Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Use of polymer composition in removing heavy metal ions of fruit and vegetable juice

A technology of heavy metal ions and complexes, applied in the direction of food science, etc., can solve problems such as the influence of nutritional components, the destruction of nutritional components, and the single selectivity of chelating resin method, and achieve the effect of quick results and reduced content of heavy metal ions

Inactive Publication Date: 2010-08-25
BEIJING OKEANOS TECH
View PDF2 Cites 10 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The adsorption method is easy to adsorb the beneficial nutrients in fruit juice and vegetable juice, but it is difficult to adsorb heavy metal ions, so the application of the adsorption method is greatly limited.
At the same time, it is easy to cause secondary pollution, and the regeneration cycle of the adsorbent is not easy to realize
[0007] The ion exchangers used in the ion exchange treatment generally show a certain acidity and alkalinity, which has a certain destructive effect on the beneficial nutrients in fruit juices and vegetable juices; at the same time, the charges carried by the ion exchangers themselves may also affect the juice It will affect the nutrients in the vegetable juice, and it is easy to cause the fruit juice and vegetable juice to be cloudy
This limits the application of ion exchange in the removal of heavy metal ions from fruit and vegetable juices
[0008] The selectivity of the chelating resin method is single, because the lead, cadmium, mercury and copper elements in fruit juice and vegetable juice generally exist in the form of cations, but arsenic can exist in the form of cations and anions. The relatively complex existence of heavy metals makes it necessary to use a variety of chelating resins in combination, which not only increases the cost and prolongs the operation time, but also makes it difficult to realize the regeneration cycle of the chelating resin. At the same time, the chelating resin may have low mechanical properties. , poor thermal stability and other disadvantages
[0009] The research on the removal of heavy metal ions by biochemical methods has just started, the theory of this method is not yet mature, the composition of cell components involved in metal complexation and the biosynthesis process are still unclear, and the kinetics of heavy metal elements being adsorbed or complexed is lacking. data, and cannot carry out process design and scale-up and economic balance, etc.
Therefore, there is no industrialized example of this technology in removing heavy metals from fruit and vegetable juices

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] Example 1 Preparation and application of polyurethane foam loaded with methyl hexamethylene dithiocarbamate

[0041] Raw materials: toluene diisocyanate 80 / 20, produced by BASF; polyether polyol, Shell SC5601 type; polymer polyol, Shanghai Gaoqiao Petrochemical Company GPOP-2402 type; amine catalyst, gas company type A1 / A33; surface Activator, Dow Corning Company L-580 type; tin catalyst, Gas Company T9 type.

[0042] Preparation:

[0043] 1. Weigh 60 grams of toluene diisocyanate 80 / 20 in a plastic beaker.

[0044] 2. Weigh 90 grams of polyether polyol and 10 grams of polymer polyol and pour them into a 1-liter beaker.

[0045] 3. Weigh 5 grams of deionized water, 0.25 grams of amine catalyst, 1.0 grams of surfactant and 20 grams of dichloromethane, add them to a 100 ml beaker, stir until the mixture becomes clear, and use it as the activation agent used in the foaming process. agent mixture.

[0046] 4. Add the activator mixture into a 1-liter beaker filled with p...

Embodiment 2

[0061] The preparation and application of the polyurethane foam of embodiment 2 load Schiff base type chitosan

[0062] Raw materials: toluene diisocyanate 80 / 20, produced by BASF; polyether polyol, GEP560 type of Shanghai Gaoqiao Petrochemical Company; polymer polyol, GPOP-2402 type of Shanghai Gaoqiao Petrochemical Company; amine catalyst, A1 / A33 type; surfactant, gas company DC5810 type; tin catalyst, gas company T9 type.

[0063] Preparation:

[0064] 1. Weigh 65 grams of toluene diisocyanate 80 / 20 in a plastic beaker.

[0065] 2. Weigh 90 grams of polyether polyol and 10 grams of polymer polyol and pour them into a 1-liter beaker.

[0066] 3. Weigh 5.5 grams of deionized water, 0.22 grams of amine catalyst, 0.8 grams of surfactant and 20 grams of dichloromethane into a 100 ml beaker, stir until the mixture becomes clear, as the activator used in the foaming process mixture.

[0067] 4. Add the activator mixture into a 1-liter beaker filled with polyol, and stir vigor...

Embodiment 3

[0084] Preparation and application of the polyurethane foam of embodiment 3 loaded phosphorous acid

[0085] Preparation method: The preparation of the polyurethane foam is the same as in Examples 1 and 2.

[0086] Dissolve trimethyl phosphite in ethanol, add about 1 cm cubic polyurethane foam small pieces (1 gram of polyurethane foam small pieces need 10 grams of phosphorous acid), heat and reflux for 2 hours under vigorous stirring, and filter. The filter cake was vacuum-dried at 50°C for 2 hours to obtain small pieces of polyurethane foam loaded with phosphorous acid, which were stored in a dark sealed glass container for later use.

[0087] Application: Take 1000 ml of carrot juice produced by a certain company, add / add 45 grams of the above-mentioned polyurethane foam, stir vigorously for 75 minutes, filter, and collect the filtrate.

[0088]Use Varian 700 type inductively coupled plasma emission spectrometry (ICP-AES) to measure the heavy metal content in the carrot jui...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses a use of polymer composition in removing heavy metal ions of fruit and vegetable juice. The polymer composition is a compound comprising functional groups capable of providing lone pair electrons in the structure loaded on a polymer carrier; the compound and the heavy metal ions can be formed into coordination bonds, thereby being capable of efficiently, quickly and conveniently removing heavy metal ions of fruit and vegetable juice. The method is simple and easy to use and quick in effect without the defects of the methods normally used such as adsorptive process method, ion-exchange processing method and chelating resin method, and has very strong specificity for absorbing various heavy metal irons but basically not absorbing the active ingredients in fruit and vegetable juice; the content of the heavy metal irons in fruit and vegetable juice after treatment in the method is obviously reduced; the method can reach Sanitation Standard of Fruit and Vegetable Juice Beverage (GB19297-2003), and protects the environment and has industrialized prospect.

Description

technical field [0001] The invention relates to the application of a polymer compound in removing heavy metal ions, in particular to the application of a polymer compound in removing heavy metal ions in fruit and vegetable juices. Background technique [0002] In the past 30 years, with the rapid development of my country's economy, the problem of environmental pollution has become increasingly serious, especially the residue of heavy metals is one of the most serious forms of pollution in our country. Heavy metal pollution refers to environmental pollution caused by heavy metals or their compounds, mainly due to human factors such as mining, exhaust emissions, sewage irrigation, and the use of heavy metal products. After heavy metals pollute soil, air and water, they will enter the food chain and eventually enter the human body. And because of the biomagnification effect, during the progress of the food chain from low-level to high-level, harmful substances such as heavy m...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): A23L2/80
Inventor 许峰高源
Owner BEIJING OKEANOS TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products