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High-filling high-heat distortion temperature polypropylene composite material and preparation method thereof

A composite material and deformation temperature technology, which is applied in the fields of high-filling and high-heat-distortion-temperature polypropylene composite materials and their preparation and components, can solve the problems of high heat-distortion temperature and complicated process of modified polypropylene, and improve heat aging resistance. , the effect of increasing solubility, improving heat resistance and heat distortion temperature

Active Publication Date: 2012-07-11
KINGFA SCI & TECH CO LTD +3
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to overcome the deficiencies in the prior art, such as high thermal deformation temperature of modified polypropylene and complicated process, to provide a high-filling high thermal deformation temperature polypropylene composite material

Method used

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  • High-filling high-heat distortion temperature polypropylene composite material and preparation method thereof
  • High-filling high-heat distortion temperature polypropylene composite material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] A high-filling high heat distortion temperature polypropylene composite material is composed of the following raw materials in weight percentage: polypropylene A (brand: K7726H, Sinopec Yanshan Petrochemical Company) 30%; polypropylene B (brand: 140 powder, Sinopec Co., Ltd. Maoming Branch) 8%; elastomer 10%; talcum powder 50%; composite antioxidant 1.5%; nucleating agent 0.2%; processing aid 0.3%.

[0037]The composite antioxidant is preferably A+B type, wherein A is 1,3,5-tri(3,5-di-tert-butyl-4-hydroxybenzyl)-s-triazine-2,4,6 -(1H,3H,5H ) triketone (Ningbo Jinhai Yabao Chemical Co., Ltd.) 1.0%, B is tris(2,4-di-tert-butylphenyl)phenylphosphite (Ningbo Jinhai Yabao Chemical Co., Ltd.) 0.25% and tetrakis (β-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate) pentaerythritol ester (Beijing Yizhong Weiye Chemical Co., Ltd.) 0.25%; the elastomer is ethylene-butene Copolymer (Shenzhen Yongcheng Plastic Chemical Co., Ltd.); the talc powder is AH-3000N1 (Liaoning Aihai Talc Co....

Embodiment 2

[0043] A high-filling high heat distortion temperature polypropylene composite material is composed of the following raw materials in weight percentage: polypropylene A (brand: K7760, Sinopec Yanshan Petrochemical Company) 70%; polypropylene B (brand: 300 powder, Sinopec Co., Ltd. Maoming branch) 5%; elastomer 14%; talcum powder 10%; composite antioxidant 0.7%; nucleating agent 0.1%; processing aid 0.2%.

[0044] The composite antioxidant is preferably A+B type, wherein A is 0.5% of tetrafunctional glycidylamine epoxy resin (Guangzhou Rongsheng Chemical Co., Ltd.), and B is bis(2.4-di-tert-butylphenyl ) pentaerythritol diphosphite (Ningbo Jinhai Yabao Chemical Co., Ltd.) company) 0.1%. The elastomer is 7% of ethylene-butene copolymer and 7% of ethylene-propylene-octene terpolymer (Shanghai Bading Trading Co., Ltd.). The talc powder is AH-3000N9 (Liaoning Aihai Talc Co., Ltd.). The nucleating agent is NA-11 (Youdi Trading (Shanghai) Co., Ltd.). Described processing aid is m...

Embodiment 3

[0050] A high-filling high heat distortion temperature polypropylene composite material is composed of the following raw materials in weight percentage: polypropylene A (brand: AP3N, American Exxon Chemical Jiangmen Co., Ltd.) 60%; polypropylene B (brand: 300 powder ) 8%; talcum powder 30%; compound antioxidant 1.3%; nucleating agent 0.3%; processing aid 0.4%.

[0051] The composite antioxidant is preferably A+B type, wherein A is 1.0% of tetrafunctional glycidylamine epoxy resin (Guangzhou Rongsheng Chemical Co., Ltd.), and B is di(eighteenteen) thiodipropionate Ester (Ningbo Jinhai Yabao Chemical Co., Ltd.) 0.2% and tetrakis (β-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate) pentaerythritol ester (Beijing Yizhong Weiye Chemical Co., Ltd.) 0.1%. The talc powder is AH-1250 (Liaoning Aihai Talc Co., Ltd.). Described nucleating agent is HPN-68L (American Milliken chemical company). The processing aid is composed of 0.2% polyethylene wax, 0.1% ethylene bis stearamide and 0.1% c...

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Abstract

The invention discloses a high-filling high-heat distortion temperature polypropylene composite material, which is prepared from the following raw materials in percentage by weight: 30 to 70 percent of co-polypropylene, 5 to 10 percent of powder polypropylene, 10 to 50 percent of talcpowder, 0.5 to 1.5 percent of composite antioxidant, 0.1 to 0.5 percent of nucleating agent, 0.1 to 1 percent of processing aid and 0 to 20 percent of elastomer, wherein the composite antioxidant is a mixture of an antioxidant with multipolar functional group and a common antioxidant; and the functionality of theantioxidant with the polar functional group is more than or equal to 3. A method for preparing the composite material comprises the following steps of: mixing the power polypropylene, the elastomer, the talcpowder, the nucleating agent and partial processing aid to form talcpowder masterbatches; and uniformly mixing the talcpowder masterbatches and the rest components, and performing melt extrusion and granulation. The polypropylene composite material disclosed by the invention has good mechanical properties, also has higher heat distortion temperature, and is suitable for manufacturing automotive interior and exterior parts, parts of air conditioner and the like.

Description

technical field [0001] The invention belongs to the technical field of modified materials, and in particular relates to a high-filling and high-heat-distortion-temperature polypropylene composite material and a preparation method thereof, which are mainly used in the manufacture of interior and exterior trim parts of automobiles, air conditioners and other components. Background technique [0002] Polypropylene (PP) is a thermoplastic synthetic resin with excellent performance. It has the advantages of small specific gravity, non-toxicity, easy processing, anti-disturbance warp and good electrical insulation. and so on have a wide range of applications. However, polypropylene also has some shortcomings, such as large molding shrinkage, low-temperature brittleness, insufficient wear resistance, and low heat distortion temperature. Many parts, such as automobile engines and air conditioners, have high requirements on the heat resistance of materials. If the heat distortion te...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/14C08L23/12C08K13/02C08K3/34C08J3/22B29B9/06B29C47/92B29C48/92
CPCB29C48/04B29C48/92B29C2948/92704B29C2948/92895
Inventor 王灿耀黄达罗忠富杨燕杨波李永华宁凯军
Owner KINGFA SCI & TECH CO LTD
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