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High-temperature oxidation resistant coating for steel with high nickel content

A high-temperature oxidation-resistant, nickel-steel technology, applied in the direction of fire-proof coatings, alkali metal silicate coatings, coatings, etc., can solve the problems of decreased anti-oxidation effect of coatings, increased surface defects of plates, and difficult removal of iron oxide scales, etc., to achieve improved Product surface quality, adhesion reduction, effect of adhesion reduction

Inactive Publication Date: 2010-05-12
WUHAN IRON & STEEL (GROUP) CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in this method, when the temperature of the heating furnace exceeds 1300°C, or the residence time of the billet in the heating furnace is too long due to equipment failure (for example, the residence time exceeds 300 minutes), the anti-oxidation effect of the coating will drop sharply, resulting in surface defects of the rolled plate. Increase
In addition, this method is still not easy to remove the oxide scale when the high-pressure water descaling is performed on the alloy steel with a nickel content higher than 4.0%.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] Example 1: Take quartz powder (SiO 2 Content 95%) 15kg, periclase powder (MgO content 82%) 8.5kg, alumina powder (Al 2 O 3 Content 98%) 22kg, zircon powder (ZrO 2 Content 60%, SiO 2 Content 38%) 8.5kg, chromium iron powder (Cr content 70%) 46kg, mixed and ball milled in a ball mill to -500 mesh size for use. Add 15 kg of sodium silicate (modulus 3.0) with a concentration of 45 Baume degrees and 30 kg of water into the coating reaction kettle, and then add the ball-milled coating powder while stirring to obtain a high-nickel steel anti-oxidation coating.

Embodiment 2

[0015] Example 2: Mix 35 kg of aluminum dihydrogen phosphate with 30 kg of water and pour it into a container. While stirring, add 325 mesh silicon oxide powder (SiO 2 Content 98.5%) 10kg, 325 mesh periclase powder (MgO content 80%) 5kg, 325 mesh high bauxite (Al 2 O 3 Content 80%) 30kg, 300 mesh iron chromium powder (Cr content 70%) 55kg. If the high nickel-containing steel anti-oxidation coating is not used immediately, 5kg of bentonite anti-coating precipitation should be added to the above components.

Embodiment 3

[0016] Example 3: Add 35 kg of aluminum dihydrogen phosphate, 30 kg of water, and 10 kg of silica sol in the container in sequence to prepare a high-temperature adhesive, and then add alumina powder (1250 mesh Al 2 O 3 Content 98%) 35kg, silica powder (1250 mesh SiO 2 Content 98.5%) 15kg, zirconia powder (1000 mesh ZrO 2 Content 98%) 15kg, chromium trioxide (800 mesh Cr 2 O 3 The content is 98%) 35kg, which is a high-temperature oxidation resistant coating for high nickel steel.

[0017] Spray, roll or brush the high-nickel steel anti-oxidation paint obtained in the above example 1 on the surface of alloy steel billet with a nickel content of 4-6% to reach a certain film thickness (0.5-1.0mm). The coating environment does not have any special requirements. It can be coated at any temperature below 400℃. After coating, it will naturally dry at ambient temperature. There is no special requirement for the working viscosity of the coating, as long as it can be coated to the required co...

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PUM

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Abstract

The invention relates to a high-temperature oxidation resistant coating for steel with high nickel content, which is characterized by being prepared by mixing mixed powder of silicon oxide, alumina, chromium-containing iron powder, magnesia and zirconium oxide with high-temperature adhesive, wherein the mixed powder contains the ingredients in percentage by mass as follows: 10-25% of SiO2, 20-35% of Al2O3, 35-60% of chromium-containing powder, 0-15% of MgO, and 20-15% of ZrO2, wherein the content of the MgO and the ZrO2 can not be 0 simultaneously. The high-temperature oxidation resistant coating has the beneficial effects that by using the coating, iron oxide sheet generated in the heating process of alloy steel billet with the nickel content above 4% can be reduced, and more importantly, the adhesive force of the iron oxide sheet of the steel billet is greatly reduced and can be basically removed under the condition of the existing processing equipment, thus reducing the scrap rate caused by the iron oxide sheet by above 50%.

Description

Technical field [0001] The invention relates to a water-based inorganic high-temperature resistant coating used to slow down the surface oxidation of a nickel-containing steel billet during the heating process and make the oxide scale easy to remove. Background technique [0002] Iron oxide scale is an unavoidable defect on the surface of steel plates in hot rolling production. For nickel-containing steel plates, iron oxide scale is particularly harmful, especially when the area is large, the iron scale is thick, and it is difficult to remove with existing equipment and methods, manual grinding wheels are required. Machine repair and grinding are time-consuming and labor-intensive, and affect the surface quality of the steel plate, and even cause the steel plate to waste. Therefore, how to reduce and effectively remove the oxide scale of the billet after heating has always been one of the difficult problems for hot rolling enterprises to overcome. [0003] At present, one of the m...

Claims

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Application Information

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IPC IPC(8): C09D1/00C09D1/02C09D5/18
Inventor 詹胜利张炼梁文黄大军周光武任池锦
Owner WUHAN IRON & STEEL (GROUP) CORP
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