Adhesive for compounding marble veneer with base material and preparation method thereof

A marble and adhesive technology, applied in the direction of adhesives, adhesive types, polyether adhesives, etc., can solve problems such as difficulty in escaping small molecules, easy-to-contaminate materials, and unsustainable plasticizing effects, etc., to achieve cost reduction and good Combined effect, effect of increased usage

Active Publication Date: 2011-01-19
HUNAN MAGPOW ADHESIVE INDS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This kind of adhesive still has deficiencies, one is to use active calcium carbonate powder as inorganic filler, the oil absorption value is higher, easy to thicken, which restricts the amount of filler used, adding solvent ethanol, it is difficult for small molecules to escape during curing, and the other is The use of phenalkamine curing agent will cause serious yellowing and discoloration, and it is easy to contaminate materials. The third is the plasticization of dibutyl phthalate, which affects the bonding strength. It does not meet environmental protection requirements, and the plasticizing effect is difficult to last. It is indeed necessary to improve

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Preparation of component A

[0025] In the reactor, add 20 parts of epoxy resin E-44, which are parts by weight, the same below, 15 parts of E-51, 6 parts of polyether with an average molecular weight of 3000 and a functional degree of 2.5, start stirring, and heat up to 110°C, vacuum at the same time, the vacuum degree is controlled at -0.09MPa, react and dehydrate for 1.5 hours, cool down to 60°C, stop heating, eliminate the vacuum, add 0.2 parts of wetting agent and reactive diluent butanediol diglycidyl ether 2 parts, 0.15 parts of defoaming agent, 0.9 parts of coupling agent KH-560, continue to stir for 30 minutes after adding the above raw materials, then put in 25 parts of quasi-spherical silicon micropowder 300 mesh, 23 parts of heavy calcium carbonate 600 mesh, quasi-spherical 10 parts of silicon micropowder 800 mesh, stir for 3.5 hours after adding the powder, and vacuumize for 1 hour at the same time, the vacuum degree is -0.02MPa, then cool down to 40°C, fil...

Embodiment 2

[0029] Preparation of component A

[0030] 30 parts of epoxy resin E-44, 5 parts of reactive diluent butanediol diglycidyl ether, 2 parts of polyether with an average molecular weight of 3000 and a functionality of 2.5, 19 parts of 600-mesh heavy calcium carbonate, and the amount of other raw materials With embodiment 1 with preparation method;

[0031] Preparation of Component B

[0032] Formula and preparation process are with embodiment 1.

Embodiment 3

[0034] Preparation of component A

[0035] Raw material proportioning and preparation method are with embodiment 1;

[0036] Preparation of Component B

[0037] The amount of fatty amine selected from triethylenetetramine, isophorone diamine and butanediol diglycidyl ether is 13.7 parts, 5.3 parts and 15 parts respectively. When preparing the modified amine, first add 5.3 parts of isophorone diamine and 3.75 parts of butanediol diglycidyl ether. After the reaction is completed, add 13.7 parts of triethylenetetramine at one time, and evenly add butanediol dropwise within 1 hour 11.25 parts of diglycidyl ether, all the other materials and preparation method are with embodiment 1.

[0038] According to the adhesive industry standard GB24264-2009 for decorative stone materials, the main technical indicators of the embodiment samples are as follows:

[0039] project

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PUM

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Abstract

The invention relates to a bi-component modified epoxy adhesive for compounding a marble veneer with base materials such as a marble slab, a granite slab, a porcelain slab and a preparation method thereof. The adhesive comprises a component A and a component B, wherein the component A is prepared from epoxy resin, polyether, torispherical silicon micro-powder, heavy calcium carbonate and an auxiliary agent; and the component B is prepared from homemade modified amine, polyether amine, the torispherical silicon micro-powder, the heavy calcium carbonate and the auxiliary agent. The product has the characteristics of room temperature curing, high bond strength, water, heat and freeze-thaw resistance, low cost, convenient construction and the like.

Description

technical field [0001] The present invention relates to a kind of modified epoxy adhesive used for compounding facing stone thin boards, in particular to a kind of modified epoxy adhesive for compounding which takes marble thin boards as panels and marble boards, granite boards and porcelain boards as base materials and its Preparation. Background technique [0002] Marble slabs are elegant in texture, with clear and beautiful textures, and are often used as decorative materials for interior and exterior walls, floors, ceilings, window sills, tabletops, and sanitary ware of buildings. With the improvement of people's living standards and the promotion of cultural literacy, the number of such decorative materials is increasing. However, the marble material is brittle, the plate has many cracks, and the strength is not high. The thickness of the plate is generally not less than 20mm, which increases the consumption of marble materials, especially precious marble materials, an...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J163/00C09J171/00C09J11/04C09J163/02
Inventor 袁媛王理尧刘辉
Owner HUNAN MAGPOW ADHESIVE INDS
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