Use of polymer composition in removing heavy metal ions of fruit and vegetable juice
A technology of heavy metal ions and complexes, applied in the direction of food science, etc., can solve problems such as the influence of nutritional components, the destruction of nutritional components, and the single selectivity of chelating resin method, and achieve the effect of quick results and reduced content of heavy metal ions
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Embodiment 1
[0040] Example 1 Preparation and application of polyurethane foam loaded with methyl hexamethylene dithiocarbamate
[0041] Raw materials: toluene diisocyanate 80 / 20, produced by BASF; polyether polyol, Shell SC5601 type; polymer polyol, Shanghai Gaoqiao Petrochemical Company GPOP-2402 type; amine catalyst, gas company type A1 / A33; surface Activator, Dow Corning Company L-580 type; tin catalyst, Gas Company T9 type.
[0042] Preparation:
[0043] 1. Weigh 60 grams of toluene diisocyanate 80 / 20 in a plastic beaker.
[0044] 2. Weigh 90 grams of polyether polyol and 10 grams of polymer polyol and pour them into a 1-liter beaker.
[0045] 3. Weigh 5 grams of deionized water, 0.25 grams of amine catalyst, 1.0 grams of surfactant and 20 grams of dichloromethane, add them to a 100 ml beaker, stir until the mixture becomes clear, and use it as the activation agent used in the foaming process. agent mixture.
[0046] 4. Add the activator mixture into a 1-liter beaker filled with p...
Embodiment 2
[0061] The preparation and application of the polyurethane foam of embodiment 2 load Schiff base type chitosan
[0062] Raw materials: toluene diisocyanate 80 / 20, produced by BASF; polyether polyol, GEP560 type of Shanghai Gaoqiao Petrochemical Company; polymer polyol, GPOP-2402 type of Shanghai Gaoqiao Petrochemical Company; amine catalyst, A1 / A33 type; surfactant, gas company DC5810 type; tin catalyst, gas company T9 type.
[0063] Preparation:
[0064] 1. Weigh 65 grams of toluene diisocyanate 80 / 20 in a plastic beaker.
[0065] 2. Weigh 90 grams of polyether polyol and 10 grams of polymer polyol and pour them into a 1-liter beaker.
[0066] 3. Weigh 5.5 grams of deionized water, 0.22 grams of amine catalyst, 0.8 grams of surfactant and 20 grams of dichloromethane into a 100 ml beaker, stir until the mixture becomes clear, as the activator used in the foaming process mixture.
[0067] 4. Add the activator mixture into a 1-liter beaker filled with polyol, and stir vigor...
Embodiment 3
[0084] Preparation and application of the polyurethane foam of embodiment 3 loaded phosphorous acid
[0085] Preparation method: The preparation of the polyurethane foam is the same as in Examples 1 and 2.
[0086] Dissolve trimethyl phosphite in ethanol, add about 1 cm cubic polyurethane foam small pieces (1 gram of polyurethane foam small pieces need 10 grams of phosphorous acid), heat and reflux for 2 hours under vigorous stirring, and filter. The filter cake was vacuum-dried at 50°C for 2 hours to obtain small pieces of polyurethane foam loaded with phosphorous acid, which were stored in a dark sealed glass container for later use.
[0087] Application: Take 1000 ml of carrot juice produced by a certain company, add / add 45 grams of the above-mentioned polyurethane foam, stir vigorously for 75 minutes, filter, and collect the filtrate.
[0088]Use Varian 700 type inductively coupled plasma emission spectrometry (ICP-AES) to measure the heavy metal content in the carrot jui...
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