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Extrusion grade ASA resin with easy processing and high apparent property and preparation method thereof

An ASA resin and easy-to-process technology, applied in the field of extrusion grade ASA resin and its preparation, can solve the problems of poor apparent performance and difficult processing, and achieve excellent apparent performance, stable product quality, and simple process flow. Effect

Inactive Publication Date: 2010-10-06
SHANGHAI KUMHO SUNNY PLASTICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are relatively few studies on improving melt fracture in the extruded ASA system. Patent CN200580040844.8 improves the phenomenon of ASA melt fracture by adding PMMA, tetrafluoroethylene, and polyethylene wax, while patent CN00805380.4 uses Zinc salts of organic acids can improve the melt fracture phenomenon of polyesters, but the processing is difficult and the appearance performance is not good

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 6

[0033] A preparation method for extrusion-grade ASA resin of easy processing and high apparent performance, the method comprises the following steps:

[0034] (1) Prepare materials according to the following components and contents: 10 parts by weight of SAN-1 with a molecular weight of 100,000, 40 parts by weight of SAN-2 with a molecular weight of 120,000, and 50 parts by weight of ASA rubber powder with a rubber phase acrylate content of 30%. , 5 parts by weight of calcium carbonate, 5 parts by weight of barium sulfate, 0.1 part by weight of ethylene-vinyl acetate copolymer with a molecular weight of 10000, 0.01 part by weight of hexagonal boron nitride with a particle diameter of 0.1 μm, and 0.5 parts by weight of triphenyl phosphate (TPP) Parts, 0.2 parts by weight of alkylated monophenol, 0.2 parts by weight of antioxidant (1010), 1 part by weight of silicone oil;

[0035] (2) After the above-mentioned preparation materials are stirred and fully mixed in a high-speed mix...

Embodiment 7

[0038] A preparation method for extrusion-grade ASA resin of easy processing and high apparent performance, the method comprises the following steps:

[0039](1) Prepare materials according to the following components and contents: 35 parts by weight of SAN-1 with a molecular weight of 120,000, 30 parts by weight of SAN-2 with a molecular weight of 150,000, 30 parts by weight of ASA rubber powder with a rubber phase acrylate content of 70% , 3 parts by weight of oxidized polyethylene wax with a molecular weight of 6000, 1 part by weight of rhombohedral boron nitride with a particle diameter of 1.0 μm, 1 part by weight of bisphenol A bis(diphenyl phosphate) (BDP), resorcinol 2 parts by weight of bis(diphenyl phosphate) (RDP), 0.3 parts by weight of alkylated bisphenols, 0.3 parts by weight of diphenyl phosphite, 0.5 parts by weight of antioxidant (1010), 0.5 parts by weight of antioxidant (168) Parts by weight, 1 part by weight of white mineral oil, 1 part by weight of fatty ac...

Embodiment 8

[0043] A preparation method for extrusion-grade ASA resin of easy processing and high apparent performance, the method comprises the following steps:

[0044] (1) Prepare materials according to the following components and contents: 25 parts by weight of SAN-1 with a molecular weight of 100,000, 30 parts by weight of SAN-2 with a molecular weight of 130,000, and 45 parts by weight of ASA rubber powder with a rubber phase acrylate content of 60%. , a particle diameter of 3000-5000 mesh talcum powder 6 parts by weight, a molecular weight of 2000 polyethylene wax 0.8 parts by weight, a particle diameter of 0.5 μm cubic boron nitride 0.4 parts by weight, pyromellitic acid tetra(iso)octyl 0.5 Parts by weight, 0.5 parts by weight of trimellitate, 0.3 parts by weight of triphenyl phosphite, 0.6 parts by weight of antioxidant (1076), 2 parts by weight of magnesium stearate;

[0045] (2) After the above-mentioned preparation materials are stirred and fully mixed in a high-speed mixer, ...

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Abstract

The invention relates to an extrusion grade ASA resin with easy processing and high apparent property and a preparation method thereof. The extrusion grade ASA resin comprises the following components in part by weight: 50 to 70 parts of SAN resin, 30 to 50 parts of ASA rubber powder, 0 to 10 parts of inorganic filler, 0.1 to 3 parts of low molecular wax, 0.01 to 1 part of boron nitride, 0.5 to 3 parts of plasticizer, 0.2 to 0.6 part of light stabilizer, 0.2 to 1 part of antioxidant and 1 to 3 parts of lubricant. The preparation method comprises the following steps of: stirring and fully mixing the raw materials in a high-speed mixer, delivering the materials into a double-screw extruder through a metering device, melting and compounding the materials under the delivery, shearing and mixing of the screws, and extruding, bracing, cooling and granulating the materials to obtain the extrusion grade ASA resin with easy processing and high apparent property. Compared with the prior art, the preparation method reduces the production energy consumption, improves the bending phenomenon of profiles and plates, and improves the apparent property of ASA.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to an extrusion-grade ASA resin with easy processing and high apparent performance and a preparation method thereof. Background technique [0002] Acrylonitrile-acrylate-styrene (ASA) plastics are preferentially used in automobile manufacturing, sports and entertainment venues, bathroom and sanitary products, and electrical and electronic fields due to their very good weather resistance and aging resistance. With the rapid development of the market economy and the real estate industry, plastic extruded profiles, sheets, pipes, and plates have gained unprecedented opportunities for development, especially the use of plastic PVC products is the largest. [0003] However, PVC products have poor weather resistance and can only be made into white products. With the improvement of people's colorful and personalized needs, a variety of ASA and PVC co-extrusion products have appe...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L25/12C08L33/20C08L51/00C08K3/38C08K13/02
Inventor 周霆徐建荣董建廷李荣群辛敏琦
Owner SHANGHAI KUMHO SUNNY PLASTICS
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