Cured resin for artificial quartz and preparation of artificial quartz

An artificial quartz stone and resin curing technology, applied in the field of artificial quartz stone, can solve the problems of poor transparency and anti-fouling ability, not very outstanding product performance, and low hardness of polyester resin, so as to achieve low resin content and small internal stress , the effect of slowing down the curing speed

Active Publication Date: 2010-11-03
上海新天和树脂有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] 1. Due to the manual or semi-mechanical (jetting) operation, the labor intensity is high, the efficiency is low, and the production cycle is long;
[0004] 2. Since the pigment, color paste, etc. are added manually, and the stirring is not even uniform, the resulting product will not be very stable;
[0005] 3. Since most of the materials used are aluminum hydroxide and calcium carbonate with high oil absorption rate, the relative proportion of resin added will be very high, between 30% and 50%, the cost is high, and the product performance is not very outstanding
However, polyesterable resins with reduced shrinkage obtained by this method have the disadvantages of low hardness, poor transparency and stain resistance of the product.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0055] A cured resin for artificial quartz stone, the cured resin is liquid at normal temperature, and is made by condensation reaction of polyhydric alcohol with saturated acid and unsaturated acid. The reaction system and styrene are calculated as follows in weight percentage:

[0056] Propylene Glycol 16%

[0057] Ethylene glycol 9%

[0058] Glycerol 3%

[0059] Phthalic anhydride 27%

[0060] Maleic anhydride 14%

[0061] Styrene 31% (45% by weight percentage of the above-mentioned alkyd reaction system)

[0062] According to the above-mentioned alkyd reaction system mass percentage, add the following components:

[0063] High temperature stabilizer 60ppm

[0064] Antioxidant 25ppm

[0065] Chain terminator 30ppm.

[0066] The preparation method is that propylene glycol, ethylene glycol, glycerin, phthalic anhydride, and maleic anhydride are added to the reaction pot at one time for polycondensation reaction. After 10 hours of polycondensation, the reaction degree r...

Embodiment 2

[0068] A cured resin for artificial quartz stone, the cured resin is liquid at normal temperature, and is made by condensation reaction of polyhydric alcohol with saturated acid and unsaturated acid. The reaction system and styrene are calculated as follows in weight percentage:

[0069] Propylene Glycol 15%

[0070] Ethylene glycol 6%

[0071] Glycerol 3%

[0072] Diethylene glycol 8%

[0073] Phthalic anhydride 26%

[0074] Maleic anhydride 13%

[0075] Styrene 29% (40% by weight percentage of the above-mentioned alkyd reaction system)

[0076] According to the above-mentioned alkyd reaction system mass percentage, add the following components:

[0077] High temperature stabilizer 100ppm

[0078] Antioxidant 40ppm

[0079] Chain terminator 50ppm.

[0080] The preparation method is that propylene glycol, ethylene glycol, glycerol, diethylene glycol, phthalic anhydride, and maleic anhydride are added to the reaction pot at one time for polycondensation reaction. After ...

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Abstract

The invention provides a cured resin for artificial quartz and the artificial quartz prepared by the cured resin, which relate to the cured resin for the artificial quartz and the artificial quartz prepared by the cured resin, in particular to a method for preparing the artificial quartz which has easy formability and appearance similar to marmoreal. The cured resin for the artificial quartz is in liquid state at normal temperature, and is prepared by a condensation reaction of polylol, saturated acid and unsaturated acid; an alcohol acid reaction system comprises the following components in percentage by weight: 37 to 47 percent of the polylol, 35 to 40 percent of saturated acid or estolide, and 18 to 23 percent of unsaturated acid or estolide, wherein 30 to 45 percent of cross-linking agent is added into the alcohol acid reaction system; the saturated acid or estolide is phthalic acid or phthalic anhydride; and the unsaturated acid or estolide is maleic acid or maleic anhydride. Thecured resin for the artificial quartz can be used for preparing the artificial quartz, has sufficient curing, small internal stress inside the product and performance capable of reaching maximum.

Description

technical field [0001] The cured resin for artificial quartz and the prepared artificial quartz of the present invention relate to a cured resin for artificial quartz, a method for preparing the cured resin, an artificial quartz prepared by using the cured resin and a method for preparing the artificial quartz, in particular to a A method for the preparation of artificial quartz stones that are easy to form and are used to produce a marble-like appearance. Background technique [0002] The main feature of artificial marble is that fillers such as stone powder or crushed glass or quartz sand are mixed with unsaturated polyester resin pigments, and then solidified by adding curing agents and accelerators. The main disadvantages of these production processes and marble products made from them are : [0003] 1. Due to the manual or semi-mechanical (jetting) operation, the labor intensity is high, the efficiency is low, and the production cycle is long; [0004] 2. Since the pi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B14/06C04B26/02C08F283/01
Inventor 林定多麻慎荣何炜
Owner 上海新天和树脂有限公司
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