Method for producing agricultural chitosan and active calcium fertilizer by utilizing crawfish
A technology of active calcium fertilizer and chitin, applied in the application, agriculture, organic fertilizer and other directions, can solve the problems of restricting the healthy development of the chitin industry, polluting the environment, loss of nutrients, etc., to solve the problem of secondary pollution, and the production process is simple. Effect
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Embodiment 1
[0016] Get crayfish to remove 1kg of the residue after the meat, as in the glass reaction container, add mixed acid solution I 10kg, mixed acid solution I is nitric acid, citric acid, acetic acid, formic acid and water according to mass ratio 12:2:6:2: Mixed at 400°C, 40°C cycle reaction for 10 hours, solid-liquid separation, washing the solid part with water for 3 times and drying in the sun, it is agricultural chitin, chitin in agricultural chitin≥70%, calcium≤5%, moisture≤ 10%, miscellaneous protein ≤ 15%, heavy metal qualified, 180 grams of agricultural chitin can be obtained, and the yield rate is 18%; the liquid part is concentrated and spray-dried to obtain 700 grams of active calcium fertilizer, which contains calcium nitrate, calcium formate, Soluble organic calcium such as calcium acetate, calcium amino acid, calcium gluconate, calcium citrate, calcium butyrate, calcium sorbate, calcium malate, etc., also contains protein, trace elements and other nutrients.
Embodiment 2
[0018] Take 500g of the crayfish residue after removing the meat, and add 3kg of mixed acid solution II to the glass reaction vessel. Mixed acid solution I is made by mixing nitric acid, lactic acid and water according to the mass ratio of 10:2:88, and the reaction is carried out at 30°C. After 5 hours, carry out solid-liquid separation, wash the solid part with water for 3 times and dry it in the sun, which is agricultural chitin, in which chitin≥70%, calcium≤5%, moisture≤10%, miscellaneous protein≤15%, The heavy metal is qualified, and 98 grams of chitin for agricultural use can be obtained, with a yield of 19.6%. The liquid part is concentrated and spray-dried to obtain 360 grams of active calcium fertilizer. The active calcium fertilizer contains calcium nitrate, calcium formate, calcium acetate, amino acid calcium, and calcium gluconate. , Calcium citrate, calcium butyrate, calcium sorbate, calcium malate and other soluble organic calcium, also contains protein, trace elem...
Embodiment 3
[0020] Take 5kg of crayfish residue after removing the meat, and add 20kg of mixed acid solution III to the glass reaction vessel, mixed acid solution I is nitric acid, lactic acid, cystine, gluconic acid and water according to the mass ratio of 10:2:6:2 : 78 mixed, reacted at 50°C for 3 hours, separated from solid and liquid, washed with water for 3 times and dried in the sun, then it is agricultural chitin. Chitin in agricultural chitin ≥ 70%, calcium ≤ 5%, moisture ≤10%, miscellaneous protein ≤15%, heavy metal qualified; 1000 grams of agricultural chitin can be obtained, and the yield is 20%; the liquid part is concentrated and spray-dried to obtain 3.6kg of active calcium fertilizer, which contains calcium nitrate and formic acid Calcium, calcium acetate, calcium amino acid, calcium gluconate, calcium citrate, calcium butyrate, calcium sorbate, calcium malate and other soluble organic calcium, also contains protein, trace elements and other nutrients.
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