Anti-aging plastomer modified asphalt coating material with magnalium-based layed double hydroxide and preparation method thereof
A double hydroxide, anti-aging technology, applied in the direction of building structure, building insulation materials, building components, etc., can solve the problems of difficult asphalt-based waterproof membrane anti-aging performance, limited stability, etc., to improve UV aging resistance Performance and service life extension effect
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Embodiment 1
[0022] Add 12 parts (parts by mass, the same below) of atactic polypropylene (APP) to 58 parts of asphalt (softening point 44.5°C, penetration 120dmm) that has been heated to 170°C, keep the temperature at 170-180°C, Stir with the rotating speed of 4000rpm on the shear mixer for 1.5 hours, add 3 parts of magnesium-aluminum-based layered double hydroxides (formed as Mg 0.75 al 0.25 (OH) 2 (CO 3 ) 0.12 1.2H 2 O, and surface modified by dodecyl siloxane, the particle size in a and b directions is 2.1 μm, and the particle size in the c-axis direction is 0.13 μm, about 110 layers), and the holding temperature is 170-180 ° C , stirred and reacted at a speed of 4000rpm for 1 hour, then added 27 parts of talc powder (200 mesh in particle size), reduced the stirring speed to 2000rpm, kept the temperature at 170-180°C, and stirred for 1 hour to obtain a magnesium aluminum Base-layer double hydroxide aging-resistant plastic body modified asphalt coating material.
[0023] The ultra...
Embodiment 2
[0025] Add 13.5 parts of atactic polypropylene (APP) to 56 parts of asphalt (softening point 44.5°C, penetration 120dmm) that has been heated to 170°C, keep the temperature at 170-180°C, and use a high-shear mixer at 5000rpm Stir at a rotating speed of 1 hour, add 5 parts of magnesium-aluminum-based layered double hydroxide, keep the temperature at 170-180 ° C, stir and react at a rotating speed of 5000 rpm for 1 hour, and then add 25.5 parts of talcum powder (particle size: 200 mesh), Reduce the stirring speed to 3000rpm, keep the temperature at 170-180°C, and stir for 1 hour to obtain a magnesium-aluminum-based layered double hydroxide aging-resistant plastic body modified asphalt coating material.
[0026] The magnesium-aluminium-based layered double hydroxide aging-resistant plastic body modified asphalt coating material was subjected to ultraviolet aging test in the ultraviolet aging box. The softening point before and after increased from 144.2°C to 148.4°C, an increase ...
Embodiment 3
[0028] Add 9 parts of amorphous olefin copolymer (APAO) and 4 parts of random polypropylene (APP) to 55 parts of asphalt (softening point 46.5 °C, penetration 95 dmm) that has been heated to 180 ° C, and keep the temperature at 180 ~ 190°C, stirred at a speed of 3000rpm on a high-shear mixer for 2 hours, added 2 parts of magnesium-aluminum-based layered double hydroxide, kept the temperature at 180-190°C, stirred and reacted at a speed of 4000rpm for 1 hour, and then added 15 1 part of talcum powder and 15 parts of heavy calcium carbonate (both particle sizes are 200 mesh), reduce the stirring speed to 2000rpm, keep the temperature at 180-190°C, and stir for 1 hour to obtain a magnesium-aluminum-based layered double hydroxide Aging-resistant plastomer-modified asphalt coatings.
[0029] The ultraviolet aging test was carried out on the magnesium-aluminum-based layered double hydroxide aging-resistant plastic body modified asphalt coating material in the ultraviolet aging box. ...
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