Heat resisting low expansion silumin and preparation thereof

A high-silicon aluminum alloy and low-expansion technology, which is applied in the field of non-ferrous metal materials and their preparation and forming, can solve the problems of few practical applications, difficult adaptation of aluminum alloys, and many research results, and achieve the goal of improving comprehensive performance and good wear resistance Effect

Inactive Publication Date: 2009-08-12
HUAZHONG UNIV OF SCI & TECH
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

In China, there are still many research results and few practical applications.
At present, the aluminum alloys of A390, ZL108, ZL109 and other grades widely used in China are increasingly difficult to meet the needs of the development of the modern transportation industry, and there is an urgent need to develop new aluminum alloy materials and corresponding production processes

Method used

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  • Heat resisting low expansion silumin and preparation thereof
  • Heat resisting low expansion silumin and preparation thereof

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preparation example Construction

[0028] The preparation of the heat-resistant low-expansion high-silicon aluminum alloy includes two processes of smelting and modification. Materials of Si, Mn, RE, and phosphorus elements usually use their intermediate alloys. Si is usually made of aluminum-silicon master alloy, or industrial pure aluminum ingot plus crystalline silicon, Mn is made of aluminum-manganese master alloy, RE is made of aluminum-rare-earth master alloy, and phosphorus element is made of phosphor-copper master alloy. Before starting the preparation, the raw materials are prepared according to the above mass percentages for use. Due to the need for metamorphic treatment during the preparation process, a large amount of P will be burned during the metamorphic treatment process, so P should be added in excess, that is, the amount of phosphorus added is 0.04 to 0.1% of the total weight of the raw materials, so that the prepared high-silicon aluminum The actual content of P in the alloy is 0.006-0.04%. ...

Embodiment 1

[0033] Put No. A00 pure Al, 99.9% (mass fraction, the same below) pure Ni, 99.99% pure Cu, and Al-25.8% Si master alloy into the melting furnace to melt it into an aluminum-silicon alloy melt. Then the alloy melt is superheated to 850°C, and Al-10%Mn master alloy is added. Then heat to dissolve and stir evenly to obtain a mixed melt; after that, adjust the melt temperature to 780°C and add 99.9% pure Mg, and the obtained alloy composition is Al-20Si-2Cu-1Ni-0.4Mg-0.5Mn-1.0RE -0.01P, the rest is Al. Add Al-15% RE master alloy after melting, the content of Ce in RE is 50%, so that the final RE content of the aluminum alloy is 1.0%, which mainly plays the role of eutectic Si modification. Refining the melt with pure Ar gas at 820°C, removing slag, and standing for 10 minutes. Phosphor-bronze master alloy is added to modify the primary crystal Si, and the amount of P added is 0.06% of the total weight of the raw material, so that the final content of P is about 0.01%. Keep warm...

Embodiment 2

[0035] Put No. A00 pure Al, No. 1 crystalline silicon, 99.9% (mass fraction, the same below) pure Ni, and 99.99% pure Cu into the smelting furnace to melt it into an aluminum-silicon alloy melt. Then the alloy melt is superheated to 870°C, and Al-10%Mn master alloy is added. Then heat to dissolve and stir evenly to obtain a mixed melt; after that, adjust the melt temperature to 800°C and add 99.9% pure Mg, melt in a crucible resistance furnace, and prepare the alloy composition as Al-25Si-2.5Cu-0.5Ni- 0.8Mg-0.6Mn-0.8RE-0.04P, the rest is Al. Al-10% RE is added after melting, and the Ce content in RE is 65%, so that the final RE content of the aluminum alloy is 0.8%, which mainly plays the role of eutectic Si modification. Refining the melt with pure Ar gas at 820°C, removing slag, and standing for 10 minutes. Phosphor-bronze master alloy is added to modify the primary crystal Si, and the amount of P added is 0.10% of the total weight of the raw material, so that the final co...

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Abstract

The invention belongs to the field of non-ferrous materials and preparation and formation thereof, and relates to heat-resisting low-expansion high-silicon cast aluminum alloy. The alloy comprises the following compositions in percentage by mass: 18 to 25 percent of silicon, 1.0 to 2.5 percent of copper, 0.2 to 0.8 percent of magnesium, 0.5 to 2.5 percent of nickel, 0.3 to 0.6 percent of manganese, 0.3 to 1.0 percent of misch metal RE (the content of cerium is more than 40 percent), 0.006 to 0.04 percent of phosphorus, and the balance of aluminum. The production method comprises: firstly, melting raw materials of copper, nickel, silicon and aluminum into an aluminum silicon alloy fused mass; secondly, re-superheating the aluminum silicon alloy fused mass to the temperature of between 850 and 870 DEG C, adding manganese raw materials, and obtaining a mixed fused mass after uniform melting; thirdly, adjusting the temperature of the mixed fused mass to between 780 and 800 DEG C and adding the magnesium into the mixed fused mass; fourthly, adding rare earth raw materials into the mixed fused mass, maintaining at the temperature for 10 to 15 minutes, and raising the temperature to between 820 and 840 DEG C; fifthly, performing refining; and sixthly, raising the temperature of the refined mixed fused mass to between 830 and 850 DEG C, adding phosphorus raw materials into the mixed fused mass for modification, maintaining at the temperature for 15 to 20 minutes after modification, and performing casting, wherein the casting temperature is between 790 and 830 DEG C. Castings can well meet the performance requirements of peripheral materials of automobile engines after T6 heat treatment.

Description

technical field [0001] The invention belongs to the field of non-ferrous metal materials and their preparation and molding, and relates to a cast aluminum-silicon alloy material used at high temperature, that is, a heat-resistant low-expansion high-silicon cast aluminum alloy and a preparation method thereof. Background technique [0002] At present, the design of automobile engines is developing in the direction of high speed and low energy consumption. The engine speed and temperature increase, so the requirements for engine piston materials and cylinder materials are correspondingly increased, mainly focusing on heat resistance, wear resistance, and corrosion resistance. Good performance, small thermal expansion, light weight, etc., so it is particularly important to choose suitable materials. Many cars use aluminum alloy materials for engine pistons, radiators, oil pans, cylinder blocks and cylinder heads, crankcases, filters and other components. There are roughly four...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C21/02C22C1/02C22C1/03C22C1/10
Inventor 吴树森万里毛有武姜华文钟鼓
Owner HUAZHONG UNIV OF SCI & TECH
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