD