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Bamboo alpha-pulp for viscose and production method thereof

A production method and technology of bamboo pulp, applied in the field of bamboo pulp for viscose and its production, can solve the problems of insufficient fiber purity, increased consumption, and increased waste rubber rate, and achieve good reaction performance and uniform oxidation , reduce the effect of hemifiber increase

Inactive Publication Date: 2010-06-16
TANGSHAN SANYOU GRP DONGGUANG PULP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

"Although the bamboo pulp made by the above two methods can be used for viscose fiber, although the process of boiling + caustic soda is simple, the content of the first fiber in the bamboo pulp is only 79-91.2%, indicating that the fiber purity reaches If the fiber content of cotton pulp and wood pulp is less than the standard, it is not conducive to the quality control of downstream viscose production and increases consumption. Moreover, due to the high content of semi-fiber and other impurities, the reactivity of bamboo pulp cannot pass. In the viscose production process It is difficult to make rubber in the middle, and the rate of waste rubber increases. Only by mixing bamboo pulp, cotton pulp, and wood pulp can the production be ensured, which affects the purity of bamboo pulp fibers and is not conducive to bamboo pulp replacing cotton and wood pulp. large-scale production of bamboo pulp

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] Preparation: First, use a bamboo cutting machine to crush the bamboo into bamboo pieces with a length of 30 mm and a width of 20 mm. Soak them in clean water at room temperature and pressure for 10 hours to make them fully absorb water and swell to facilitate cooking. Rinse with water to remove impurities such as dust and dust to reduce the burden of cooking. , Improve slurry purity.

[0030] One-time cooking: long 30mm through the purification process, the small bamboo chips of wide 20mm are packed in the digester, the caustic soda consumption accounts for 15% (percentage of sodium hydroxide and dry raw material) of absolute dry slurry, and degree of sulfidation is 15% (sulfurized Sodium content to the percentage of sodium hydroxide and sodium sulfide total amount (calculated as sodium oxide)), liquid ratio 1: 2.5, heating time: 150 minutes, holding time: 100 minutes, holding temperature 180 ℃.

[0031] Secondary cooking: After fully washing, dehydrating, and drying th...

Embodiment 2

[0038] Preparation: First, use a bamboo cutting machine to crush the bamboo into bamboo pieces with a length of 20mm and a width of 10mm. Soak them in clean water at room temperature and pressure for 9 hours to make them fully absorb water and swell to facilitate cooking, and remove dust, dust and other impurities by washing with water to reduce the burden of cooking. , Improve slurry purity.

[0039] One-time cooking: the small bamboo chips through the purification process are packed into the digester, the caustic soda consumption accounts for 17% (the percentage of sodium hydroxide and the absolute dry material) of the absolute dry slurry, and the degree of sulfidation is 10% (the ratio of the amount of sodium sulfide to sodium hydroxide and the percentage of the total amount of sodium sulfide (calculated as sodium oxide)), the liquid ratio is 1:3, the heating time: 120 minutes, the holding time: 130 minutes, and the holding temperature is 168°C.

[0040] Secondary cooking: ...

Embodiment 3

[0047] Preparation: First, use a bamboo cutting machine to crush the bamboo into bamboo pieces with a length of 25mm and a width of 15mm, soak them in clean water at room temperature and pressure for 8 hours to make them fully absorb water and expand for cooking, and remove dust, dust and other impurities by washing with water to reduce the burden of cooking , Improve slurry purity.

[0048] One-time cooking: the small bamboo chips through the purification process are packed into the digester, the caustic soda consumption accounts for 20% (the percentage of sodium hydroxide and the absolute dry material) of the absolute dry slurry, and the degree of sulfidation is 5% (the ratio of the amount of sodium sulfide to sodium hydroxide and the percentage of the total amount of sodium sulfide (calculated as sodium oxide)), the liquid ratio is 1:4, the heating time: 150 minutes, the holding time: 150 minutes, and the holding temperature is 165°C.

[0049] Secondary cooking: After fully...

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Abstract

The invention discloses a bamboo alpha-pulp for viscose and a production method thereof. Main quality indexes of a bamboo pulp finished product are that: the degree of polymerization is 500 to 600 DP, alpha cellulose is more than or equal to 92 percent, ash is less than or equal to 0.20 percent, iron is less than or equal to 30 ppm, and the reaction performance is less than or equal to 200s. The production method comprises the following steps: preparing materials, stewing, bleaching, acidating and pulping. The stewing method adopts two-time different processes. The primary stewing adopts a sulfate method and the secondary stewing adopts a pure caustic soda method. The primary stewing can effectively dissolve the lignin in bamboo chips, remove the alkaline lignin and alkali soluble impurities through multistage washing, and reduce the pollution. The secondary stewing further removes hemicellulose and residual lignin, purifies the alpha cellulose, and guarantees that the reaction performance of the bamboo alpha-pulp can totally pass. The production method greatly improves the content of the alpha cellulose and reaction performance passing speed of the bamboo alpha-pulp, reduces the discharge of the stewing waste liquor, and provides a basis for further improving the yield and quality of bamboo fibers in chemical fiber production.

Description

technical field [0001] The invention relates to a bamboo pulp made from bamboo and a manufacturing method thereof, in particular to a bamboo pulp for viscose and a manufacturing method thereof. Background technique [0002] The traditional regenerated fibers are pulped from coniferous wood and cotton linters and then made into fibers by the "viscose method". Due to the lack of forest resources and limited cotton fields in my country, the development scale of traditional natural fibers is limited, and the production of viscose fibers from cotton pulp and wood pulp is restricted. Therefore, people gradually shift their attention to the development and utilization of new natural fibers, and it has become a development trend to seek new raw materials for regenerated fibers. The fiber content of bamboo reaches about 40-50%, which is a better natural fiber raw material. my country's bamboo resources account for nearly a quarter of the world's bamboo resources, and it is the larg...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F2/06D21C3/26
Inventor 毕绍新王忠学夏武臣张宝恒陈玉彬姬荣亮吴红帅孟令华靳朝晖彭利民郭新宾马静
Owner TANGSHAN SANYOU GRP DONGGUANG PULP CO LTD
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