Processing method for high anti-reflective glass for packaging solar battery pack

A technology of solar cells and processing methods, applied in the direction of electrical components, sustainable manufacturing/processing, circuits, etc., can solve the problems of poor adhesion on glass surfaces, poor film layer uniformity, and low stability of sol, and achieve particle prevention Agglomeration, not easy to erase damage and peeling, strong anti-friction effect

Active Publication Date: 2010-09-29
无锡海达光能股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The currently reported anti-reflection coating solutions are generally SiO 2 Sol, which generally has the disadvantages of low sol stability, short shelf life, poor adhesion on the glass surface after coating, and poor mechanical strength; as far as the coating process is concerned, there are generally vacuum sputtering methods, chemical vapor deposition methods, and spraying methods. , Spin coating method, among which vacuum sputtering method and chemical vapor deposition method have high requirements on equipment and high production cost, while spray coating method and spin coating method have disadvantages such as poor film uniformity, low surface quality, and difficult control.

Method used

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  • Processing method for high anti-reflective glass for packaging solar battery pack
  • Processing method for high anti-reflective glass for packaging solar battery pack

Examples

Experimental program
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Effect test

Embodiment 1

[0018] At room temperature, dissolve 1730ml of tetraethyl orthosilicate in 18030ml of absolute ethanol, under vigorous stirring, add 310ml of deionized water and 30ml of hydrochloric acid with a concentration of 0.12mol / L in sequence, control the pH value to 2.4, and then add 2 gram of lithium magnesium silicate, sealed and stirred for 3 hours, and aged for 15 days for later use; SiO 2 The anti-reflection coating solution is placed in an ultrasonic oscillator for 10 minutes, and the glass substrate is made of 3.2mm ultra-clear float glass, which is coated on both sides by the vertical pulling method. The pulling speed is 500mm / min, and then the Drying; tempering the coated glass, the tempering temperature is 700°C, the high temperature heating time is 170 seconds, and the enhanced wind pressure is 90%, and finally the high anti-reflection coating solar cell module packaging glass is obtained. The light transmittance of the packaging glass in the 400nm-1000nm band reaches an av...

Embodiment 2

[0020] At room temperature, dissolve 1,730ml of tetraethyl orthosilicate in 18,030ml of absolute ethanol. Under vigorous stirring, add 310ml of deionized water and 17ml of hydrochloric acid with a concentration of 0.12mol / L in order to control the pH value to 3.3, and then add 3 grams of lithium magnesium silicate, sealed and stirred for 3 hours, and aged for 15 days for later use; SiO 2 The anti-reflection coating solution was placed in an ultrasonic oscillator for 10 minutes, and the glass substrate was made of 3.2mm ultra-clear float glass, and the double-sided coating was applied to the substrate by the vertical pulling method. The pulling speed was 500mm / min, and then the Drying under low temperature; temper the coated glass, the tempering temperature is 700°C, the high temperature heating time is 170 seconds, and the enhanced wind pressure is 90%, and finally the high anti-reflection coating solar cell module packaging glass is obtained. The packaging glass has an averag...

Embodiment 3

[0022] At room temperature, dissolve 1,730ml of tetraethyl orthosilicate in 8,650ml of absolute ethanol. Under vigorous stirring, add 519ml of deionized water and 9ml of hydrochloric acid with a concentration of 0.12mol / L in sequence to control the pH value to 2, and then add 5 grams of lithium magnesium silicate, sealed and stirred for 2 hours, and aged for 11 days for later use; SiO 2The anti-reflection coating solution is placed in an ultrasonic oscillator for 5 minutes, and the glass substrate is made of 3.2mm ultra-clear float glass, which is coated on both sides by the vertical pulling method. The pulling speed is 500mm / min, and then the Drying; temper the coated glass with a tempering temperature of 800°C, a high-temperature heating time of 170 seconds, and an enhanced wind pressure of 95%, and finally obtain a highly anti-reflection coated solar cell module packaging glass. The average light transmittance of the packaging glass in the 400nm-1000nm band reaches 95.2%. ...

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Abstract

The invention provides a processing method for high anti-reflective glass for packaging a solar battery pack. The method has the advantages of high controllability, low production cost and simple process; and the prepared coated glass for packaging the solar battery pack has the advantages of high surface quality, high mechanical strength and obvious anti-reflection effect. The method comprises the following steps of: firstly, preparing SiO2 anti-reflection film solution; secondly, plating a film on the surface of glass with the SiO2 anti-reflection film solution; and finally, performing toughening treatment on the coated glass at a high temperature. The method is characterized in that: the preparation of the SiO2 anti-reflection film solution comprises the following steps of: adding a diluent into silicic ester at normal temperature, wherein the volume ratio of the silicic ester to the diluent is 1:(5-20); sequentially adding water and a hydrolysis catalyst with violently stirring, wherein the volume ratio of the silicic ester to the water is 1:(0.1-0.3) and the volume ratio of the silicic ester to the hydrolysis catalyst is 1:(0.005-0.15); regulating the pH of the reaction system to between 2 and 5, adding 1 to 5 grams of lithium magnesium silicate, and hermetically stirring the mixture for 2 to 10 hours; and aging the stirred mixture for 7 to 15 days at room temperature, wherein the gram / liter ratio of the lithium magnesium silicate to the silicic ester is 2:3.

Description

technical field [0001] The invention relates to the technical field of solar cell module production, in particular to a processing method of high anti-reflection glass for solar cell module packaging. Background technique [0002] In the 21st century, natural resources are increasingly scarce and energy is increasingly scarce. These have become the main problems and challenges facing the world today. For the sustainable development of human beings, human beings must be required to take active measures in seeking new environmentally friendly alternative energy sources. Solar energy is an inexhaustible clean energy, and effective use of solar energy will greatly alleviate these problems and challenges. Since Bell Laboratories in the United States made a practical monocrystalline silicon solar cell for the first time in 1954, solar cells have always been a hot spot in the field of scientific research and industrial application. After decades of hard work, the research on solar...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C17/25H01L31/0232H01L31/18G02B1/113H01L31/048
CPCY02E10/50Y02P70/50
Inventor 陆斌武
Owner 无锡海达光能股份有限公司
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