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Method for preparing high-flow high-heat-resistance transparent polyvinyl chloride alloy capable of injection molding

A polyvinyl chloride and injection molding technology, which is applied in the field of preparation of transparent polyvinyl chloride alloys, can solve the problems of insufficient heat resistance and toughness of polyvinyl chloride, difficulty in taking into account the fluidity of polyvinyl chloride, and restricting the application of rigid polyvinyl chloride. , to achieve the effect of improving compatibility, improving fluidity and promoting uniform dispersion

Inactive Publication Date: 2010-12-15
ZHEJIANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The Chinese patent CN1651505A published on August 10, 2005 discloses a heat-resistant and smoke-suppressing polyvinyl chloride composition and its preparation method, which uses multi-component composite technology to improve the defects of polyvinyl chloride's insufficient heat resistance and toughness
It can also be seen from the existing research that while improving the heat resistance and mechanical properties of PVC, the existing PVC modifiers are often difficult to take into account the fluidity of PVC, and even make processing more difficult
In addition, the addition of existing polyvinyl chloride processing aids and modifiers often leads to poor transparency of products, which limits the application of rigid polyvinyl chloride in transparent occasions

Method used

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  • Method for preparing high-flow high-heat-resistance transparent polyvinyl chloride alloy capable of injection molding
  • Method for preparing high-flow high-heat-resistance transparent polyvinyl chloride alloy capable of injection molding

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] Add 100 parts by weight of S700 polyvinyl chloride and 1 part by weight of organotin stabilizer into a high-speed mixer, mix to 50°C, add 1 part by weight of acrylic processing aid, 1 part by weight of monoglycerin stearate ester, mixed to 70°C, added 0.3 parts by weight of oxidized polyethylene wax, mixed to 90°C, added 4 parts by weight of polyurethane elastomer, 4 parts by weight of polymethyl methacrylate and 1 part by weight of methyl methacrylate-butanedi ethylene-styrene copolymer, mixed to 110°C and cooled to obtain a polyvinyl chloride compound; the polyvinyl chloride compound was added to a conical twin-screw extruder, and the temperature in the first zone was 130°C, and the temperature in the second zone was 140 ℃, the temperature in the third zone is 150 ℃, the temperature in the fourth zone is 140 ℃, the screw speed is 4 rpm, and the feeding speed is 5 rpm. transparent polyvinyl chloride alloy.

Embodiment 2

[0021] Add 100 parts by weight of grade S1000 polyvinyl chloride and 3 parts by weight of organotin stabilizer into a high-speed mixer, mix to 60°C, add 3 parts by weight of acrylic processing aids, 3 parts by weight of monoglyceryl stearate , mixed to 80 ° C, added 1 weight part of oxidized polyethylene wax, mixed to 100 ° C, added 100 parts by weight of polyurethane elastomer, 100 parts by weight of methyl methacrylate-methyl acrylate copolymer and 50 parts by weight of methyl methacrylate Ester-butadiene-styrene copolymer, mixed to 120°C and cooled to obtain a polyvinyl chloride compound; the polyvinyl chloride compound was added to a conical twin-screw extruder, and the temperature in the first zone was 170°C, and the temperature in the second zone was The temperature in the zone is 180°C, the temperature in the third zone is 185°C, the temperature in the fourth zone is 180°C, the screw speed is 30 rpm, and the feeding speed is 20 rpm. Thermo-injection moldable clear polyv...

Embodiment 3

[0023] Add 100 parts by weight of SG3 polyvinyl chloride and 2 parts by weight of liquid calcium zinc stabilizer into a high-speed mixer, mix to 55°C, add 2 parts by weight of acrylic processing aids, 2 parts by weight of stearic acid, and mix to 75°C, add 1 part by weight of oxidized polyethylene wax, mix to 95°C, add 30 parts by weight of polyurethane elastomer, 50 parts by weight of polymethyl methacrylate and 25 parts by weight of methyl methacrylate-butadiene-benzene Ethylene copolymer, mixed to 120°C and cooled to obtain a polyvinyl chloride compound; the polyvinyl chloride compound was added to a conical twin-screw extruder, and the temperature in the first zone was 150°C, the temperature in the second zone was 160°C, and the temperature in the third zone was 160°C. The temperature in the zone is 165°C, the temperature in the fourth zone is 160°C, the screw speed is 15 rpm, and the feeding speed is 10 rpm, and it is melt-extruded and pelletized to obtain a high-fluidity,...

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Abstract

The invention discloses a method for preparing high-flow high-heat-resistance transparent polyvinyl chloride alloy capable of injection molding. The method comprises the following steps of: adding 100 weight parts of polyvinyl chloride and 1-3 weight parts of heat stabilizers into a high-speed mixer for mixing; sequentially adding 1-3 weight parts of acrylate processing aids, 1-3 parts of internal lubricants, 0.3-1 weight part of external lubricant, 4-100 weight parts of flow modifiers, 4-100 weight parts of heat-resistant anti-reflection modifiers and 1-50 weight parts of impact modifiers; taking out the mixed material, cooling, and adding the cooled material into a cone-shaped twin-screw extruder; melting and extruding under the condition that the temperature of a first area is 130-170 DEG C, the temperature of a second area is 140-180 DEG C, the temperature of a third area is 150-185 DEG C and the temperature of a fourth area is 140-180 DEG C; and granulating. In the preparation method of the alloy, the polyvinyl chloride, the processing aid and the modifiers are mechanochemically treated by adopting a new process, thereby the effective adsorption of the processing aid is enhanced, the compatibility of the modifiers and the polyvinyl chloride is improved, and the alloy product has the advantages of good transparency, good flowability, high heat resistance, high strength, and the like.

Description

technical field [0001] The invention relates to a preparation method of a transparent polyvinyl chloride alloy with high fluidity and high heat resistance which can be injection molded. Background technique [0002] Polyvinyl chloride is one of the commonly used general-purpose plastics. It has the advantages of flame retardancy, high chemical resistance, good mechanical strength and electrical insulation, low price, and wide application fields. PVC also has some disadvantages, such as poor fluidity, poor heat resistance, poor thermal stability, difficult processing, etc., which limit its use. [0003] Plastic alloys are a class of new materials with high performance, functionalization and specialization obtained by physical blending or chemical grafting. Plastic alloys can improve or enhance the performance of existing plastics and reduce costs, and are widely used in automobiles, electronics, precision instruments, office equipment, packaging materials, building materials...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/06C08L33/12C08L33/08C08L75/04C08L51/00C08K5/57B29C47/92B29C48/92
CPCB29C48/04B29C48/875B29C48/92B29C2948/9259B29C2948/92704B29C2948/92828B29C2948/92885B29C2948/92895
Inventor 宋义虎都佩华郑强
Owner ZHEJIANG UNIV
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