Preparation method of protonized ionic liquid modified rubber/inorganic filler composite material

A technology of protonated ions and inorganic fillers, which is applied in the field of preparation of protonated ionic liquid modified rubber/inorganic filler composite materials, can solve the problems of interface bonding limiting the performance and influence of composite materials, and achieves improved processing performance and enhanced interfacial interaction. effect, the effect of reducing Mooney viscosity

Inactive Publication Date: 2010-09-15
SOUTH CHINA UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Although polyethylene glycol can improve the dispersion of inorganic fillers, the weak interfacial bonding limits the improvement of the performance of rubber/inorganic filler composites; silane coupling ag

Method used

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  • Preparation method of protonized ionic liquid modified rubber/inorganic filler composite material
  • Preparation method of protonized ionic liquid modified rubber/inorganic filler composite material
  • Preparation method of protonized ionic liquid modified rubber/inorganic filler composite material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] (1) 4-picoline sorbate prepared by mixing 4-picoline and sorbic acid in a molar ratio of 1:1 and reacting at 25° C. for 1 hour.

[0034] (2) According to the basic formula of rubber: styrene-butadiene rubber 100, white carbon black 40, zinc oxide 5, stearic acid 1, dicumyl peroxide (DCP) 1, anti-aging agent 4010na 1.5, 4-picoline sorbic acid salt variable. After blending on a double-roll mill, park overnight and then vulcanize on a flat vulcanizer at 170°C×10min to obtain a 4-picoline sorbate-modified styrene-butadiene rubber / silica composite material.

Embodiment 2

[0036] (1) 1-methylimidazole sorbate prepared by mixing 1-methylimidazole and sorbic acid in a molar ratio of 1:1 and reacting at 25° C. for 1 hour.

[0037] (2) According to the basic formula of rubber: styrene-butadiene rubber 100, halloysite 40, zinc oxide 5, stearic acid 1, dicumyl peroxide (DCP) 1, anti-aging agent 4010na 1.5, 1-methylimidazole sorbic acid salt variable. After blending on a double-roll mill, park overnight and vulcanize on a flat vulcanizer at 170°C×6min to prepare 1-methylimidazolium sorbate-modified styrene-butadiene rubber / halloysite composite material

Embodiment 3

[0039] (1) 2-methylimidazole and α-methacrylic acid were mixed according to a molar ratio of 1:1, and reacted in an ice-water bath for 0.5 hours to obtain colorless and transparent 2-methylimidazole methacrylate.

[0040] (2) According to the basic formula of rubber: styrene-butadiene rubber 100, silica 40, zinc oxide 5, stearic acid 1, cumene peroxide (DCP) 1, antioxidant MB 1.5, 1-methylimidazole methacrylic acid salt variable. After blending on a double-roll mill, park overnight and then vulcanize on a flat vulcanizer at 170°C×8min to prepare 2-methylimidazolium methacrylate modified styrene-butadiene rubber / white carbon black composites.

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Abstract

The invention relates to a preparation method of a protonized ionic liquid modified rubber/inorganic filler composite material, which comprises the steps of: 1, preparing a structure of a functional protonized ionic liquid; and 2, ensuring that the functional protonized ionic liquid is used for an in situ modified inorganic filler reinforced rubber composite material. The invention can effectively lower the agglomeration among strong-polarity inorganic fillers, improves the diffusion of the fillers in a rubber base body, and is beneficial to improving the processing property, the vulcanization characteristic, the mechanical property, the abrasive resistance and the like of the rubber/inorganic filler composite material. The method has the characteristics of popularization and low cost, and can be widely applied to preparing various high-property rubber/inorganic filler composite materials.

Description

technical field [0001] The invention relates to a preparation method of a protonated ionic liquid modified rubber / inorganic filler composite material. technical background [0002] Ultra-fine inorganic fillers (such as silica and clay) have excellent reinforcing effects on various rubbers, and have gained important applications in the fields of light-colored rubber products and green tires. However, the strong polarity and high surface energy of inorganic fillers make their dispersion in the rubber matrix difficult, which not only affects the properties of rubber, but also increases the processing energy consumption. At the same time, in rubber processing, processing aids (such as accelerators, activators, vulcanizing agents, stabilizers) will have serious surface adsorption due to the strong polarity of the surface of ultrafine inorganic fillers, reducing the efficiency of the aids. Therefore, when using ultrafine inorganic fillers to reinforce rubber materials, surface pr...

Claims

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Application Information

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IPC IPC(8): C08L9/06C08K13/02C08K3/36C08K5/3432C08K3/34C08K5/3445C08K5/378
Inventor 郭宝春类延达唐征海
Owner SOUTH CHINA UNIV OF TECH
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