Daily-used fine porcelain with high property and preparation method thereof

A high-performance, daily-use technology, applied in the field of daily-use ceramics, can solve the problems of poor molding performance, reduced product mechanical strength, poor light transmittance, etc., and achieve the effect of good blank molding performance, easy industrialization and promotion, and improved mechanical strength.

Active Publication Date: 2010-03-10
JINGDEZHEN CERAMIC INSTITUTE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the existing bone china, talc and high-quartz porcelain meet the requirements of high whiteness, high transparency and high strength, they all have two common shortcomings: one is that the thermal expansion coefficients of the three are very large, and bone china, The expansion coefficients of steatite porcelain and high quartz porcelain are 8~9×10 -6 /℃, 7.8~8×10 -6 /℃ and 7.5~8.0×10 -6 /°C
For steatite porcelain and high-quartz porcelain, if the ratio of glass phase to crystal phase, crystal phase particle size and crystal phase transformation in the porcelain body are not well controlled, their thermal stability is difficult to achieve after 180 ° C ~ 20 ℃ water heat exchange once the standard without cracking
The second shortcoming of these three types of high-grade daily-use fine porcelain is that it is difficult to control the process.
For example, both bone china and talc porcelain have the fatal weaknesses of poor molding performance and narrow firing range; high-quartz porcelain has problems such as high requirements for quartz particle gradation, and the amount of cristobalite in the porcelain body is difficult to control.
[0003] The usual feldspar-quartz-kaolin ternary system and sericite-quartz-kaolin ternary system high-grade daily-use fine porcelain have the advantages of high thermal stability, good molding performance, and wide firing range, but they cannot combine high whiteness, High transparency and high strength in one
In these two ternary system porcelain bodies, the two performance requirements of "high strength" and "high transparency" are contradictory in the prep...

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] Weigh various raw materials according to the blank formula: kaolin 40%, quartz 18%, potash feldspar 15%, antireflection agent 9%, alumina 18%, and the chemical composition of the blank: SiO 2 53.81%, Al 2 O 3 38.55%, K 2 O2.63%, Na 2 O 1.06%, CaO 1.82%, MgO 0.81%, P 2 O 5 1.32%. The anti-reflective agent is a clinker composed of 49% albite, 20% ashes, 12% calcite and 16% burnt talc. Put the above-mentioned raw materials into a ball mill, mix and grind to the required fineness (that is, the cumulative percentage of particles below 10μm accounts for more than 90%), and then proceed to sieving, iron removal, pressure filtration, mud smelting, staleness, and molding in order. High-temperature biscuit firing at ℃~1320℃, after polishing and selection, frit glaze is applied, and then glaze firing at 1160℃~1200℃, and finally a new high-performance daily fine porcelain with "high whiteness, high permeability and high strength" is obtained.

Embodiment 2

[0017] Weigh various raw materials according to the blank formula: kaolin 45%, quartz 22%, potash feldspar 10%, antireflection agent 10%, alumina 13%, and the chemical composition of the blank: SiO 2 59.18%, Al 2 O 3 33.66%, K 2 O1.07%, Na 2 O 1.21%, CaO 2.50%, MgO 0.95%, P 2 O 5 1.43%, the anti-reflective agent is a frit composed of 45% albite, 25% bone ashes, 15% calcite and 18% burnt talc.

[0018] The production process is the same as in Example 1.

Embodiment 3

[0020] Weigh various raw materials according to the blank formula: kaolin 41%, quartz 20%, potash feldspar 12%, antireflection agent 12%, alumina 15%, and the chemical composition of the blank: SiO 2 55.63%, Al 2 O 3 35.50%, K 2 O1.32%, Na 2 O 1.49%, CaO 3.05%, MgO 1.41%, P 2 O 5 1.60%, the anti-reflective agent is a frit composed of 47% albite, 23% bone ashes, 18% calcite and 19% burnt talc. The production process is the same as in Example 1.

[0021] The properties of the products prepared by the above embodiments are as follows:

[0022] Main performance index

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PUM

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Abstract

The invention belongs to the technical field of daily-used ceramics, relating to daily-used fine porcelain with high property and a preparation method thereof. The chemical constituents of the daily-used fine porcelain are 52-60% of SiO2, 32-40% of Al2O3, 1-3% of K2O, 1-3% OF Na2O, 1.5-3.5% of CaO, 0.5-1.5% of MgO and 1-2% of P2O5. The adopted raw material formulation is as follows: 40-45% of kaoline, 15-25% of quartz, 10-15% of potassium feldspar, 10-20% of alumina and 8-15% of antireflective agent. The daily-used fine porcelain of the invention integrates three characteristics of high strength, high white and high transparence, and has the characteristics of good molding property, wide sintering arrange and high thermal stability and the like, thereby overcoming the defect of bad light transmittance of normal strengthened porcelain, and solving the problems of uneasy molding and narrow sintering arrange of high-grade porcelain such as steatite porcelain and bone porcelain. The porcelain is sintered at the temperature of 1270-1320 DEG C, is easy to be produced and promoted, and is hopeful to become novel high-grade daily-used fine porcelain after bone porcelain and steatite porcelain.

Description

Technical field [0001] The invention belongs to the technical field of daily-use ceramics, and relates to a high-performance daily-use fine porcelain and a production method thereof. Background technique [0002] High whiteness, high transparency and high strength have always been the goals pursued by domestic and foreign advanced daily fine porcelain. Although the existing bone ash porcelain, talc porcelain and high quartz porcelain meet the requirements of high whiteness, high permeability and high strength, they all have two common shortcomings: one is that the thermal expansion coefficients of the three are very large. The expansion coefficients of talc porcelain and high quartz porcelain are 8~9×10 respectively -6 / ℃、7.8~8×10 -6 / ℃ and 7.5~8.0×10 -6 / ℃. The greater the thermal expansion coefficient of ceramics, the greater the thermal stress that it generates with temperature changes, and as a result, the thermal stability of the product is likely to be poor. For example, t...

Claims

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Application Information

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IPC IPC(8): C04B33/00C04B33/24
Inventor 江伟辉包镇红谭训彦苗立锋虞澎澎刘健敏
Owner JINGDEZHEN CERAMIC INSTITUTE
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