Polyvinyl chloride (PVC ) heat shrink label film
A heat-shrinkable, PVC resin technology, applied in the field of PVC heat-shrinkable label films, can solve problems such as the inability to effectively block vitamin C damage, the limited ability of ink to absorb ultraviolet rays, and the juices that are not resistant to ultraviolet rays. , The effect of improving ultraviolet absorption capacity and avoiding degradation damage
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Embodiment 1
[0017] Example 1: Anti-ultraviolet PVC heat-shrinkable label film.
[0018] Formula: 100 parts by weight of SG-5 type PVC resin, 2.0 parts by weight of methyl tin mercaptide 181, 4.5 parts by weight of dioctyl phthalate (DOP), 1.5 parts by weight of processing aid ACR-201, modifier MBS BTA-717 3.2 parts by weight, internal lubricant G-16 0.9 parts by weight, external lubricant AC316A 0.3 parts by weight, 2,4,6-tris(2′-hydroxy-4′-n-butoxyphenyl)-1 , 0.6 parts by weight of 3,5-triazine (triazine-5), 0.6 parts by weight of 2-hydroxy-4-n-octyloxy-benzophenone (UV-531), 0.6 parts by weight of 2-(2′-hydroxy-3 ',5'-di-tert-butyl)benzotriazole (UV-320) 0.4 parts by weight, 2,3,5-dichlorophenyl salicylate 0.5 parts by weight, 2-cyano-3,3-di 0.8 parts by weight of ethyl phenyl acrylate (N-35).
[0019] Preparation: Weigh the material according to the formula, and the process flow: high-speed mixing——cooling and mixing——extruder plasticizing——film blowing head molding——secondary blowin...
Embodiment 2
[0021] Example 2: Anti-ultraviolet PVC heat-shrinkable label film.
[0022] Formula: 100 parts by weight of SG-7 PVC resin, 2.5 parts by weight of methyl tin 191, 5.0 parts by weight of dioctyl terephthalate (DOTP), 2.0 parts by weight of processing aid ACR K-120ND, modifier MBS B521 4.0 parts by weight, internal lubricant G60 1.2 parts by weight, external lubricant G78 0.6 parts by weight, 2-(2'-hydroxy-5'-methylphenyl) benzotriazole (UV-P) 0.6 parts by weight, 2 - 0.8 parts by weight of hydroxy-4-methoxybenzophenone (UV-531), 0.4 parts by weight of p-tert-butylphenyl salicylate (TBS), 2-cyano-3,3-diphenylacrylic acid 0.8 parts by weight of 2-ethylhexyl ester (N-539).
[0023] Preparation: as in Example 1.
[0024] Film properties: film thickness 0.050mm, diameter 780mm, transverse shrinkage rate 50%, longitudinal shrinkage rate 2%, absorbance 0.52 (the maximum value of ultraviolet light absorption at 360~380nm), ultraviolet light (350nm) transmittance 39.2%.
Embodiment 3
[0025] Embodiment 3: Anti-ultraviolet PVC heat-shrinkable label film.
[0026]Formula: 100 parts by weight of SG-5 PVC resin, 1.8 parts by weight of isooctyl dimercaptoacetate di-n-octyltin (DOTTG), 3.0 parts by weight of epoxy soybean oil (ESBO), 1.8 parts by weight of processing aid ACR K-125, Modifier MBS B22 2.8 parts by weight, internal lubricant monoglyceride stearate (GMS) 0.8 parts by weight, external lubricant oxidized polyethylene wax 0.3 parts by weight, 2-(2'-hydroxyl-4'-n-octyloxy phenyl) benzotriazole (UV-510) 1.7 parts by weight, bisphenol A disalicylate (BAD) 0.6 parts by weight, ethyl 2-cyano-3,3-diphenylacrylate (N- 35) 1.2 parts by weight.
[0027] Preparation: as in Example 1.
[0028] Film properties: film thickness 0.050mm, diameter 780mm, transverse shrinkage rate 50%, longitudinal shrinkage rate 2%, absorbance 0.49 (360~380nm ultraviolet light absorption maximum), ultraviolet light (350nm) transmittance 42.7%.
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